Abstract
The metastable solubilities and the physicochemical properties including density and pH of the reciprocal quaternary system(LiCl+MgCl2+Li2SO4+MgSO4+H2O) at 348.15 K and 0.1 MPa were determined using the isother-mal evaporation method. The dry-salt diagram and water-phase diagram were plotted based on the experimental data. There are five invariant points, eleven univariant curves, and seven crystallization zones corresponding to hexahy-drite, tetrahydrite, kieserite, bischofite, lithium sulfate monohydrate, lithium chloride monohydrate and lithium car-nallite. Comparison between the stable and metastable diagrams at 348.15 K indicates that the metastable phenome-non of magnesium sulfate is obvious, and the crystallization regions of hexahydrite and tetrahydrite disappear in the stable phase diagram. A comparison of the metastable dry-salt phase diagrams at 308.15, 323.15 and 348.15 K shows that with the increasing of temperature the epsomite crystallization zone disappears from the dry-salt phase diagram of 303.15 K, and a new kieserite crystallization zone is presented at 348.15 K. The density and pH in the metastable equilibrium solution present regular change with the increasing of Jänecke index J(2Li+), and the calculated densities using the empirical equation agree well with the experimental values.
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References
Zheng X. Y., Tibet Saline Lake, China Science Press, Beijing, 1988
Sun B., Song P. S., Du X. H., J. Salt Lake Res., 1994 2, 26
Xiang L., Liu F., Jin Y. C., Sea-Lake Salt Chem. Ind., 2002 31, 24
Meng L. Z., Guo Y. F., Li D., Deng T. L., Chem. Res. Chinese Universities, 2017 33(4), 655
Luo M., Jiang W. Q., Han X., Guo R. G., Li T., Yu L. M., Chem. J. Chinese Universities, 2018 39(1), 148
Meng Y. J., Liu X. Y., Liu L., Li B. X., Zhao X. D., Feng L. K., Wang Y. X., Wang X. F., Chem. Res. Chinese Universities, 2015 31(5), 820
Vajjsfjel’d M. E., Shevchuk V. G., Russ. J. Inorg. Chem., 1969 14, 571
Kycyeov M., Musuralejev K., Emaeakunov V., Russ. J. Inorg. Chem., 1966 39, 2116
Ren K. W., Song P. S., Chin. J. Inorg. Chem., 1994 10, 69
Shevchuk V. G., Vajjsfjel’d M. E., Russ. J. Inorg. Chem., 1964 9, 2773
Shevchuk V. G., Vajjsfjel’d M. E., Russ. J. Inorg. Chem., 1967 12, 1691
Vajjsfjel’d M. E., Shevchuk V. G., Russ. J. Inorg. Chem., 1968 13, 600
Guo Z. Z., Liu Z. Q., Chen J. Q., Acta Chim. Sin., 1991 49, 937
Gao J., Deng T. L., J. Chem. Eng. Data, 2011 56, 1452
Meng L. Z., Yu X. P., Li D., Deng T. L., J. Chem. Eng. Data, 2011 56, 4627
Deng T. L., Yin H. A., Tang M. L., Chem. J. Chinese Universities, 2000 21(10), 1572
Zeng Y., Yin H. A., Tang M. L., Feng X. X., Chem. J. Chinese Universities, 2003 24(6), 968
Wang S. Q., Gao J., Yu X., Sun B., Deng T. L., J. Salt Lake Res., 2007 15, 44
Fang C. H., J. Salt Lake Res., 1990 2, 15
Speight J., Lange’s Handbook of Chemistry(Seventeenth Edition), McGraw-Hill Education, New York, 2016
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Supported by the National Natural Science Foundation of China(Nos.U1607129, U1607123, 21773170), the China Postdoctoral Science Foundation(Nos.2016M592827, 2016M592828), the Application Foundation and Advanced Technology Program of Tianjin, China(No.15JCQNJC08300), and the Yangtze Scholars and Innovative Research Team of the Chinese University(No.IRT-17R81).
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Yu, X., Wang, Q., Guo, Y. et al. Metastable Phase Equilibrium in the Reciprocal Quaternary System LiCl+MgCl2+Li2SO4+MgSO4+H2O at 348.15 K and 0.1 MPa. Chem. Res. Chin. Univ. 34, 798–802 (2018). https://doi.org/10.1007/s40242-018-7407-8
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DOI: https://doi.org/10.1007/s40242-018-7407-8