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Mild and highly efficient method for the oxidation of sulfides and oxidative coupling of thiols catalyzed by Fe3O4@MCM-41@VO-SPATB as efficient and magnetically recoverable nanocatalyst

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Abstract

The use of oxo vanadium complex with s-propyl-2-aminobenzothioate ligand immobilized onto functionalized magnetic nanoporous MCM-41(Fe3O4@MCM-41@VO-SPATB) as efficient and magnetically recoverable nanocatalyst for oxidation of sulfides into sulfoxides and oxidative coupling of thiols into disulfides using H2O2 as green oxidant is presented. This method provides much improved modification of oxidation reactions in terms of mild reaction conditions, short reaction time and good-to-excellent yields of products. Another important feature of this method is the ability to reuse the magnetite nanocatalyst for several times with no loss of its catalytic activity.

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Acknowledgements

The authors gratefully acknowledge Ilam University Research Council for partial financial support of this research project.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Ilam University, Ilam, P. O. Box 69315516, Iran

    Mohsen Nikoorazm, Arash Ghorbani-Choghamarani & Zahra Erfani

  2. Department of Environment, Faculty of Natural Resource, University of Kurdistan, Sanandaj, 66177-15177, Iran

    Farshid Ghorbani

Authors
  1. Mohsen Nikoorazm
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  2. Farshid Ghorbani
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  3. Arash Ghorbani-Choghamarani
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  4. Zahra Erfani
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Correspondence to Mohsen Nikoorazm.

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Nikoorazm, M., Ghorbani, F., Ghorbani-Choghamarani, A. et al. Mild and highly efficient method for the oxidation of sulfides and oxidative coupling of thiols catalyzed by Fe3O4@MCM-41@VO-SPATB as efficient and magnetically recoverable nanocatalyst. J IRAN CHEM SOC 16, 553–562 (2019). https://doi.org/10.1007/s13738-018-1536-3

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