Abstract
Biphasic defective TiO2–x/reduced graphene oxide(RGO) nanocomposites were synthesized by simple hydrothermal reactions. Compared with TiO2–x and commercial P25, TiO2–x/RGO shows much better photocatalytic activity and excellent stability in pollutants degradation, which could be ascribed to Ti3+ centers complexed with RGO and the synergetic effect between the two phases. The study reveals a new route for the synthesis of mixed-phase defective TiO2–x/carbon material nanocomposites for photocatalytic applications.
Similar content being viewed by others
References
Chen X. B., Shen S. H., Guo L. J., Mao S. S., Chem. Rev., 2010, 110, 6503
Brown G. E. Jr., Henrich V. E., Casey W. H., Clark D. L., Eggleston C., Felmy A., Goodman D. W., Gratzel M., Maciel G., McCarthy M. I., Nealson K. H., Sverjensky D. A., Toney M. F., Zachara J. M., Chem. Rev., 1999, 99, 77
Liu L., Chen X. B., Chem. Rev., 2014, 114, 9890
Ma Y., Wang X. L., Jia Y. S., Chen X. B., Han H. X., Li C., Chem. Rev., 2014, 114, 9987
Fujishima A., Honda K., Nature, 1972, 238, 37
Asahi R., Morikawa T., Ohwaki T., Aoki K., Taga Y., Science, 2001, 293, 269
Thompson T. L., Yates J. T., Chem. Rev., 2006, 106, 4428
Yang H. G., Sun C. H., Qiao S. Z., Zou J., Liu G., Smith S. C., Cheng H. M., Lu G. Q., Nature, 2008, 453, 638
Chen X. B., Liu L., Liu Z., Marcus M. A., Wang W. C., Oyler N. A., Grass M. E., Mao B. H., Glans P. A., Yu P. Y., Guo J. H., Mao S. S., Sci. Rep., 2013, 3, 1510
Liu X., Gao S. M., Xu H., Lou Z. Z., Wang W. J., Huang B. B., Dai Y., Nanoscale, 2013, 5, 1870
Zheng Z. K., Huang B. B., Meng X. D., Wang J. P., Wang S. Y., Lou Z. Z., Wang Z. Y., Qin X. Y., Zhang X. Y., Dai Y., Chem. Commun., 2013, 49, 868
Nowotny M. K., Sheppard L. R., Bak T., Nowotny J., J. Phys. Chem. C, 2008, 112, 5275
Wang Z., Yang C. Y., Lin T. Q., Yin H., Chen P., Wan D. Y., Xu F. F., Huang F. Q., Lin J. H., Xie X. M., Jiang M. H., Energy Environ. Sci., 2013, 6, 3007
Grabstanowicz L. R., Gao S., Li T., Rickard R. M., Rajh T., Liu D. J., Xu T., Inorg. Chem., 2013, 52, 3884
Chen X. B., Liu L., Yu P. Y., Mao S. S., Science, 2011, 331, 746
Zuo F., Wang L., Wu T., Zhang Z. Y., Borchardt D., Feng P. Y., J. Am. Chem. Soc., 2010, 132, 11856
Wang J. Q., Su S. Y., Liu B., Cao M. H., Hu C. W., Chem. Commun., 2013, 49, 7830
Fan C. M., Peng Y., Zhu Q., Lin L., Wang R. X., Xu A. W., J. Phys. Chem. C, 2013, 117, 24157
Wang J., Shen L. F., Nie P., Xu G. Y., Ding B., Fang S., Dou H., Zhang X. G., J. Mater. Chem. A, 2014, 2, 9150
Zhang H., Lv X. J., Li Y. M., Wang Y., Li J. H., ACS Nano, 2010, 4, 380
Liang Y. Y., Wang H. L., Casalongue H. S., Chen Z., Dai H. J., Nano Res., 2010, 3, 701
Perera S. D., Mariano R. G., Vu K., Nour N., Seitz O., Chabal Y., Balkus K. J. Jr., ACS Catal., 2012, 2, 949
Geim A. K., Novoselov K. S., Nature Materials, 2007, 6, 183
Cong S., Xu Y. M., J. Phys. Chem. C, 2011, 115, 21161
Shah M. S. A. S., Park A. R., Zhang K., Park J. H., Yoo P. J., ACS Appl. Mater. Interfaces, 2012, 4, 3893
Carneiro J. T., Savenije T. J., Moulijn J. A., Mul G., J. Phys. Chem. C, 2011, 115, 2211
Wang F. L., Ho J. H., Jiang Y. J., Amal R., ACS Appl. Mater. Inter-faces, 2015, 7, 23941
Hummers W. S., Offeman R. E., J. Am. Chem. Soc., 1958, 80, 1339
Xu Y. X., Bai H., Lu G. W., Li C., Shi G. Q., J. Am. Chem. Soc., 2008, 130, 5856
Spurr R. A., Myers H., Anal. Chem., 1957, 29, 760
Song X. M., Wu J. M., Tang M. Z., Qi B., Yan M., J. Phys. Chem. C, 2008, 112, 19484
Rezaee M., Mousavi Khoie S. M., Liu K. H., Cryst. Eng. Comm., 2011, 13, 5055
Yan J. Q., Wu G. J., Guan N. J., Li L. D., Li Z. X., Cao X. Z., Phys. Chem. Chem. Phys., 2013, 15, 10978
Zhang X. Y., Li H. P., Cui X. L., Li Y. H., J. Mater. Chem., 2010, 20, 2801
Parker J. C., Siegel R. W., J. Mater. Res., 1990, 5, 1246
Cronemeyer D. C., Phys. Rev., 1959, 113, 1222
Zheng Z. K., Huang B. B., Qin X. Y., Zhang X. Y., Dai Y., Whangbo M. H., J. Mater. Chem., 2011, 21, 9079
Li J. G., Buchel R., Isobe M., Mori T., Ishigakii T., J. Phys. Chem. C, 2009, 113, 8009
Bityurin N., Znaidi L., Kanaev A., Chem. Phys. Lett., 2003, 374, 95
Suriye K., Praserthdam P., Jongsomjit B., Appl. Surf. Sci., 2007, 253, 3849
Author information
Authors and Affiliations
Corresponding authors
Additional information
Supported by the Doctoral Startup Foundation of Anhui University, China(No.10113190077), the Natural Science Foundation of Anhui Province, China(No.1608085QB39) and the National Natural Science Foundation of China(No.51402001).
Rights and permissions
About this article
Cite this article
Gao, G., Zhu, Q., Chong, H. et al. Synthesis of Biphasic Defective TiO2–x/Reduced Graphene Oxide Nanocomposites with Highly Enhanced Photocatalytic Activity. Chem. Res. Chin. Univ. 34, 158–163 (2018). https://doi.org/10.1007/s40242-018-7369-x
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40242-018-7369-x