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Synthesis, characterization and H2 adsorption performances of polymeric Co(II) and Ni(II) complexes of pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole

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Abstract

We studied the synthesis and characterization of polymeric coordination complexes of Co(II) and Ni(II) ions with pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole. The e lemental analysis, infrared spectroscopy, powder X-ray diffraction, magnetic susceptibility, thermal analysis and X-ray single crystal techniques were used in the characterization. The X-ray single crystal analysis suggests that the pyrazine-2,3-dicarboxylato ligand acts as a bridging ligand through the oxygen atoms of the carboxylate groups and the nitrogen atoms on the pyrazine ring. The 1-vinylimidazole ligand behaves as a monodentate ligand via the ring nitrogen atom. Further, the H2 adsorption studies were carried out at 75 K for various increasing pressures and the highest H2 adsorption performances for Co(II) and Ni(II) complexes were estimated as 2.66 and 2.99 wt% at 87 bar. The theoretical calculations using the crystal data were also performed to determine the voids in the structure of Co(II) complex.

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Acknowledgements

This study was supported by the Scientific and Technological Research Council of Turkey (TUBITAK) [Project Number: 110T131]. Thanks to Orhan BUYUKGUNGOR, Murat TAS, Selcuk DEMIR and Ramazan SAHIN for their contributions.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Arts and Science, Ondokuz Mayis University, 55139, Samsun, Turkey

    Omer Andac & Hakan Yilmaz

  2. Department of Chemistry, Faculty of Arts and Science, Yildiz Technical University, 34210, Istanbul, Turkey

    Semih Gorduk

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  1. Omer Andac
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  2. Semih Gorduk
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  3. Hakan Yilmaz
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Correspondence to Semih Gorduk or Hakan Yilmaz.

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Andac, O., Gorduk, S. & Yilmaz, H. Synthesis, characterization and H2 adsorption performances of polymeric Co(II) and Ni(II) complexes of pyrazine-2,3-dicarboxylic acid and 1-vinylimidazole. J IRAN CHEM SOC 15, 1699–1708 (2018). https://doi.org/10.1007/s13738-018-1367-2

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