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Effect of Basicity on the Reduction Behavior of Iron Ore Pellets

  • Research Article - Chemical Engineering
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Abstract

Physicochemical properties of the iron ore pellets depend on the iron oxide concentrate, gangue content and the amount of fluxes added. The objective of this present work is to study the reducibility as well as the softening–melting behavior of the iron ore bearing fines (mainly containing hematite) pellet with lime to silica ratio (C/S) varying from 0.9 to 2.4 in the temperature range of 1100–\(1400 \,^{{\circ }}\hbox {C}\). Reduction test results show that the highest degree of reduction and degree of metallization of about 95.1 and 94.3%, respectively, are achieved for pellets having C/S ratio 1.6 reduced at \(1400\,^{{\circ }}\hbox {C}\) for 60 min. Further increase in C/S ratio resulted in lowering the reduction rates due to the formation of calcium ferrite phases as confirmed from X-ray diffractogram and photomicrographs. However, softening–melting characteristics study of slag (C/S above 1.6) revealed that the slag of C/S ratio 2.0 can be considered as primary slag.

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References

  1. Mandal, A.K.; Sarkar, A.; Sinha, O.P.: Conversion of solid waste fines of comminution process into feeding material of the Blast Furnace grade iron ore pellets. SGAT Bull. 13, 95–113 (2012)

    Google Scholar 

  2. Sarkar, A.; Mandal, A.K.; Sinha, O.P.: Pelletisation behavior of fluxed iron ore pellets of varying basicities made with waste fines. Int. J. Sci. Eng. 5, 9–14 (2013)

    Article  Google Scholar 

  3. Dwarapudi, S.; Ghosh, T.K.; Tathavadkar, V.; Denys, M.B.; Bhattacharjee, D.; Venugopal, R.: Effect of MgO in the form of magnesite on the quality and microstructure of hematite pellets. Int. J. Miner. Process. 112–113, 55–62 (2012)

    Article  Google Scholar 

  4. Nogueira, P.F.; Fruehan, R.J.: Blast furnace burden softening and melting phenomena – melting onset in acid and basic fluxed pellets. I&SM 30, 29–35 (2003)

    Google Scholar 

  5. Dwarapudi, S.; Ghosh, T.K.; Shankar, A.; Tathavadkar, V.; Bhattacharjee, D.; Venugopal, R.: Effect of pyroxenite flux on the quality and microstructure of hematite pellets. Int.l J. Miner. Process. 96, 45–53 (2010)

    Article  Google Scholar 

  6. Onoda, M., Tsuchiya, O., Sugiyama, T., Fujita, I.; Quality improvements of lime fluxed pellets. In: Proceedings of ISS-AIME 40th Iron Making Conference, Toronto, Canada, pp. 286-298 (1980)

  7. Panigrahy, S.C.; Jena, B.C.; Rigaud, M.: Characterization of bonding and crystalline phases in fluxed pellets using peat moss and bentonite as binders. Metall. Trans. B. 21, 463–474 (1990)

    Article  Google Scholar 

  8. Umadevi, T.; Kumar, P.; Lobo, N.F.; Prabhu, M.; Mahapatra, P.C.; Ranjan, M.: Influence of Pellet Basicity (CaO/SiO2) on Iron Ore Pellet Properties and Microstructure. ISIJ Int. 51, 14–20 (2011)

    Article  Google Scholar 

  9. Iljana, M.; Kemppainen, A.; Paananen, T.; Mattila, O.; Pisilä, E.; Kondrakov, M.; Fabritius, T.: Effect of adding limestone on the metallurgical properties of iron ore pellets. Int. J. Miner. Process. 141, 34–43 (2015)

    Article  Google Scholar 

  10. Dwarapudi, S.; Ghosh, T.K.; Shankar, A.; Tathavadkar, V.; Bhattacharjee, D.; Venugopal, R.: Effect of pellet basicity and MgO content on the quality and microstructure of hematite pellets. Int. J. Miner. Process. 99, 43–53 (2011)

    Article  Google Scholar 

  11. Friel, J.J.; Erickson, E.S.: Chemistry, microstructure, and reduction characteristics of dolomite-fluxed magnetite pellets. Metall. Trans. B. 11, 233–243 (1980)

    Article  Google Scholar 

  12. Yadav, U.S.; Pandey, B.D.; Das, B.K.; Jena, D.N.: Influence of magnesia on sintering characteristics of iron ore. Ironnmak. Steelmak. 29, 91–95 (2002)

    Article  Google Scholar 

  13. Mandal, A.K.; Sinha, O.P.: Characterization of fluxed iron ore pellets as compared to feed material for blast furnace. J. Progress. Res. Chem. 2, 74–82 (2015)

    Google Scholar 

  14. Phillips, B.; Muan, A.: Phase equilibria in the system CaO-iron oxide-SiO2. Air. J. Am. Ceram. Soc. 42, 413–423 (1959)

    Article  Google Scholar 

  15. Biswas, A.K.: Principle of Blast Furnace Iron Making. Calcutta (1984)

  16. Bogdandy, L. von., Engell, H.J.: The Reduction of Iron Ores. New York (1971)

  17. Murakami, T.; Kodaira, T.; Kasai, E.: Effect of the reduction of calcium ferrite on disintegration behavior of sinter under high hydrogen atmosphere. ISIJ Int. 55, 1197–1205 (2015)

    Article  Google Scholar 

  18. Levin, E.M.; Robbins, C.R.; McMurdie, H.F.: Phase Diagrams for Ceramists. Fig. 2647, p. 185. The American Ceramic Society, Columbus (1969)

    Google Scholar 

  19. Mohanty, U.K.: Thermo Physical Properties of Some Metallorthermic Slags. Ph.D. thesis. NIT Rourkela, India (1998)

  20. Behera, R.C.; Mohanty, U.K.; Mohanty, A.K.: Viscosity and constitution of slags associated with metallorthermic extraction of some less common metals. High Temp. Mater. Process. 9, 57–76 (1990)

    Article  Google Scholar 

  21. Dash, S.; Mohanty, N.; Mohanty, U.K.; Sarkar, S.: A novel technique for determination of flow characteristics of blast furnace slag. Open J. Met. 02, 42–47 (2012)

    Article  Google Scholar 

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Correspondence to Manoja Kumar Mohanty.

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Mohanty, M.K., Mishra, S., Mishra, B. et al. Effect of Basicity on the Reduction Behavior of Iron Ore Pellets. Arab J Sci Eng 43, 5989–5998 (2018). https://doi.org/10.1007/s13369-018-3107-4

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  • DOI: https://doi.org/10.1007/s13369-018-3107-4

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