Journal of the Iranian Chemical Society

, Volume 15, Issue 8, pp 1699–1708 | Cite as

Synthesis, characterization and H2 adsorption performances of polymeric Co(II) and Ni(II) complexes of pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole

  • Omer Andac
  • Semih Gorduk
  • Hakan Yilmaz
Original Paper


We studied the synthesis and characterization of polymeric coordination complexes of Co(II) and Ni(II) ions with pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole. The e lemental analysis, infrared spectroscopy, powder X-ray diffraction, magnetic susceptibility, thermal analysis and X-ray single crystal techniques were used in the characterization. The X-ray single crystal analysis suggests that the pyrazine-2,3-dicarboxylato ligand acts as a bridging ligand through the oxygen atoms of the carboxylate groups and the nitrogen atoms on the pyrazine ring. The 1-vinylimidazole ligand behaves as a monodentate ligand via the ring nitrogen atom. Further, the H2 adsorption studies were carried out at 75 K for various increasing pressures and the highest H2 adsorption performances for Co(II) and Ni(II) complexes were estimated as 2.66 and 2.99 wt% at 87 bar. The theoretical calculations using the crystal data were also performed to determine the voids in the structure of Co(II) complex.


Pyrazine-2,3-dicarboxylic acid 1-Vinylimidazole Polymeric complex Bridging ligand H2 adsorption 



This study was supported by the Scientific and Technological Research Council of Turkey (TUBITAK) [Project Number: 110T131]. Thanks to Orhan BUYUKGUNGOR, Murat TAS, Selcuk DEMIR and Ramazan SAHIN for their contributions.

Supplementary material

13738_2018_1367_MOESM1_ESM.doc (797 kb)
Supplementary material 1 (DOC 797 kb)


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Copyright information

© Iranian Chemical Society 2018

Authors and Affiliations

  1. 1.Department of Chemistry, Faculty of Arts and ScienceOndokuz Mayis UniversitySamsunTurkey
  2. 2.Department of Chemistry, Faculty of Arts and ScienceYildiz Technical UniversityIstanbulTurkey

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