Abstract
In this study, the carbon-doped zirconium dioxide (\(\hbox {ZrO}_{2}\)–C) nanocatalyst was synthesized by sol–gel method and was used for the degradation of basic red 46 (BR46) in water. In order to optimize the dye removal efficiency, different experimental variables involving pH, \(\hbox {ZrO}_{2}\)–C concentration, initial BR46 concentration, and light intensity were analyzed by the response surface methodology. Variance analysis showed high determination coefficient values, with \(R^{2}\) and adjusted-\(R^{2}\) of, respectively, 0.9984 and 0.9965, as well as, a satisfactory prediction of the second-order regression model. Optimization results showed a maximum color removal efficiency of 98.4% at the optimal condition with initial pH 11, ZrO2–C concentration \(= 0.15\) g/L, UV light intensity \(= 18\,\hbox {W}\) and the initial dye concentration \(= 5\) mg/L. Finally, a new kinetic model, in the form of Langmuir–Hinshelwood equation, based on the intrinsic element reactions was developed. The results indicated that the developed DDR-II model fitted well with the experimental data and with a minimal value of the mean absolute relative residual (13.08%).
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Kim, C.S.; Shin, J.W.; An, S.H.; Jang, H.D.; Kim, T.O.: Photodegradation of volatile organic compounds using zirconium-doped TiO2/SiO2 visible light photocatalysts. Chem. Eng. J. 40, 204–206 (2012)
Agorku, E.S.; Pandey, A.C.; Mamba, B.B.; Mishra, A.K.: Gd, C, N, S multi-doped ZrO2 for photocatalytic degradation of indigo carmine dye from synthetic water under simulated solar light. Mater. Today Proc. 2, 3909–3920 (2015)
Khaksar, M.; Amini, M.; Boghaei, D.M.; Chae, K.H.; Gautam, S.: Mn-doped ZrO2 nanoparticles as an efficient catalyst for green oxidative degradation of methylene blue. Catal. Commun. 72, 1–5 (2015)
Sudrajat, H.; Babel, S.; Sakai, H.; Takizawa, S.: Rapid enhanced photocatalytic degradation of dyes using novel N-doped ZrO\(_{2}\). J. Environ. Manag. 165, 224–234 (2016)
Alalm, M.G.; Ookawara, S.; Fukushi, D.; Sato, A.; Tawfik, A.: Improved WO3 photocatalytic efficiency using ZrO\(_{2}\) and Ru for the degradation of carbofuran and ampicillin. J. Hazard. Mater. 302, 225–231 (2016)
López, T.; Alvarez, M.; Tzompantzi, F.; Picquart, M.: Photocatalytic degradation of 2,4-dichlorophenoxiacetic acid and 2,4,6-trichlorophenol with ZrO\(_{2}\) and Mn/ZrO\(_{2}\) sol–gel materials. J. Sol-Gel Sci. Technol. 37, 207–211 (2006)
Basahel, S.N.; Ali, T.T.; Mokhtar, M.; Narasimharao, K.: Influence of crystal structure of nanosized ZrO\(_{2}\) on photocatalytic degradation of methyl orange. Nanoscale Res. Lett. 10, 1–13 (2015)
Gusain, D.; Dubey, S.; Upadhyay, S.N.; Weng, C.H.; Sharma, Y.C.: Studies on optimization of removal of orange G from aqueous solutions by a novel nanoadsorbent. J. Ind. Eng. Chem. 33, 42–45 (2016)
Fakhri, A.; Behrouz, S.; Tyagi, I.; Agarwal, S.; Gupta, V.K.: Synthesis and characterization of ZrO\(_{2}\) and carbon-doped ZrO\(_{2}\) nanoparticles for photocatalytic application. J. Molecul. Liq. 216, 342–346 (2016)
Hoffmann, M.R.; Martin, S.T.; Choi, W.; Bahnemann, D.W.: Environmental applications of semiconductor photocatalysis. Chem. Rev. 95, 69–96 (1995)
Navio, J.A.; Hidalgo, M.C.; Colon, G.; Botta, S.G.; Litter, M.I.: Preparation and physicochemical properties of ZrO\(_{2}\) and Fe/ZrO\(_{2}\) prepared by a sol–gel technique. Langmuir 17, 202–210 (2001)
Botta, S.G.; Navio, J.A.; Hidalgo, M.C.; Restrepo, G.M.; Litter, M.I.: Photocatalytic properties of ZrO\(_{2}\) and Fe/ZrO\(_{2}\) semiconductors prepared by a sol–gel technique. J. Photochem. Photobiol. A Chem. 129, 89–99 (1999)
Sreethawong, T.; Ngamsinlapasathian, S.; Yoshikawa, S.: Synthesis of crystalline mesoporous-assembled ZrO\(_{2}\) nanoparticles via a facile surfactant-aided sol–gel process and their photocatalytic dye degradation activity. Chem. Eng. J. 228, 256–262 (2013)
Matsui, H.; Ohkura, N.; Karuppuchamy, S.; Yoshihara, M.: The effect of surface area on the photo-catalytic behavior of ZrO2/carbon clusters composite materials. Ceram. Int. 39, 5827–5831 (2013)
Turchi, C.S.; Ollis, D.F.: Photocatalytic degradation of organic water contaminants: mechanisms involving hydroxyl radical attack. J. Catal. 122, 178–192 (1990)
Li, Y.; Sun, S.; Ma, M.; Ouyang, Y.; Yan, W.: Kinetic study and model of the photocatalytic degradation of rhodamine B (RhB) by a TiO\(_{2}\)-coated activated carbon catalyst: effects of initial RhB content, light intensity and TiO\(_{2}\) content in the catalyst. Chem. Eng. J. 142, 147–155 (2008)
Mansouri, M.; Nademi, M.; Olya, M.E.; Lotfi, H.: Study of methyl tert-butyl Ether (MTBE) photocatalytic degradation with UV/TiO\(_{2}\)–ZnO–CuO nanoparticles. J. Chem. Heal. Risks 7, 19–32 (2017)
Ollis, D.F.; Pelizzetti, E.; Serpone, N.: Photocatalyzed destruction of water contaminant. Environ. Sci. Technol. 25, 1522–1529 (1991)
Box, G.E.P.; Draper, N.R.: Empirical Model-Building and Response Surfaces. Wiley, New York (1987)
Bas, D.; Boyaci, I.H.: Modeling and optimization I: usability of response surface methodology. J. Food Eng. 78, 836–845 (2007)
Akhbari, A.; Zinatizadeh, A.A.L.; Mohammadi, P.; Irandoust, M.; Mansouri, Y.: Process modeling and analysis of biological nutrients removal in an integrated RBC-AS system using response surface methodology. Chem. Eng. J. 168, 269–279 (2011)
Ghorbania, F.; Younesi, H.; Ghasempouri, S.M.; Zinatizadeh, A.A.; Amini, M.; Daneshi, A.: Application of response surface methodology for optimization of cadmium biosorption in an aqueous solution by Saccharomyces cerevisiae. Chem. Eng. J. 145, 267–275 (2008)
Montgomery, D.C.: Design and Analysis of Experiments, 7th edn. Wiley, New Delhi (2012)
Anupam, K.; Dutta, S.; Bhattacharjee, C.; Datta, S.: Adsorptive removal of chromium (VI) from aqueous solution over powdered activated carbon: optimisation through response surface methodology. Chem. Eng. J. 173, 135–143 (2011)
Aydin, Y.A.; Aksoy, N.D.: Adsorption of chromium on Chitosan: optimization, kinetics and thermodynamics. Chem. Eng. J. 151, 188–198 (2009)
Li, Z.Q.; Lu, C.J.; Xia, Z.P.; Zhou, Y.; Luo, Z.: X-ray diffraction patterns of graphite and turbostratic carbon. Carbon 45, 1686–1695 (2007)
Myers, R.H.; Montgomery, D.C.: Response Surface Methodology: Process and Product Optimization Using Designed Experiments, 2nd edn. Wiley, New York (2002)
Zhang, J.; Fu, D.; Xu, Y.; Liu, C.: Optimization of parameters on photocatalytic degradation of chloramphenicol using TiO\(_{2}\) as photocatalyist by response surface methodology. J. Environ. Sci. 22, 1281–1289 (2010)
Khataee, A.R.; Fathinia, M.; Aber, S.: Kinetic modeling of liquid phase photocatalysis on supported TiO\(_{2}\) nanoparticles in a rectangular flat-plate photoreactor. Ind. Eng. Chem. Res. 49, 12358–12364 (2010)
Khataee, A.R.; Fathinia, M.; Aber, S.: Kinetic study of photocatalytic decolorization of C.I. Basic Blue 3 solution on immobilized titanium dioxide nanoparticles. Chem. Eng. Res. Des. 89, 2110–2116 (2011)
Amani-Ghadim, A.R.; Dorraji, M.S.S.: Modeling of photocatalyatic process on synthesized ZnO nanoparticles: kinetic model development and artificial neural networks. Appl. Catal. B Environ. 163, 539–546 (2015)
Kaneco, S.; Li, N.; Itoh, K.; Katsumata, H.; Suzuki, T.; Ohta, K.: Titanium dioxide mediated solar photocatalytic degradation of thiram in aqueous solution: kinetics and mineralization. Chem. Eng. J. 148, 50–56 (2009)
Moradi, H.; Sharifnia, S.; Rahimpour, F.: Photocatalytic decolorization of reactive yellow 84 from aqueous solutions using ZnO nanoparticles supported on mineral LECA. Mater. Chem. Phys. 158, 38–44 (2015)
Dutta, S.; Parsons, S.A.; Bhattacharjee, C.; Jarvis, P.; Datta, S.; Bandyopadhyay, S.: Kinetic study of adsorption and photo-decolorization of reactive red 198 on TiO\(_{2}\) surface. Chem. Eng. J. 155, 674–679 (2009)
Terzian, R.; Serpone, N.; Fox, M.A.: Heterogeneousphotocatalyzed oxidation of creosote components: mineralization of xylenols by illuminated TiO\(_{2}\) in oxygenated aqueous media. J. Photochem. Photobiol. A Chem. 90, 125–135 (1995)
Rothenberger, G.; Moser, J.; Graetzel, M.; Serpone, N.; Sharma, D.K.: Charge carrier trapping and recombination dynamics in small semiconductor particles. JACS 107, 8054–8059 (1985)
Arana, J.; Peña Alonso, A.; Doña Rodríguez, J.M.; Herrera Melián, J.A.; González Díaz, O.; Pérez Peña, J.: Comparative study of MTBE photocatalytic degradation with TiO\(_{2}\) and Cu–TiO\(_{2}\). Appl. Catal. B 78, 355–363 (2008)
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Setarehshenas, N., Hosseini, S.H. & Ahmadi, G. Optimization and Kinetic Model Development for Photocatalytic Dye Degradation. Arab J Sci Eng 43, 5785–5797 (2018). https://doi.org/10.1007/s13369-017-3010-4
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DOI: https://doi.org/10.1007/s13369-017-3010-4