Abstract
In this work, silicon@reduced graphene oxide/pyrolytic carbon nanofibers (Si@RGO/C NFs) composite with double modified layer is prepared through electrospinning, stabilization and carbonization. In this composite, polyethylene oxide–polypropylene oxide–polyethylene oxide (P123, a non-ionic surfactant) is introduced as the dispersant, which can make silicon nanoparticles evenly dispersed in electrospinning solution to prevent it from agglomeration. Graphene modified layer can buffer the volumetric expansion of silicon nanoparticles, prevent direct contact between silicon and electrolyte as well as enhance the electrical conductivity. Moreover, carbon fibers synthesized by electrospinning can encapsulate silicon@graphene composite internally to form a double modified layer. This composite with double modified layer can further alleviate the volume change of silicon nanoparticles and avoid direct contact between silicon and electrolyte to form a stable interface. Owing to the above-mentioned merits, the Si@RGO/C NFs composite exhibits excellent cyclic stability and superior rate performance. Particularly, it maintains a specific capacity of 929 mA h g−1 with the retention ratio of 83.1% after 100 cycles at 0.5 A g−1 and delivers an outstanding rate capability of 1003 mA h g−1 at 2 A g−1.
Similar content being viewed by others
References
A.R. Dehghani-Sanij, E. Tharumalingam, M. Dusseault, R. Fraser, Renew. Sustain. Energy Rev. 104, 192 (2019)
S. Yun, Y. Zhang, Q. Xu, J. Liu, Y. Qin, Nano Energy 60, 600 (2019)
K. Liu, K. Li, Q. Peng, C. Zhang, Front. Mech. Eng. 14, 47 (2019)
W. Pan, W. Peng, G. Yan, H. Guo, Z. Wang, X. Li, W. Gui, J. Wang, Energy Technol. 6, 2139 (2018)
Y. Lu, X. Hou, L. Miao, L. Li, R. Shi, L. Liu, J. Chen, Angew. Chem. Int. Ed. 58, 7020 (2019)
G. Chen, J. An, Y. Meng, C. Yuan, B. Matthews, F. Dou, L. Shi, Y. Zhou, P. Song, G. Wu, Nano Energy 57, 157 (2019)
F.A. Susai, D. Kovacheva, A. Chakraborty, T. Kravchuk, R. Ravikumar, M. Talianker, J. Grinblat, L. Burstein, Y. Kauffmann, D.T. Major, ACS Appl. Energy Mater. 2, 4521 (2019)
X. Yang, Y.Y. Wang, B.H. Hou, H.J. Liang, X.X. Zhao, H. Fan, G. Wang, X.L. Wu, Acta Metall. Sin. -Engl. Lett. (2020). https://doi.org/10.1007/s40195-020-01001-7
S. Mohapatra, S.V. Nair, A.K. Rai, Acta Metall. Sin. -Engl. Lett. 31, 164 (2018)
S. Liang, X. Wang, Y. Xia, S. Xia, E. Metwalli, B. Qiu, Q. Ji, S. Yin, S. Xie, K. Fang, L. Zheng, M. Wang, X. Zou, R. Li, Z. Liu, J. Zhu, P.M. Buschbaum, Y. Cheng, Acta Metall. Sin. -Engl. Lett. 31, 910 (2018)
M. Salah, P. Murphy, C. Hall, C. Francis, R. Kerr, M. Fabretto, J. Power Sources 414, 48 (2019)
Y. Ma, H. Tang, Y. Zhang, Z. Li, X. Zhang, Z. Tang, J. Alloys Compd. 704, 599 (2017)
Y. Jin, Y. Tan, X. Hu, B. Zhu, Q. Zheng, Z. Zhang, G. Zhu, Q. Yu, Z. Jin, J. Zhu, ACS Appl. Mater. Interfaces 9, 18 (2017)
S. Chen, Z. Chen, Y. Luo, M. Xia, C. Cao, Nanotechnology 28, 165404 (2017)
M. Ashuri, Q. He, L.L. Shaw, Nanoscale 8, 74 (2016)
A. Casimir, H. Zhang, O. Ogoke, J.C. Amine, J. Lu, G. Wu, Nano Energy 27, 359 (2016)
H. Liu, Z. Shan, W. Huang, D. Wang, Z. Lin, Z. Cao, P. Chen, S. Meng, L. Chen, ACS Appl. Mater. Interfaces 10, 4715 (2018)
M. Wang, G. Wang, S. Wang, J. Zhang, J. Wang, W. Zhong, F. Tang, Z. Yang, J. Zheng, X. Li, Chem. Eng. J. 356, 895 (2019)
G.N. Yushin, I. Luzinov, B. Zdyrko, A. Magasinski, U.S. Patent No. 10,283,759, 7 May 2019
H. Cho, K. Kim, C.M. Park, G. Jeong, J. Power Sources 410, 25 (2019)
P. Li, J. Hwang, Y. Sun, ACS Nano 13, 2624 (2019)
F. Wang, Z. Hu, L. Mao, J. Mao, J. Power Sources 450, 227692 (2020)
W. Tao, P. Wang, Y. You, K. Park, C. Wang, Y. Li, F. Cao, S. Xin, Nano Res. 12, 1739 (2019)
W. Wang, Y. Liang, Y. Kang, L. Liu, Z. Xu, X. Tian, W. Mai, H. Fu, H. Lv, K. Teng, Mater. Chem. Phys. 223, 762 (2019)
C. Lv, J. Yang, Y. Peng, X. Duan, J. Ma, Q. Li, T. Wang, Electrochim. Acta 297, 258 (2019)
K. Javed, M. Oolo, N. Savest, A. Krumme, Crit. Rev. Solid State Mater. Sci. 44, 427 (2019)
J. Xue, T. Wu, Y. Dai, Y. Xia, Chem. Rev. 119, 5298 (2019)
L. Zhang, S. Gbewonyo, A. Aboagye, A.D. Kelkar, (William Andrew Publishing, 2019), pp. 867–878
O. Pech, S. Maensiri, J. Alloys Compd. 781, 541 (2019)
L. Ji, X. Zhang, Energy Environ. Sci. 3, 124 (2010)
M. Wang, W. Song, J. Wang, L. Fan, Carbon 82, 337 (2015)
H. Tao, L. Fan, Y. Mei, X. Qu, Electrochem. Commun. 13, 1332 (2011)
C. Wu, M. Lu, H. Chuang, Polymer 46, 5929 (2005)
Z. Wu, J. Yang, B. Yu, B. Shi, C. Zhao, Z. Yu, Rare Met. 38, 832 (2019)
I. Kovalenko, B. Zdyrko, A. Magasinski, B. Hertzberg, Z. Milicev, R. Burtovyy, I. Luzinov, G. Yushin, Science 334, 75 (2007)
Acknowledgements
This work was financially supported by the National Natural Science Foundation of China (No. 51974370), the Program of Huxiang Young Talents (No. 2019RS2002), the Innovation-Driven Project of Central South University (No. 2020CX027), and the Central Universities of Central South University (No. 2018zzts436).
Author information
Authors and Affiliations
Corresponding author
Additional information
Available online at http://link.springer.com/journal/40195.
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Yan, Y., Guo, H., Wang, Z. et al. Electrospinning-Enabled Si/C Nanofibers with Dual Modification as Anode Materials for High-Performance Lithium-Ion Batteries. Acta Metall. Sin. (Engl. Lett.) 34, 329–336 (2021). https://doi.org/10.1007/s40195-020-01087-z
Received:
Revised:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s40195-020-01087-z