Persistent organic pollutants in tropical coastal and offshore environment: part A—atmospheric polycyclic aromatic hydrocarbons

  • I.-C. Lai
  • C.-L. Lee
  • F.-C. Ko
  • J.-C. Lin
  • H.-C. Huang
Original Paper


Air samples were collected at four sites from August 2009 to May 2010. Temporal variation of polycyclic aromatic hydrocarbon (PAH) concentrations showed the highest concentration in November and the lowest in May, except for one case attributable to a specific meteorological event, a typhoon, which resulted in a dramatic increase in PAHs concentrations. PAH compositional pattern, diagnostic ratios, hierarchical cluster analysis, and principal component analysis indicated that the major sources of PAHs in the Gaoping coastal area were local vehicle emissions, stationary sources, and coal/wood combustion. In addition, the distinct compositional patterns at each sampling site suggested that sources of PAHs varied with sampling periods. Back trajectory analysis indicated that transport pathway and moving speed of air parcels were two important factors that influence temporal and spatial variation of PAH concentrations. Air parcel pathways and PAH compositional patterns also indicated that PAHs observed at an offshore island (Liu-Chiu Isle) in November were affected by sources in the southwest coastal area of Taiwan. The data set of PAH concentrations built in this study provides useful information to estimate air–water exchange behavior of PAHs and to investigate the fate of PAHs in the Gaoping coastal area.


Seasonal variation Source identification Back trajectory analysis Air parcel pathway 



The authors acknowledge financial support from the National Science Council and the Ministry of Education of Taiwan R. O. C., under contract Number NSC 98-2011-M-110-008 and DOE 98C030219. We also appreciate the US NOAA Air Resources Laboratory that provided the online HYSPLIT model used in the publication.

Supplementary material

13762_2013_482_MOESM1_ESM.doc (375 kb)
Supplementary material 1 (DOC 375 kb)


  1. Agrell C, Larsson P, Okla L, Agrell J (2002) PCB congeners in precipitation, wash out ratios and depositional fluxes within the Baltic Sea region, Europe. Atmos Environ 36:371–383CrossRefGoogle Scholar
  2. Castro-Jiménez J, Mariani G, Vives I, Skejo H, Umlauf G, Zaldívar JM, Dueri S, Messiaen G, Laugier T (2011) Atmospheric concentrations, occurrence and deposition of persistent organic pollutants (POPs) in a Mediterranean coastal site (Etang de Thau, France). Environ Pollut 159:1948–1956CrossRefGoogle Scholar
  3. Central Weather Bureau Taiwan (2012) Accessed 12 Aug 2012
  4. Draxler RR, Hess GD (1997) Description of the HYSPLIT_4 modeling system. NOAA Technical Memorandum ERL ARL-224, NOAA Air Resources Laboratory, MDGoogle Scholar
  5. Draxler RR, Hess GD (1998) An overview of the HYSPLIT_4 modeling system of trajectories, dispersion, and deposition. Aust Meteorol Mag 47:295–308Google Scholar
  6. Dutton JA (1976) Aperiodic trajectories and stationary points in a three-component spectral model of atmospheric flow. J Atmos Sci 33:1499–1504CrossRefGoogle Scholar
  7. Fang M-D, Ko F-C, Baker JE, Lee C-L (2008) Seasonality of diffusive exchange of polychlorinated biphenyls and hexachlorobenzene across the air–sea interface of Kaohsiung Harbor, Taiwan. Sci Total Environ 407:548–565CrossRefGoogle Scholar
  8. Fang M-D, Lee C-L, Jiang J-J, Ko F-C, Baker JE (2012) Diffusive exchange of PAHs across the air–water interface of the Kaohsiung Harbor lagoon, Taiwan. J Environ Manag 110:179–187CrossRefGoogle Scholar
  9. Gigliotti CL, Totten LA, Offenberg JH, Dachs J, Reinfelder JR, Nelson ED, Glenn IV TR, Eisenreich SJ (2005) Atmospheric concentrations and deposition of polycyclic aromatic hydrocarbons to the Mid-Atlantic East Coast region. Environ Sci Technol 39:5550–5559Google Scholar
  10. Halsall CJ, Sweetman AJ, Barrie LA, Jones KC (2001) Modelling the behaviour of PAHs during atmospheric transport from the UK to the Arctic. Atmos Environ 35:255–267CrossRefGoogle Scholar
  11. Halse AK, Schlabach M, Eckhardt S, Sweetman A, Jones KC, Breivik K (2011) Spatial variability of POPs in European background air. Atmos Chem Phys 11:1547–1564CrossRefGoogle Scholar
  12. Harrison RM, Smith DJT, Luhana L (1996) Source apportionment of atmospheric polycyclic aromatic hydrocarbons collected from an urban location in Birmingham, U.K. Environ Sci Technol 30:825–832CrossRefGoogle Scholar
  13. Huang H-C, Lee C-L, Lai C-H, Fang M-D, Lai IC (2012) Transboundary movement of polycyclic aromatic hydrocarbons (PAHs) in the Kuroshio Sphere of the western Pacific Ocean. Atmos Environ 54:470–479CrossRefGoogle Scholar
  14. Irwin RJ, Van Mouwerik M, Stevens L, Seese MD, Basham W (1998) Environmental contaminants encyclopedia. Fort Collins, ColoradoGoogle Scholar
  15. Jurado E, Jaward FM, Lohmann R, Jones KC, Simó R, Dachs J (2004) Atmospheric dry deposition of persistent organic pollutants to the Atlantic and inferences for the global oceans. Environ Sci Technol 38:5505–5513CrossRefGoogle Scholar
  16. Jurado E, Jaward F, Lohmann R, Jones KC, Simó R, Dachs J (2005) Wet deposition of persistent organic pollutants to the global oceans. Environ Sci Technol 39:2426–2435CrossRefGoogle Scholar
  17. Khalili NR, Scheff PA, Holsen TM (1995) PAH source fingerprints for coke ovens, diesel and gasoline engines, highway tunnels, and wood combustion emissions. Atmos Environ 29:533–542CrossRefGoogle Scholar
  18. Lai IC, Lee C-L, Zeng K-Y, Huang H-C (2011) Seasonal variation of atmospheric polycyclic aromatic hydrocarbons along the Kaohsiung coast. J Environ Manag 92:2029–2037CrossRefGoogle Scholar
  19. Lai IC, Chang Y-C, Lee C-L, Chiou G-Y, Huang H-C (2013) Source identification and characterization of atmospheric polycyclic aromatic hydrocarbons along the southwestern coastal area of Taiwan—with a GMDH approach. J Environ Manag 115:60–68CrossRefGoogle Scholar
  20. Larsen RK, Baker JE (2003) Source apportionment of polycyclic aromatic hydrocarbons in the urban atmosphere: a comparison of three methods. Environ Sci Technol 37:1873–1881CrossRefGoogle Scholar
  21. Nielsen T (1996) Traffic contribution of polycyclic aromatic hydrocarbons in the center of a large city. Atmos Environ 30:3481–3490CrossRefGoogle Scholar
  22. Omar NYMJ, Abas MRB, Ketuly KA, Tahir NM (2002) Concentrations of PAHs in atmospheric particles (PM-10) and roadside soil particles collected in Kuala Lumpur, Malaysia. Atmos Environ 36:247–254CrossRefGoogle Scholar
  23. Panther BC, Hooper MA, Tapper NJ (1999) A comparison of air particulate matter and associated polycyclic aromatic hydrocarbons in some tropical and temperate urban environments. Atmos Environ 33:4087–4099CrossRefGoogle Scholar
  24. Park SS, Kim YJ, Kang CH (2002) Atmospheric polycyclic aromatic hydrocarbons in Seoul, Korea. Atmos Environ 36:2917–2924CrossRefGoogle Scholar
  25. Perwak J, Byrne M, Coons S, Goyer M, Harris J, Cruse P, DeRosier R, Moss K, Wendt S (1982) An exposure and risk assessment for benzo[a]pyrene and other polycyclic aromatic hydrocarbons, vol IV. U.S Environmental Protection Agency, Washington, DCGoogle Scholar
  26. Ravindra K, Sokhi R, Van Grieken R (2008) Atmospheric polycyclic aromatic hydrocarbons: source attribution, emission factors and regulation. Atmos Environ 42:2895–2921CrossRefGoogle Scholar
  27. Safe S (1990) Polychlorinated biphenyls (PCBs), dibenzo-p-dioxins (PCDDs), dibenzofurans (PCDFs), and related compounds: environmental and mechanistic considerations which support the development of toxic equivalency factors (TEFs). Crit Rev Toxicol 21:51–88CrossRefGoogle Scholar
  28. Safe S, Hutzinger O (1984) Polychlorinated biphenyls (PCBs) and Polybrominated biphenyls (PBBs): biochemistry, toxicology, and mechanism of action. Crit Rev Toxicol 13:319–395CrossRefGoogle Scholar
  29. UN/ECE/EB.AIR/1998/1 Protocol to the 1979 convention on long-range transboundary air pollution on persistent organic pollutants. Accessed 12 Aug 2012
  30. van Drooge BL, Ballesta PPr (2009) Seasonal and daily source apportionment of polycyclic aromatic hydrocarbon concentrations in PM10 in a semirural European area. Environ Sci Technol 43:7310–7316CrossRefGoogle Scholar
  31. Venkataraman C, Lyons JM, Friedlander SK (1994) Size distributions of polycyclic aromatic hydrocarbons and elemental carbon. 1. Sampling, measurement methods, and source characterization. Environ Sci Technol 28:555–562CrossRefGoogle Scholar
  32. Vreugdenhil HJI, Lanting CI, Mulder PGH, Boersma ER, Weisglas-Kuperus N (2002) Effects of prenatal PCB and dioxin background exposure on cognitive and motor abilities in Dutch children at school age. J Pediatr 140:48–56CrossRefGoogle Scholar
  33. Wania F, MacKay D (1996) Peer reviewed: tracking the distribution of persistent organic pollutants. Environ Sci Technol 30:390A–396ACrossRefGoogle Scholar
  34. Yang Y, Guo P, Zhang Q, Li D, Zhao L, Mu D (2010) Seasonal variation, sources and gas/particle partitioning of polycyclic aromatic hydrocarbons in Guangzhou, China. Sci Total Environ 408:2492–2500CrossRefGoogle Scholar
  35. Yunker MB, Macdonald RW, Vingarzan R, Mitchell RH, Goyette D, Sylvestre S (2002) PAHs in the Fraser River basin: a critical appraisal of PAH ratios as indicators of PAH source and composition. Org Geochem 33:489–515CrossRefGoogle Scholar
  36. Zhou J, Wang T, Huang Y, Mao T, Zhong N (2005) Size distribution of polycyclic aromatic hydrocarbons in urban and suburban sites of Beijing, China. Chemosphere 61:792–799CrossRefGoogle Scholar

Copyright information

© Islamic Azad University (IAU) 2013

Authors and Affiliations

  • I.-C. Lai
    • 1
  • C.-L. Lee
    • 1
    • 2
    • 3
  • F.-C. Ko
    • 4
  • J.-C. Lin
    • 1
  • H.-C. Huang
    • 1
  1. 1.Department of Marine Environment and EngineeringNational Sun Yat-sen UniversityKaohsiungTaiwan
  2. 2.Kuroshio Research Group, Asia-Pacific Ocean Research CenterNational Sun Yat-sen UniversityKaohsiungTaiwan
  3. 3.Center for Emerging Contaminants ResearchNational Sun Yat-sen UniversityKaohsiungTaiwan
  4. 4.Institute of Marine Biodiversity and Evolutionary BiologyNational Dong-Hwa UniversityPingtungTaiwan

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