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In situ Growing PtCo Bimetallic Catalyst on Plant Tannin-grafted Collagen Fiber for Catalytic Hydrogenation of Cinnamaldehyde with Desirable Performance

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Abstract

PtCo x bimetallic nanoparticles(NPs) supported on tannin-grafted collagen fiber(CF-BT) have been pre-pared via a novel synthetic strategy, and applied for catalytic hydrogenation of cinnamaldehyde(CAL), a typic unsa-turated aldehyde. The catalysts were systematically and specifically characterized by means of XRD, XPS, TEM-EDX and SEM to clarify the structure-property correlation. It was found that the PtCo x /CF-BT catalysts exhi-bited significantly enhanced catalytic activity and desirable stability in catalytic hydrogenation of CAL, which is ascribed to the synergistic interaction between bimetallic components, the effective dispersion, the anchoring role of CF-BT matrix on bimetallic NPs, as well as the lower mass transfer resistance of the matrix.

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Authors and Affiliations

  1. Department of Scientific Research, Sichuan Normal University, Chengdu, 610068, P. R. China

    Ziyi Liao

  2. College of Chemistry and Materials Science, Sichuan Normal University, Chengdu, 610068, P. R. China

    Yang Lan, Kai Wang, Miao Lei, Yang Liao, Hui Mao, Jun Ma & Shilin Zhao

  3. Engineering Research Center for the Development of Farmland Ecosystem Service Functions, Sichuan Province Institutions of Higher Education, Chengdu, 610068, P. R. China

    Yang Liao, Hui Mao, Jun Ma & Shilin Zhao

Authors
  1. Ziyi Liao
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  2. Yang Lan
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  3. Kai Wang
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  4. Miao Lei
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  5. Yang Liao
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  6. Hui Mao
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  7. Jun Ma
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  8. Shilin Zhao
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Corresponding authors

Correspondence to Jun Ma or Shilin Zhao.

Additional information

Supported by the National Natural Science Foundation of China(Nos.21776188, 51173122, 21406147), the Science and Technology Department of Sichuan Province, China(No.2016SZ0071), the Education Department of Sichuan Province, China(No.16ZA0049) and the Engineering Research Center for the Development of Farmland Ecosystem Service Functions, Sichuan Province Institutions of Higher Education, China.

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Liao, Z., Lan, Y., Wang, K. et al. In situ Growing PtCo Bimetallic Catalyst on Plant Tannin-grafted Collagen Fiber for Catalytic Hydrogenation of Cinnamaldehyde with Desirable Performance. Chem. Res. Chin. Univ. 34, 285–289 (2018). https://doi.org/10.1007/s40242-018-7234-y

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  • DOI: https://doi.org/10.1007/s40242-018-7234-y

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