Skip to main content
Log in

Integration of Photocatalytic Oxidation and Biodegradation Treatment Processes to Enhance Degradation Efficiency of CETP Wastewater Contaminants

  • Published:
BioNanoScience Aims and scope Submit manuscript

Abstract

In the present, experiment reported an emerging approach of integrated treatment processes such as photocatalytic oxidation and biodegradation to increase degradation efficiency of CETP wastewater. Photocatalytic oxidation process performed using hybrid photocatalyst Ti02 impregnated with activated carbon (AC) and biodegradation was performed by developed biofilm on biocarrier. Synthesized TiO2/AC powder was characterized by sophisticated instrumentation. A lab scale photocatalytic bioreactor was designed to remove pollutants from CETP effluent. In this setup, sample was treated with hybrid photocatalyst TiO2/AC under the sunlight and developed biofilm; sampling was done and analyzed. Our results show better degradation within 6 h because of generation of hydroxyl radical and superoxide species reacted with pollutants. This presented experiment shows the rapid degradation and increase removal efficiency of pollutants by using the integrated processes.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Ahmadi, M., Amiri, P., & Amiri, N. (2015). Combination of TiO2-photocatalytic process and biological oxidation for the treatment of textile wastewater. Korean Journal of Chemical Engineering, 32, 1327–1332.

    Article  Google Scholar 

  2. Areerachakul, N., Vigneswaran, S., Ngo, H., & Kandasamy, J. (2007). Granular activated carbon (GAC) adsorption-photocatalysis hybrid system in the removal of herbicide from water. Separation and Purification Technology, 55, 206–211.

    Article  Google Scholar 

  3. Bandara, J., Pulgarin, C., Peringer, P., & Kiwi, J. (1997). Chemical (photo558activated) coupled biological homogeneous degradation of p-nitro-o-toluene-sulfonic acid in a flow reactor. Journal of Photochemistry and Photobiology A, 111, 253–263.

    Article  Google Scholar 

  4. Barkay, T., & Schaefer, J. (2001). Metal and radionuclide bioremediation: issues, considerations and potentials. Current Opinion in Microbiology, 4, 318–323.

    Article  Google Scholar 

  5. Boroski, M., Rodrigues, A. C., Garcia, J. C., Sampaio, L. S., Nozaki, J., & Hioka, N. (2009). Combined electrocoagulation and TiO2 photoassisted treatment applied to wastewater effluents from pharmaceutical and cosmetic industries. Journal of Hazardous Materials, 162, 448–454.

    Article  Google Scholar 

  6. Carpio, E., Zuniga, P., Ponce, S., Solis, J., Rodriguez, J., & Estrada, W. (2005). Photocatalytic degradation of phenol using TiO2 nanocrystals supported on activated carbon. Journal of Molecular Catalysis A: Chemical, 228, 293–298.

    Article  Google Scholar 

  7. Chong, M. N., Jin, B., Chow, C. W., & Saint, C. (2010). Recent developments in photocatalytic water treatment technology: a review. Water Research, 44, 2997–3027.

    Article  Google Scholar 

  8. Coelho, C., Oliveira, A., Pereira, M. F., & Nunes, O. (2006). The influence of activated carbon surface properties on the adsorption of the herbicide molinate and the bio-regeneration of the adsorbent. Journal of Hazardous Materials, 138, 343–349.

    Article  Google Scholar 

  9. Crittenden, J., Suri, R., Perram, D., & Hand, D. (1997). Decontamination of water using adsorption and photocatalysis. Water Research, 31, 411–418.

    Article  Google Scholar 

  10. El-Sharkawy, E. A., Soliman, A. Y., & Al-Amer, K. M. (2007). Comparative study for the removal of methylene blue via adsorption and photocatalytic degradation. Journal of Colloid and Interface Science, 310, 498–508.

    Article  Google Scholar 

  11. EPA. (2000) Wastewater technology factsheet: granular activated carbon absorption and regeneration; http://www.epa.gov/OWOWM.html/mtb/carbon_absorption.pdf.

  12. Fulekar, M., Wadgaonkar, S., & Singh, A. (2013). Decolourization of dye compounds by selected bacterial strains isolated from dyestuff industrial area. International Journal of Advanced Research and Technology 2: ISSN, 2278–7763.

  13. Ghaly, M., Jamil, T., El-Seesy, I., Souaya, E., & Nasr, R. (2011). Treatment of highly polluted paper mill wastewater by solar photocatalytic oxidation with synthesized nano TiO2. Chemical Engineering Journal, 168, 446–454.

    Article  Google Scholar 

  14. Ghoreishi, S., & Haghighi, R. (2003). Chemical catalytic reaction and biological oxidation for treatment of non-biodegradable textile effluent. Journal of Chemical Engineering, 95, 163–169.

    Article  Google Scholar 

  15. Hanchang, S. (2011). Point sources of pollution: local effects and control-industrial wastewater-types, amounts and effects. Encyclopedia of life support systems, 1, 191.

    Google Scholar 

  16. Hao, O., Kim, H., & Chiang, P. (1999). Decolorization of wastewater. Critical Reviews in Environmental Science and Technology, 30, 449–505.

    Article  Google Scholar 

  17. Harada, M., Honda, M., Yamashita, H., & Anpo, M. (1999). Preparation of titanium oxide photocatalysts loaded on activated carbon and their photocatalytic reactivity for the degradation of 2-propanol diluted in water. Research on Chemical Intermediates, 25, 757–768.

    Article  Google Scholar 

  18. Jiang, H., & Bishop, P. L. (1994). Aerobic biodegradation of azo dyes in biofilms. Water Science and Technology, 29, 525–530.

    Article  Google Scholar 

  19. Khan A, Mazyck D, Wu C (2002) TiO2 coated activated carbon: a regenerative technology for water recovery. In: 32nd International Conference on Environmental Systems, San Antonio, TX.

  20. Marsolek, M. D., Torres, C. I., Hausner, M., & Rittmann, B. E. (2008). Intimate coupling of photocatalysis and biodegradation in a photocatalytic circulating-bed bio film reactor. Biotechnology and Bioengineering, 101, 83–92.

    Article  Google Scholar 

  21. Metcalf & Eddy Inc., Wastewater Engineering, Disposal & Reuse; Tata McGrawHill, New York, 2003.

  22. Pandey, B., & Fulekar, M. H. (2012a). Bioremediation of dyestuff compounds using indigenous microorganism in a bioreactor. APCBEE Procedia, 1, 27–33.

    Article  Google Scholar 

  23. Pandey, B., & Fulekar, M. H. (2012b). Bioremediation technology: a new horizon for environmental clean-up. Biology and Medical, 4, 51–59.

    Google Scholar 

  24. Pera-Titus, M., Garcia-Molina, V., Banos, M., Gimenez, J., & Esplugas, S. (2004). Degradation of chlorophenols by means of advanced oxidation processes: a general review. Applied Catalysis B: Environmental, 47, 219–256.

    Article  Google Scholar 

  25. Pirkanniemi, K., & Sillanpaa, M. (2000). Heterogeneous water phase catalysis as an environmental application: a review. Chemosphere, 48, 1047–1060.

    Article  Google Scholar 

  26. Rai, M., Rama Bhat, P., Prajna, P., Jayadev, K., & Venkatakrishna, R. P. (2014). Degradation of malachite green and Congo red using Aloe barabadensis Mill. Extractive International Journal of Current Microbiology and Applied Science, 3, 330–340.

    Google Scholar 

  27. Sheintuch, M., & Matatov-Meytal, Y. (1999). Comparison of catalytic processes with other regeneration methods of activated carbon. Catalysis Today, 53, 73–80.

    Article  Google Scholar 

  28. Singh, R., Paul, D., & Jain, R. (2006). Biofilms: implications in bioremediation a review. TRENDS in Microbio, 14, 389–397.

    Article  Google Scholar 

  29. Srinivasan, S., Prea Samita Mary, G., Kalyanaraman, C., Sureshkumar, P., Balakameswari, K., Suthanthararajan, R., & Ethirajulu, R. (2012). Combined advanced oxidation and biological treatment of tannery effluent. Clean Technologies and Environmental Policy, 14, 251–256.

    Article  Google Scholar 

  30. Tao, Y., Schwartz, S., Wu, C. Y., & Mazyck, D. (2005). Development of a TiO2/AC composite photocatalyst by dry impregnation for the treatment of methanol in humid airstreams. Industrial and Engineering Chemistry Research, 447, 366–7372.

    Google Scholar 

Download references

Acknowledgments

The authors thank the Vapi Green Enviro Limited for their support for this work and also thank to The Central Instrumentation Facility (CIF) for characterization of synthesized photocatalyst. The Non NET fellowship provided UGC, Delhi.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to M. H. Fulekar.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Chavan, A., Fulekar, M.H. Integration of Photocatalytic Oxidation and Biodegradation Treatment Processes to Enhance Degradation Efficiency of CETP Wastewater Contaminants. BioNanoSci. 8, 761–768 (2018). https://doi.org/10.1007/s12668-018-0534-3

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12668-018-0534-3

Keywords

Navigation