CNT supported Mn-doped ZnO nanoparticles: simple synthesis and improved photocatalytic activity for degradation of malachite green dye under visible light
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Hexagonal ZnO nanoparticles doped with Mn and supported with a minor amount of carbon nanotubes (CNTs) were synthesized through a simple coprecipitation-ultrasonication process with high yield. The effect of Mn doping, as well as CNTs addition on structure, surface morphology and texture, optical and electronic properties, was studied. We found that just 1% Mn doping and 1% CNT addition on ZnO showed the best crystallinity, highest surface area, improved visible light absorption, and a lowest estimated band gap of 2.6 eV with minimum charge recombination as revealed from photoluminescence spectra. The application of the optimum composition of the synthesized sample for the photodegradation of malachite green dye showed enhanced photocatalytic activity > 95% under visible light irradiation within 120 min at a minimum dosage of 0.1 g L−1 without any using of hole scavenger or changing the pH. This work highlighting the humble preparation procedure and develops photocatalysis research for real industrial applications.
KeywordsZinc oxide Carbon nanotubes Synthesis Photocatalyst Photodegradation Malachite green
This project was funded by the Deanship of Scientific Research (DSR) at King Abdulaziz University, Jeddah, under Grant no. (G-114-130-38). The authors, therefore, acknowledge with thanks DSR for technical and financial support.
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Conflict of interest
On behalf of all authors, the corresponding author states that there is no conflict of interest.
- Azqhandi MHA, Vasheghani BF, Rajabi FH, Keramati M (2017) Synthesis of Cd doped ZnO/CNT nanocomposite by using microwave method: photocatalytic behavior, adsorption and kinetic study. Res Phys 7:1106–1114Google Scholar
- Li WW, Yu WL, Jiang YJ, Jing CB, Zhu JY, Zhu M, Hu ZG, Tan XD, Chu JH (2010) Structure, optical, and room-temperature ferromagnetic properties of pure and transition-metal-(Cr, Mn, and Ni)-doped ZnO Nanocrystalline Films Grown By The Sol-Gel Method. J Phys Chem C 114:11951–11957CrossRefGoogle Scholar
- Rajabi M, Mirza B, Mahanpoor K, Mirjalili M, Najafi F, Moradi O, Sadegh H, Shahr-ghoshekandi R, Asif M, Tyagi I, Agarwal S, Gupta VK (2016) Adsorption of malachite green from aqueous solution by carboxylate group functionalized multi-walled carbon nanotubes: determination of equilibrium and kinetics parameters. J Ind Eng Chem 34:130–138CrossRefGoogle Scholar