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Acetic Acid Assistant Hydrogenation of Graphene Sheets with Ferromagnetism

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Abstract

Ferromagnetism of pure carbon-based materials has been widely researched for several years. In therocially and experimentally, semi-hydrogenation graphene sheets exhibit ferromagnitism, which is related to the degree of hydrogenation. Here we reported the controllable hydrogenation of graphene using ball-milling method with acetic acid as hydrogenating agent. The hydrogenation graphene sheets were characterized by means of transmission electron microscopy(TEM), Raman spectroscopy and X-ray photoelectron spectroscopy, and magnetic measurement. The relusts of Raman spectroscopy demonstrate that the relative intensity of D band increases with the hydrogenation degree. The resluts of magnetic meansurement indicate the maximal magnetic moment of 0.274 A·m2/kg at 2 K for semi-hydrogenation graphene.

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Authors and Affiliations

  1. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China

    Qiushi Sun, Xiaofeng Wang, Benxian Li, Yunpeng Wu, Ziqing Zhang, Xinyang Zhang, Xudong Zhao & Xiaoyang Liu

Authors
  1. Qiushi Sun
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  2. Xiaofeng Wang
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  3. Benxian Li
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  4. Yunpeng Wu
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  5. Ziqing Zhang
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  6. Xinyang Zhang
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  7. Xudong Zhao
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  8. Xiaoyang Liu
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Corresponding authors

Correspondence to Xudong Zhao or Xiaoyang Liu.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21271082, 21371068).

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Sun, Q., Wang, X., Li, B. et al. Acetic Acid Assistant Hydrogenation of Graphene Sheets with Ferromagnetism. Chem. Res. Chin. Univ. 34, 344–349 (2018). https://doi.org/10.1007/s40242-018-8001-9

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  • DOI: https://doi.org/10.1007/s40242-018-8001-9

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