Chemical Research in Chinese Universities

, Volume 34, Issue 2, pp 285–289 | Cite as

In situ Growing PtCo Bimetallic Catalyst on Plant Tannin-grafted Collagen Fiber for Catalytic Hydrogenation of Cinnamaldehyde with Desirable Performance

  • Ziyi Liao
  • Yang Lan
  • Kai Wang
  • Miao Lei
  • Yang Liao
  • Hui Mao
  • Jun Ma
  • Shilin Zhao


PtCo x bimetallic nanoparticles(NPs) supported on tannin-grafted collagen fiber(CF-BT) have been pre-pared via a novel synthetic strategy, and applied for catalytic hydrogenation of cinnamaldehyde(CAL), a typic unsa-turated aldehyde. The catalysts were systematically and specifically characterized by means of XRD, XPS, TEM-EDX and SEM to clarify the structure-property correlation. It was found that the PtCo x /CF-BT catalysts exhi-bited significantly enhanced catalytic activity and desirable stability in catalytic hydrogenation of CAL, which is ascribed to the synergistic interaction between bimetallic components, the effective dispersion, the anchoring role of CF-BT matrix on bimetallic NPs, as well as the lower mass transfer resistance of the matrix.


Heterogeneous PtCox bimetallic catalyst Tannin-grafted collagen fiber Cinnamaldehyde Liquid-phase hydrogenation 


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  1. [1]
    Lionel A. S., Chem. Res., 2007, 40, 1309CrossRefGoogle Scholar
  2. [2]
    Beller M., Blaser H. U., Platinum Metals Rev., 2013, 57, 272CrossRefGoogle Scholar
  3. [3]
    Arvela P. M., Hajek J., Salmi T., Murzin D. Y., Appl. Catal. A: Gen., 2005, 292, 1CrossRefGoogle Scholar
  4. [4]
    Mahmoud S., Hammoudeh A., Gharaibeh S., Melsheimer J., J. Mol. Catal. A:Chem., 2002, 178, 161CrossRefGoogle Scholar
  5. [5]
    Ma J., Lan Y., Mao H., Liao Y., Zhao S. L., Chem. Res. Chinese Universities, 2017, 33(4), 660CrossRefGoogle Scholar
  6. [6]
    Chong P., Rong G., Xiang C. F., Catal. Lett., 2015, 144, 1Google Scholar
  7. [7]
    Liu Y. F., Liu B. L., Zhou Q. F., Zhang T. Y., Wu W. B., Chem. Res. Chinese Universities, 2017, 33(6), 971Google Scholar
  8. [8]
    Sang R., Cheng X., Li W. J., Luo P. F., Zhang Y., Nie R. F., Hai L., Wu Y., Chem. Res. Chinese Universities, 2017, 33(5), 811CrossRefGoogle Scholar
  9. [9]
    Hiroko O., Michael R. M., Heng S., David G. B., Daniela F., Robert J. D., Pradeep K. A., Christopher W. J., Catal. Lett., 2014, 144, 825CrossRefGoogle Scholar
  10. [10]
    Pisduangdawa S., Mekasuwandumrong O, Fujita S. I, Arai M., Yo-shida H., Panpranot J., Catal. Commun., 2015, 61, 11CrossRefGoogle Scholar
  11. [11]
    Diao W. J., Tengco J. M. M., Regalbuto J. R., Monnier J. R., ACS Catal., 2015, 5, 5123CrossRefGoogle Scholar
  12. [12]
    Ma J., Huang X., Liao X. P., Shi B., J. Mol. Catal. A: Chem., 2013, 366, 8CrossRefGoogle Scholar
  13. [13]
    Huang X., Li L., Liao X. P., Shi B., J. Mol. Catal. A: Chem., 2010, 320, 40CrossRefGoogle Scholar
  14. [14]
    Mao H., Chen C., Liao X. P., Shi B., J. Mol. Catal. A: Chem., 2011, 341, 51CrossRefGoogle Scholar
  15. [15]
    Dong C. J., Liu X., Xiao X. C., Chen G., Wang Y. D., Djerdj I. J., Mater. Chem. A, 2014, 2, 20089CrossRefGoogle Scholar
  16. [16]
    Gunasooriya G. T. K. K., Bavel A. P. V., Kuipers H. P. C. E., Saeys M., Surf. Sci., 2015, 642, 6CrossRefGoogle Scholar
  17. [17]
    Rong Z. M., Sun Z. H., Wang Y, Lv J. K., Wang Y., Catal. Lett., 2014, 144, 980CrossRefGoogle Scholar

Copyright information

© Jilin University, The Editorial Department of Chemical Research in Chinese Universities and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Department of Scientific ResearchSichuan Normal UniversityChengduP. R. China
  2. 2.College of Chemistry and Materials ScienceSichuan Normal UniversityChengduP. R. China
  3. 3.Engineering Research Center for the Development of Farmland Ecosystem Service FunctionsSichuan Province Institutions of Higher EducationChengduP. R. China

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