Journal of Advanced Ceramics

, Volume 7, Issue 2, pp 178–183 | Cite as

Synthesis and formation mechanism of titanium lead carbide

  • C. Ling
  • W. B. Tian
  • P. Zhang
  • W. Zheng
  • Y. M. Zhang
  • Z. M. Sun
Open Access
Research Article


Ti2PbC was synthesized for the first time by pressureless reaction synthesis using Ti/Pb/TiC as starting materials at a heating rate of 2 °C/min and holding at 1370 °C for 2 h in a tube furnace protected by Ar atmosphere. The effects of starting powders, heating rates, and holding temperatures on the formation of Ti2PbC were investigated. It was found that elementary mixture of Ti/Pb/C or higher heating rates fail to form Ti2PbC. The decreased lattice parameters in the synthesized Ti2PbC indicated the existence of Pb vacancies in the compound. A reaction mechanism was proposed to explain the formation of Ti2PbC.


Ti2PbC MAX phase differential scanning calorimetry (DSC) thermal stability 



This research is supported by the grants from National Natural Science Foundation (Nos. 51731004, 51501038, and 51671054) and the Fundamental Research Funds for the Central Universities in China.


  1. [1]
    Sun ZM. Progress in research and development on MAX phases: A family of layered ternary compounds. Int Mater Rev 2011, 56: 143–166.CrossRefGoogle Scholar
  2. [2]
    Barsoum MW. The MN+1AXN phases: A new class of solids: Thermodynamically stable nanolaminates. Prog Solid State Ch 2000, 28: 201–281.CrossRefGoogle Scholar
  3. [3]
    Xu L, Zhu D, Grasso S, et al. Effect of texture microstructure on tribological properties of tailored Ti3AlC2 ceramic. J Adv Ceram 2017, 6: 120–128.CrossRefGoogle Scholar
  4. [4]
    Arrôyave R, Talapatra A, Duong T, et al. Does aluminum play well with others? Intrinsic Al-A alloying behavior in 211/312 MAX phases. Mater Res Lett 2017, 5: 170–178.Google Scholar
  5. [5]
    Lara-Curzio E, An K, Kiggans Jr. JO, et al. Lightweight, durable lead-acid batteries. U.S. Patent 8,017,273. 2011.Google Scholar
  6. [6]
    Sun ZM, Barsoum MW. Spontaneous room temperature extrusion of Pb nano-whiskers from leaded brass surfaces. J Mater Res 2005, 20: 1087–1089.CrossRefGoogle Scholar
  7. [7]
    Zhang P, Zhang Y, Sun Z. Spontaneous growth of metal whiskers on surfaces of solids: A review. J Mater Sci Technol 2015, 31: 675–698.CrossRefGoogle Scholar
  8. [8]
    Liu B, Wang JY, Zhang J, et al. Theoretical investigation of A-element atom diffusion in Ti2AC (A = Sn, Ga, Cd, In, and Pb). Appl Phys Lett 2009, 94: 181906.CrossRefGoogle Scholar
  9. [9]
    Zheng W, Sun Z, Zhang P, et al. Research progress on MXene, two dimensional nano-materials. Mater Rev 2017, 31: 1–14.Google Scholar
  10. [10]
    Jeitschko W, Nowotny H, Benesovsky F. Die H-Phasen Ti2TlC, Ti2PbC, Nb2InC, Nb2SnC und Ta2GaC. Monatshefte für Chemie 1964, 95: 431–435.CrossRefGoogle Scholar
  11. [11]
    Wang X, Zhou Y. Solid-liquid reaction synthesis of layered machinable TijAlC2 ceramic. J Mater Chem 2002, 12: 455–460.CrossRefGoogle Scholar
  12. [12]
    Guan C, Sun N. Synthesis of high-purity Ti2SC powder by microwave hybrid heating. J Adv Ceram 2016, 5: 337–343.CrossRefGoogle Scholar
  13. [13]
    Sun Z, Zhou Y. Fluctuation synthesis and characterization of Ti3SiC2 powders. Mat Res Innovat 1999, 2: 227–231.CrossRefGoogle Scholar
  14. [14]
    Riley DP, Kisi EH, Wu E, et al. Self-propagating high-temperature synthesis of Ti3SiC2 from 3Ti+SiC+C reactants. J Mater Sci Lett 2003, 22: 1101–1104.CrossRefGoogle Scholar
  15. [15]
    Li S-B, Bei G-P, Zhai H-X, et al. Synthesis of Ti2SnC from Ti/Sn/TiC powder mixtures by pressureless sintering technique. Mater Lett 2006, 60: 3530–3532.CrossRefGoogle Scholar
  16. [16]
    Li S, Xiang W, Zhai H, et al. Formation of a single-phase Ti3AlC2 from a mixture of Ti, Al and TiC powders with Sn as an additive. Mater Res Bull 2008, 43: 2092–2099.CrossRefGoogle Scholar
  17. [17]
    Hashimoto S, Takeuchi M, Inoue K, et al. Pressureless sintering and mechanical properties of titanium aluminum carbide. Mater Lett 2008, 62: 1480–1483.CrossRefGoogle Scholar
  18. [18]
    Li J-F, Matsuki T, Watanabe R. Combustion reaction during mechanical alloying synthesis of Ti3SiC2 ceramics from 3Ti/Si/2C powder mixture. J Am Ceram Soc 2005, 88: 1318–1320.CrossRefGoogle Scholar
  19. [19]
    Ge Z, Chen K, Guo J, et al. Combustion synthesis of ternary carbide Ti3AlC2 in Ti-Al-C system. J Eur Ceram Soc 2003, 23: 567–574.CrossRefGoogle Scholar
  20. [20]
    Ji B, Fang P. Study on the mechanism of strengthening titanium alloys with plumbum. Vacuum 2003, 1: 40–41. (in Chinese)Google Scholar
  21. [21]
    Guo Q, Wang G, Guo G. Common Non-Ferrous Metal Phase Diagram Atlas ofF Binary Alloy. Chem Ind Press, 2010. (in Chinese)Google Scholar
  22. [22]
    Hartman P, Perdok WG. On the relations between structure and morphology of crystals. II. Acta Cryst 1955, 8: 521–524.CrossRefGoogle Scholar
  23. [23]
    Liu Y, Zhang P, Ling C, et al. Spontaneous Sn whisker formation on Ti2SnC. J Mater Sci: Mater Electron 2017, 28: 5788–5795.Google Scholar
  24. [24]
    El-Raghy T, Chakraborty S, Barsoum MW. Synthesis and characterization of Hf2PbC, Zr2PbC and M2SnC (M = Ti, Hf, Nb or Zr). J Eur Ceram Soc 2000, 20: 2619–2625.CrossRefGoogle Scholar
  25. [25]
    Barsoum MW, El-Raghy T, Farber L, et al. The topotactic transformation of Ti3SiC2 into a partially ordered cubic Ti(C0.67Si0.06) phase by the diffusion of Si into molten cryolite. JElectrochem Soc 1999, 146: 3919–3923.CrossRefGoogle Scholar
  26. [26]
    El-Raghy T, Barsoum MW, Sika M. Reaction of Al with Ti3SiC2 in the 800–1000 °C temperature range. Mat Sci Eng A 2001, 298: 174–178.CrossRefGoogle Scholar
  27. [27]
    Aldica G, Khodash V, Badika P, et al. Electrical conduction in initial field assisted sintering stages. Journal of Optoelectronics and Advanced Materials 2007, 9: 3863–3870.Google Scholar
  28. [28]
    Li S-B, Zhai H-X, Bei G-P, et al. Synthesis and microstructure of Ti3AlC2 by mechanically activated sintering of elemental powders. Ceram Int 2007, 33: 169–173.CrossRefGoogle Scholar
  29. [29]
    Sun D, Zhou A, Li Z, et al. Corrosion behavior of Ti3AlC2 in molten KOH at 700 °C. J Adv Ceram 2013, 2: 313–317.CrossRefGoogle Scholar

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© The Author(s) 2018

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Authors and Affiliations

  1. 1.Jiangsu Key Laboratory of Advanced Metallic Materials, School of Materials Science and EngineeringSoutheast UniversityNanjingChina
  2. 2.Jiangsu Key Laboratory of Construction Materials, School of Materials Science and EngineeringSoutheast UniversityNanjingChina

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