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Paleohydrological modeling of penesaline reflux dolomitization: Avon Park Formation (Middle Eocene), East Central Florida

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Abstract

Previous geochemical, petrological, and sedimentological investigations of the Middle Eocene Avon Park Formation (Middle Eocene) of Florida suggest that dolomitization occurred in the Eocene from normal to hypersaline seawater. Reflux of penesaline water (i.e., seawater evaporatively concentrated below evaporite mineral precipitation) is the most likely mechanism to supply the required magnesium. Density-dependent solute-transport modeling was performed to evaluate whether penesaline reflux under known or inferred Middle Eocene paleohydrological conditions could have provided enough magnesium to account for the mass of dolomite present in three cores of the upper part of the Avon Park Formation from the City of Daytona Beach. Rather than a simple down and out flow pattern, the modeling results indicate that an initial rapid vertical convection-dominated flow regime first occurs in which native groundwater is displaced by refluxed brine, and followed by a longer-duration regime dominated by steady-state lateral flow. Dolomitization from a brine with a 89.6 ppt TDS concentration would require an average minimum reflux (at 100% dolomitization efficiency) on the Florida Platform of about 8130 m3 per m2 to provide the required magnesium. Modeling results indicate that such reflux could occur over 0.7–3 million years, depending upon the aquifer hydraulic parameter values. Longer time periods would be required for the reflux of lower salinity brines and lower dolomitization efficiencies. Penesaline reflux is thus hydrologically plausible for the dolomites of the upper Avon Park Formation.

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References

  • Adams JE, Rhodes KL (1960) Dolomitization by seepage refluxion. Am Assoc Pet Geol Bull 44:1912–1920

    Google Scholar 

  • Applin PL, Applin ER (1944) Regional subsurface stratigraphy and structure of Florida and southern Georgia. Am Assoc Pet Geol Bull 28:1673–1753

    Google Scholar 

  • Applin ER, Jordan L (1945) Diagnostic foraminifera from subsurface formations in Florida. J Paleontol 19:129–148

    Google Scholar 

  • Bennett RH, Li H, Lambert DN, Fischer KM, Walter DJ, Hickox CE, Hulbert MH, Yamamoto T, Badiey M (1990) In situ porosity and permeability of selected carbonate sediment: Great Bahama Bank part 1: measurements. Mar Geotechnol 9:1–28

    Article  Google Scholar 

  • Budd DA (1997) Cenozoic dolomites of carbonate islands: their attributes and origin. Earth Sci Rev 42:1–47

    Article  Google Scholar 

  • Budd DA (2001) Permeability loss with depth in the cenozoic carbonate platform of west-central Florida. Am Assoc Pet Geol Bull 85:1253–1272

    Google Scholar 

  • Cander HS (1991) Dolomitization and water-rock interaction in the Middle Eocene Avon Park Formation, Floridan Aquifer. Dissertation, University of Texas, Austin

  • Cander HS (1994) An example of mixing-zone dolomite, middle Eocene Avon Park Formation, Floridan aquifer system. J Sediment Res 64:615–629

    Google Scholar 

  • Chen CD (1965) The regional lithostratigraphic analysis of Paleocene and Eocene rocks of Florida, Bulletin 45. Florida Geol Surv, Tallahassee

    Google Scholar 

  • Cohen KM, Finney SC, Gibbard PL, Fan J-X (2013) The ICS international chronostratigraphic chart. Episodes 36:199–204

    Article  Google Scholar 

  • Dawans JM, Swart PK (1988) Textural and geochemical alterations in late Cenozoic Bahamian dolomites. Sedimentology 35:385–403

    Article  Google Scholar 

  • Dunham RJ (1962) Classification of carbonate rocks according to depositional texture. In: Ham WE (ed) Classification of carbonate rocks. Memoir 1. Am Assoc Pet Geol, Tulsa, pp 108–121

    Google Scholar 

  • Enos P, Sawatsky LH (1981) Pore networks in Holocene carbonate sediments. J Sediment Pet 51:961–985

    Google Scholar 

  • Fanning KA, Byrne RH, Breland JA, Betzer PR, Moore WS, Elsinger RJ, Pyle TE (1981) Geothermal springs of the West Florida continental shelf: evidence for dolomitization and radionuclide enrichment. Earth Planet Sci Lett 52:345–354

    Article  Google Scholar 

  • Guo W, Langevin CD (2002) User’s guide to SEAWAT: a computer program for simulation of three-dimensional variable-density ground-water flow, Open-file report 01-434. Reston, US Geological Survey

    Google Scholar 

  • Halley RB, Schmoker JW (1983) High-porosity Cenozoic carbonate rocks of south Florida: progressive loss of porosity with depth. Am Assoc Pet Geol Bull 67:191–200

    Google Scholar 

  • Hardie LA (1987) Dolomitization: A critical view of some current views. J Sediment Pet 57:166–183

    Article  Google Scholar 

  • Henry H, Kohout FA (1972) Circulation patterns of saline groundwater affected by geothermal heating as related to waste disposal. In: Cook TD (ed) Underground waste management and environmental implications, Memoir 18. American Association of Petroleum Geologists, Tulsa, pp 202–221

    Google Scholar 

  • Hsü KJ (1966) Origin of dolomite in sedimentary sequences: a critical analysis. Miner Depos 1(2):133–138

    Article  Google Scholar 

  • Hsü KJ (1967) Chemistry of dolomite formation. In: Chilingar GV, Bissell HJ, Fairbridge RW (eds) Carbonate rocks, physical and chemical aspects. Elsevier, Amsterdam, pp 169–191

    Chapter  Google Scholar 

  • Hughes JD, Vacher HL, Sanford WE (2007) Three-dimensional flow in the Florida platform: theoretical analysis of Kohout convection at its type locality. Geology 35:663–666

    Article  Google Scholar 

  • Jones GD, Xiao Y (2005) Dolomitization, anhydrite cementation, and porosity evolution in a reflux system: insights from reactive transport models. Am Assoc Pet Geol Bull 89:577–601

    Google Scholar 

  • Jones GD, Whitaker FF, Smart PL, Sanford WE (2002) Fate of reflux brines in carbonate platforms. Geology 30:371–374

    Article  Google Scholar 

  • Kaufman J (1994) Numerical models of fluid flow in carbonate platforms: implications for dolomitization. J Sediment Res 64(1a):128–139

    Google Scholar 

  • Kohout FA (1965) A hypothesis concerning cyclic flow of salt water related to geothermal heating in the Floridan aquifer. Trans NY Acad Sci 28:249–271

    Article  Google Scholar 

  • Kohout FA, Henry HR, Banks JE (1977) Hydrogeology related to geothermal conditions of the Floridan Plateau. In: Smith KL, Griffin GM (eds) The geothermal nature of the Floridan Plateau, Special Publication 21. Florida Geological Survey, Tallahassee, pp 1–41

    Google Scholar 

  • Land LS (1985) The origin of massive dolomite. J Geol Educ 33(2):112–125

    Article  Google Scholar 

  • Langevin CD, Thorne DT Jr, Dausman AM, Sukop MC, Guo W (2008) SEAWAT version 4: a computer program for simulation of multi-species solute and heat transport, techniques and methods book 6. US Geological Survey, Reston

    Google Scholar 

  • Machel HG (2004) Concepts and models of dolomitization: a critical reappraisal. In: Braithwaite CJR, Rizzi G, Darke G (eds) The geometry and petrogeneses of hydrocarbon reservoirs, Special Publication 235. Geological Society, London, pp 7–63

    Google Scholar 

  • Maliva RG, Walker CW (1998) Hydrogeology of deep-well disposal of liquid wastes in southwestern Florida, USA. Hydrogeol J 6:538–548

    Article  Google Scholar 

  • Maliva RG, Budd DA, Clayton EA, Missimer TM, Dickson JAD (2011) Insights into the dolomitization process and porosity modification in sucrosic dolostones, Avon Park Formation (Middle Eocene), East-Central Florida, USA. J Sediment Res 81(3):218–232

    Article  Google Scholar 

  • McCaffrey MA, Lazar B, Holland HD (1987) The evaporation path of seawater and the coprecipitation of Br− and K+ with halite. J Sediment Pet 57:928–937

    Google Scholar 

  • McDonald MG, Harbaugh AW (1988) A modular three-dimensional finite-difference ground water flow model, Techniques of water-resources investigation report 06-A1. Reston, US Geological Survey

    Google Scholar 

  • Melim LA, Scholle PA (2002) Dolomitization of the capitan formation forereef facies (Permian, west Texas and New Mexico): seepage reflux revisited. Sedimentology 49:1207–1227

    Article  Google Scholar 

  • Miller JA (1986) Hydrogeologic framework of the Floridan aquifer system in Florida and in parts of Georgia, South Carolina, and Alabama, Professional paper 1403-B. Reston, US Geological Survey

    Google Scholar 

  • Miller JA (1990) Ground water atlas of the United States. Alabama, Florida, Georgia, and South Carolina, Hydrologic investigations atlas HA 730-G. US Geological Survey, Reston

    Google Scholar 

  • Missimer TM, Maliva RG (2004) Tectonically induced fracturing, folding, and groundwater flow in South Florida. Trans Gulf Coast Assoc Geol Soc 54:443–459

    Google Scholar 

  • Mitchell-Tapping HJ, Bellucci JR, Woody G, Lee TJ (1999) Mud hole: a unique warm-water submarine spring, located offshore southwestern Florida. Trans Gulf Coast Assoc Geol Soc 49:370–383

    Google Scholar 

  • Morrow DW (1982) Diagenesis 2. Dolomite—part 2. Dolomitization models and ancient dolostones. Geosci Can 9(2):95–107

    Google Scholar 

  • Pal M, Taberner C (2011) Simulation of brine reflux and geothermal circulation in large carbonate platforms: an attempt to predict dolomite geo-bodies. In: Proceedings 2011 COMSOL Conference, Stuttgart, October 26–28

  • Pitzer KS (1991) Ionic interaction approach: theory and data correlation. In: Pitzer KS (ed) Activity coefficients in electrolyte solutions. CRC Press, Boca Raton, pp 75–153

    Google Scholar 

  • Qing H, Bosence DW, Rose EP (2001) Dolomitization by penesaline sea water in Early Jurassic peritidal platform carbonates, Gibraltar, western Mediterranean. Sedimentology 48:153–163

    Article  Google Scholar 

  • Randazzo AF (1997) The sedimentary platform of Florida: Mesozoic to Cenozoic. In: Randazzo AF, Jones DS (eds) The geology of Florida. University Press of Florida, Gainesville, pp 39–56

    Google Scholar 

  • Schijf J, Byrne RH (2007) Progressive dolomitization of Florida limestone recorded by alkaline earth element concentrations in saline, geothermal, submarine springs. J Geophys Res. https://doi.org/10.1029/2006JC003659

    Article  Google Scholar 

  • Shields MJ, Brady PV (1995) Mass balance and fluid flow constraints on regional-scale dolomitization, Late Devonian, Western Canada Sedimentary Basin. Bull Can Soc Pet Geol 43:371–392

    Google Scholar 

  • Shinn EA (1983) Tidal flat environment. In: Scholle PA, Bebout DG, Moore CH (eds) Carbonate depositional environments, Memoir 22. American Association of Petroleum Geologists, Tulsa, pp 171–210

    Google Scholar 

  • Simms M (1984) Dolomitization by ground water-flow systems in carbonate platforms. Trans Gulf Coast Assoc Geol Soc 34:411–420

    Google Scholar 

  • Sperber CM, Wilkinson BH, Peacor DR (1984) Rock composition, dolomite stoichiometry, and rock/water reactions in dolomitic carbonate rocks. J Geol 92:609–622

    Article  Google Scholar 

  • Stumm W, Morgan JJ (1996) Aquatic chemistry: chemical equilibria and rates in natural waters, 3rd edn. Wiley, New York

    Google Scholar 

  • Sun SQ (1994) A reappraisal of dolomite abundance and occurrence in the Phanerozoic. J Sediment Res 64:396–404

    Article  Google Scholar 

  • Swart PK, Melim LA (2000) The origin of dolomites in tertiary sediments from the margin of Great Bahama Bank. J Sediment Res 70:738–748

    Article  Google Scholar 

  • Vahrenkamp VC, Swart PK (1994) Late Cenozoic dolomites of the Bahamas: metastable analogues for the genesis of ancient platform dolomites. In: Purser B, Tucker M, Zenger D (eds) Dolomites: a volume in honour of Dolomieu, Special publication 21. International Association Sedimentologists, pp. 133–153

  • Ward WC, Cunningham KJ, Renken RA, Wacker MA, Carlson JI (2003) Sequence-stratigraphic analysis of the Regional Observation Monitoring Program (ROMP) 29A test corehole and its relation to carbonate porosity and regional transmissivity in the Floridan aquifer system, Highlands County, Florida, Open-file report 03-201. US Geological Survey, Reston

    Book  Google Scholar 

  • Warren J (2000) Dolomite: occurrence, evolution and economically important associations. Earth Sci Rev 52:1–81

    Article  Google Scholar 

  • Whitaker FF, Smart PL (1990) Active circulation of saline ground waters in carbonate platforms: evidence from the Great Bahama Bank. Geology 18:200–203

    Article  Google Scholar 

  • Whitaker FF, Smart P L, Vahrenkamp VC, Nicholson H, Wogelius RA (1994) Dolomitization by near-normal seawater? Field evidence from the Bahamas. In: Purser B, Tucker M, Zenger D (eds) Dolomites: A volume in honour of Dolomieu, Special publication 21. International Association Sedimentologists, p 111–132

  • Whitaker FF, Smart PL, Jones GD (2004) Dolomitization: from conceptual to numerical models. In: Braithwaite CJR, Rizzi G, Darke G (eds) The geometry and petrogenesis of hydrocarbon reservoir, Special Publication 235. Geological Society, London, pp 99–139

    Google Scholar 

  • Wilson AM, Sanford W, Whitaker F, Smart PL (2001) Spatial patterns of diagenesis during geothermal circulation in carbonate platforms. Am J Sci 301:727–752

    Article  Google Scholar 

  • Wyrick GG (1960) The ground-water resources of Volusia County, Florida, Report of investigations 22. Florida Geological Survey, Tallahassee

    Google Scholar 

  • Zheng C, Wang PP (1999) MT3DMS: a modular three-dimensional multi-species model for simulation of advection, dispersion and chemical reactions of contaminants in ground water systems: documentation and user’s guide. Report SERDP-99-1. US Army Engineer Research and Development Center, Vicksburg

    Google Scholar 

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Acknowledgements

This manuscript benefited from the thoughtful reviews of two anonymous reviewers.

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Authors and Affiliations

  1. WSP USA Inc., 1567 Hayley Lane, Suite 202, Fort Myers, FL, 33907, USA

    Robert G. Maliva

  2. U. A. Whitaker College of Engineering, Florida Gulf Coast University, 10501 FGCU Boulevard South, Fort Myers, FL, 33965-6565, USA

    Thomas M. Missimer

  3. Groundwater Tek Inc., 14542 Indigo Lakes Circle, Naples, FL, 34119, USA

    Weixing Guo

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  1. Robert G. Maliva
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Correspondence to Robert G. Maliva.

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Maliva, R.G., Missimer, T.M. & Guo, W. Paleohydrological modeling of penesaline reflux dolomitization: Avon Park Formation (Middle Eocene), East Central Florida. Carbonates Evaporites 34, 941–954 (2019). https://doi.org/10.1007/s13146-018-0448-8

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