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One-pot synthesized porphyrin-based polymer supported gold nanoparticles as efficient catalysts for alkyne hydration and alcohol oxidation in water

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Abstract

The construction of porous organic polymer from 5,10,15,20-tetraphenylporphyrin (TPP) was described using one-pot Friedel-Crafts alkylation reaction. Au was simultaneously loaded on the porphyrin-based polymer denoted as Au/KAPs(DCM-TPP). This polymer-supported Au was fully characterized by many physicochemical methods. It was found to possess BET surface area of 796 m2 g−1, good thermal stability above 250 °C and Au nanoparticles with an average size of 8 nm. It was used as an efficient heterogeneous catalyst for alkyne hydration and alcohol oxidation in water. This Au catalyst exhibited excellent catalytic efficiency and recycling performance without loss of activity at least five times. A new strategy to synthesize polymer-supported Au nanoparticle catalyst was finally provided.

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Acknowledgements

We are also grateful to the Analytical and Testing Center of Huazhong University of Science and Technology, ATC School of Chemistry and Chemical Engineering, HUST, Wuhan, China.

Funding

This work was supported by the National Natural Science Foundation of China (21473064) and Key Laboratory of Catalysis and Materials Science of the State Ethnic Affairs Commission & Ministry of Education Foundation (CHCL15001).

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Authors and Affiliations

  1. Hubei Key Laboratory of Material Chemistry and Service Failure, Key Laboratory of Material Chemistry for Energy Conversion and Storage, Ministry of Education, School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China

    Jian Chen, Ju Zhang, Dajian Zhu & Tao Li

  2. Hubei Key Laboratory of Processing and Application of Catalytic Materials, College of Chemical Engineering, Huanggang Normal University, No. 146, Xingang 2 Road, Huanggang City, 438000, Hubei Province, China

    Jian Chen

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  1. Jian Chen
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Correspondence to Dajian Zhu or Tao Li.

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Chen, J., Zhang, J., Zhu, D. et al. One-pot synthesized porphyrin-based polymer supported gold nanoparticles as efficient catalysts for alkyne hydration and alcohol oxidation in water. Gold Bull 52, 19–26 (2019). https://doi.org/10.1007/s13404-018-0249-9

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