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Determination of Congo red in food samples by methyl-β-cyclodextrin/Triton X-100 synergistic sensitized fluorescence quenching method of the derivatives of calix[4]arene

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Abstract

A novel fluorescent chemosensor of the derivatives of calix[4]arene (SAX) for Congo red (CR) in methyl-β-cyclodextrin/Triton X-100 synergistic sensitized system was developed. The results showed that the fluorescence intensity of SAX could be quenched by CR, and the fluorescence quenching (∆F = FSAX − FCR-SAX) was synergistic sensitized by methyl-β-CD and Triton X-100. Under the conditions of λex/em = 332/468 nm and pH 7.5, the linear range and the detection limit for CR were found to be 0.040–8.0 μg/mL and 8.9 ng/mL, respectively. The mechanism of determination was discussed by quenching type analysis and sensitizing effect. This method has also been applied for the determination of CR in beef samples with satisfactory results.

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References

  1. R.E. Baynes, N.A. Monteiro-Riviere, G.L. Qiao, Toxicol. Lett. 93, 159 (1997)

    Article  CAS  PubMed  Google Scholar 

  2. J.L.E. Gray, J.S. Ostby, R.J. Kavlock, Fundam. Appl. Toxicol. 19, 411 (1992)

    Article  CAS  PubMed  Google Scholar 

  3. C.P. Zhong, W. Wei, Z.H. Wang, Food Sci. 35, 195 (2014)

    CAS  Google Scholar 

  4. H. Lin, C.X. Xu, C.R. Yan, Chin. J. Chromatogr. 31, 914 (2013)

    Article  CAS  Google Scholar 

  5. X.X. Qin, A. Bakheet, X.S. Zhu, J. Iran. Chem. Soc. 14, 2017 (2017)

    Article  CAS  Google Scholar 

  6. O. Sahin, M. Yilmaz, Tetrahedron Lett. 53, 2319 (2012)

    Article  CAS  Google Scholar 

  7. B. Gao, Y.Q. Feng, L.S. Zhou, Chin. J. Org. Chem. 24, 713 (2004)

    Google Scholar 

  8. X.Y. Li, M. Li, Q.F. Chen, Food Sci. 32, 238 (2011)

    CAS  Google Scholar 

  9. W.J. Wang, X.S. Zhu, C.G. Yan, Food Chem. 141, 2207 (2013)

    Article  CAS  PubMed  Google Scholar 

  10. G.F. Zhang, J.Y. Zhan, H.B. Li, Org. Lett. 13, 3392 (2011)

    Article  CAS  PubMed  Google Scholar 

  11. L.N. Ma, X.S. Zhu, Spectrochim. Acta Part A 95, 246 (2012)

    Article  CAS  Google Scholar 

  12. N.M. Feng, H.Y. Zhao, J.Y. Zhan, Org. Lett. 14, 1958 (2012)

    Article  CAS  PubMed  Google Scholar 

  13. Q. Yang, C.G. Yan, X.S. Zhu, Sens. Actuators B 191, 53 (2014)

    Article  CAS  Google Scholar 

  14. Q. Yang, X.X. Qin, C.G. Yan, X.S. Zhu, Sens. Actuators B 212, 183 (2015)

    Article  CAS  Google Scholar 

  15. X.F. Zeng, J.K. Ma, L. Luo, Org. Lett. 17, 2976 (2015)

    Article  CAS  PubMed  Google Scholar 

  16. R. Kips, A.J. Pidduck, M.R. Houlton, A. Leenaers, J.D. Mace, O. Marie, F. Pointurier, E.A. Stefaniak, P.D.P. Taylor, S. Van den Berghe, P. Van Espen, R. Van Grieken, R. Wellum, Spectrochim. Acta Part B 64, 199 (2009)

    Article  CAS  Google Scholar 

  17. M. Kodama, S. Miyagawa, Anal. Chem. 52, 2358 (1980)

    Article  CAS  Google Scholar 

  18. B. Samiey, C.H. Cheng, J. Wu, J. Chem. 2014, 14 (2014)

    Article  CAS  Google Scholar 

  19. R. Guo, X.S. Zhu, Chem. J. Chin. U 8, 508 (1987)

    CAS  Google Scholar 

  20. X.S. Zhu, L. Bao, R. Guo, Anal. Chim. Acta 523, 43 (2004)

    Article  CAS  Google Scholar 

  21. A.Q. Gong, X.S. Zhu, J. Fluoresc. 23, 1279 (2013)

    Article  CAS  PubMed  Google Scholar 

  22. J. Sun, X.S. Zhu, M. Wu, J. Fluoresc. 17, 265 (2007)

    Article  CAS  PubMed  Google Scholar 

  23. Z.T. Jiang, Y.X. Guo, R. Li, Food Anal. Methods 3, 47 (2010)

    Article  Google Scholar 

  24. F. Liu, G.P. Zhao, Chem. Res. Appl. 20, 611 (2008)

    CAS  Google Scholar 

  25. P. Berton, E.M. Martinis, Anal. Chim. Acta 640, 40 (2009)

    Article  CAS  PubMed  Google Scholar 

  26. E.M. Martinis, R.A. Olsina, Anal. Chim. Acta 628, 41 (2008)

    Article  CAS  Google Scholar 

  27. X.S. Zhu, L.N. Ma, J. Fluoresc. 21, 321 (2011)

    Article  CAS  PubMed  Google Scholar 

  28. G. Feng, X.S. Zhu, Chin. J. Spectrosc. Lab. 24, 1059 (2007)

    Google Scholar 

  29. X.S. Zhu, Y.Y. Hu, Anal. Lett. 40, 103 (2007)

    Article  CAS  Google Scholar 

  30. A.Q. Gong, X.S. Zhu, Y.Y. Hu, Talanta 73, 668 (2007)

    Article  CAS  PubMed  Google Scholar 

  31. T.T. Hou, X.S. Zhu, J. Mol. Liq. 166, 17 (2012)

    Article  CAS  Google Scholar 

  32. X.S. Zhu, J. Sun, L. Bao, Chin. J. Appl. Chem. 23, 323 (2006)

    CAS  Google Scholar 

  33. X.S. Zhu, R.R. Jiang, J. Fluoresc. 21, 385 (2011)

    Article  CAS  PubMed  Google Scholar 

  34. Q.Y. Ren, X.S. Zhu, J. Fluoresc. 26, 671 (2016)

    Article  CAS  PubMed  Google Scholar 

  35. X. Bi, J. Sun, C.G. Yan, Chin. J. Chem. 30, 1539 (2012)

    Article  CAS  Google Scholar 

  36. Y. Fu, X. Zeng, L. Mu, Sens. Actuators B 164, 69 (2012)

    Article  CAS  Google Scholar 

  37. K.B. Vimal, P.S.P. Ajay, S. Narinder, Tetrahedron 64, 5384 (2008)

    Article  CAS  Google Scholar 

  38. J. Zhao, Y.J. Wei, Spectrosc. Spect. Anal. 26, 1523 (2006)

    CAS  Google Scholar 

  39. X.S. Zhu, A.Q. Gong, S.H. Yu, Spectrochim. Acta Part A 69, 479 (2008)

    Google Scholar 

  40. S. Deepa, A.K. Mishra, J. Pharm. Biomed. Anal. 38, 556 (2005)

    Article  CAS  PubMed  Google Scholar 

  41. J.R. Lakowicz, G. Weber, Biochemistry 12, 4161 (1973)

    Article  CAS  PubMed  Google Scholar 

Download references

Acknowledgements

The authors acknowledge the financial support from the National Natural Science Foundation of China (21375117) and a project funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions.

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, People’s Republic of China

    Qiuyi Ren, Songqin Chen, Chaoguo Yan & Xiashi Zhu

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  1. Qiuyi Ren
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  2. Songqin Chen
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  3. Chaoguo Yan
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  4. Xiashi Zhu
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Correspondence to Xiashi Zhu.

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Ren, Q., Chen, S., Yan, C. et al. Determination of Congo red in food samples by methyl-β-cyclodextrin/Triton X-100 synergistic sensitized fluorescence quenching method of the derivatives of calix[4]arene. J IRAN CHEM SOC 15, 1551–1559 (2018). https://doi.org/10.1007/s13738-018-1353-8

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