Abstract
A Ni/TiO2(TBT) catalyst was prepared through in situ precipitation, using tetrabutyl titanate(TBT) as the TiO2 precursor, and was studied in CO methanation. A Ni catalyst supported on commercial TiO2 was also prepared through post precipitation and studied to compare the influence of Ni precipitation conditions on the catalyst’s performance. To gain insight on their structure and physicochemical properties, the catalysts were characterized with N2-adsorption, X-ray diffraction, transimission electron microscopy, H2 temperature programmed reduction and temperature programmed desorption. The results showed that the in situ precipitation method was beneficial to the dispersion of Ni and the formation of more active sites on the Ni/TiO2 catalyst. In addition, the density of the metal- support boundary and its interaction with the active component were also increased. These characteristics of Ni/TiO2(TBT) led to a lower light-off temperature and a suppression of Ni sintering during CO methanation. As a consequence, the Ni/TiO2(TBT) exhibited better catalytic behavior, with a CO conversion of 99.4% and CH4 selectiv-ity of 90.4% under the following conditions: p=1 MPa, t=320 °C, n(H2)/n(CO)=3, gas hour space velocity (GHSV)=2×104 mL·g–1·h–1. The life test results of the two catalysts showed that Ni/TiO2(TBT) was more stable and the catalytic activity remained at its initial level after being used for 30 h.
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Jin Y. L., Mcgregor J., Sederman A. J., Dennis J. S., Chem. Eng. Sci., 2016, 152, 754
Bian Z., Meng X., Tao M., Lv Y. H., Xin Z., Fuel, 2016, 179, 193
Li Y., Zhang Q., Chai R., Zhao G., Cao F., Ye L., Yong L., Appl. Catal. A: Gen., 2016, 510, 216
Zhang J., Zhong X., Xin M., Miao T., Fuel, 2013, 109(7), 693
Wang S. R., Wang H. X., Yin Q. Q., Zhu L. Z., Yin S., New J. Chem., 2014, 38(9), 4471
Zhu L., Yin S., Yin Q., Wang H., Wang S., Energy Sci. Eng., 2015, 3(2), 126
Djinovic P., Galletti C., Specchia V., Top. Catal., 2011, 54(16), 1042
Kimura M., Miyao T., Komori S., Chen A., Higashiyama K., Yama-shita H., Watanabe M., Appl. Catal. A: Gen., 2010, 379(1), 182
Panagiotopoulou P., Kondarides D. I., Verykios X. E., Catal. Today, 2012, 181(1), 138
Galletti C., Specchia S., Saracco G., Specchia V., Chem. Eng. Sci., 2010, 65(1), 590
Panagiotopoulou P., Kondarides D. I., Verykios X. E., Appl. Catal. B: Environ., 2009, 88(3/4), 470
Wang G., Gao Y., Wang W., Huang W., Chinese J. Chem. Phy., 2012, 25(4), 475
Wang W., Wang S., Ma X., Gong J., Chem. Soc. Rev., 2011, 40(7), 3703
Kowalczyk Z., Stolecki K., Raróg-Pilecka W., Miskiewicz E., Wilczkowska E., Karpinski Z., Appl. Catal. A: Gen., 2008, 342(1/2), 35
Ji K. M., Meng F. H., Gao Y., Li Z., Chem. J. Chinese Universities, 2016, 37(1), 134
Czekaj I., Loviat F., Raimondi F., Wambach J., Biollaz S., Wokaun A., Appl. Catal. A: Gen., 2007, 329(10), 68
Hu D., Gao J., Ping Y., Jia L., Gunawan P., Zhong Z., Xu G., Gu F., Su F., Ind. Eng. Chem. Res., 2012, 51(13), 4875
Tada S., Shimizu T., Kameyama H., Haneda T., Kikuchi R., Int. J. Hydrogen Energy, 2012, 37(7), 5527
Aziz M. A. A., Jalil A. A., Triwahyono S., Mukti R. R., Taufiq-Yap Y. H., Sazegar M. R., Appl. Catal. B: Environ., 2014, 147(7), 359
Struis R. P. W. J., Schildhauer T. J., Czekaj I., Janousch M., Biollaz S. M. A., Ludwig C., Appl. Catal. A: Gen., 2009, 362(1/2), 121
Andersson M. P., Abild-Pedersen F., Remediakis I. N., Bligaard T., Jones G., Engbæk J., Lytken O., Horch S., Nielsen J. H., Sehested J., J. Catal., 2008, 255(1), 6
Das R., Gupta A., Kumar D., Oh S. H., Pennycook S. J., Hebard A. F., J. Phys-Condens Mat., 2008, 20(38), 385213
Guo C., Wu Y., Qin H., Zhang J., Fuel Process. Technol., 2014, 124, 61
Erdöhelyi A., Pásztor M., Solymosi F., J. Catal., 1986, 98(1), 166
Urasaki K., Tanpo Y., Nagashima Y., Kikuchi R., Satokawa S., Appl. Catal. A: Gen., 2013, 452, 174
Shinde V. M., Madras G., AICHE J., 2014, 60(3), 1027
Lin X., Lin L., Huang K., Chen X., Dai W., Fu X., Appl. Catal. B: Environ., 2015, 168/169, 416
Liang H. O., Bai J., Yu D. D., Zhang Q. Y., Li C. P., Chem. J. Chinese Universities, 2017, 38(6), 947
Yan X., Liu Y., Zhao B., Wang Z., Wang Y., Liu C. J., Int. J. Hydro-gen Energy, 2013, 38(5), 2283
Ho S. W., Chu C. Y., Chen S. G., J. Catal., 1998, 178(1), 34
Seo J. G., Min H. Y., Song I. K., J. Molecul. Catal. A: Chem., 2007, 268(1/2), 9
Liu J., Li C., Wang F., He S., Chen H., Zhao Y., Wei M., Evans D. G., Duan X., Catal. Sci. Technol., 2013, 3(10), 2627
Loc L. C., Tuan N. M., Dung N. K., Phuc N. H. H., Thoang H. S., J. Clin. Microbiol., 2008, 29(3), 573
Jia C., Gao J., Li J., Gu F., Xu G., Zhong Z., Su F., Catal. Sci. Tech-nol., 2013, 3(2), 490
Guo H., Zhao X., Huilin Guo A., Zhao Q., Langmuir, 2008, 19(23), 9799
Wang Y., Ren J., Wang Y., Zhang F., Liu X., Guo Y., Lu G., J. Phy. Chem. C, 2014, 112(39), 15293
Zhu Y., Zhang S., Ye Y., Zhang X., Wang L., Zhu W., Cheng F., Tao F., ACS Catal., 2012, 2(2), 2403
Cunha E. V., Faccin F., Moro C. C., De Castro S. C., Química Nova, 2002, 25(3), 392
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Supported by the National Natural Science Foundation of China(No.51661145011), the National Science and Technology Supporting Plan, China(No.2015BAD15B06), the Foundation of the State Key Laboratory of Clean Energy Utilization, China(No. ZJUCEU2016001).
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Yin, S., Zhu, L., Liu, Y. et al. Effect of Ni Precipitation Method on CO Methanation over Ni/TiO2 Catalysts. Chem. Res. Chin. Univ. 34, 296–301 (2018). https://doi.org/10.1007/s40242-018-7205-3
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DOI: https://doi.org/10.1007/s40242-018-7205-3