Abstract
Investigations undertaken in 2013 at a foreshore site that was historically used for ship repairs in Korea indicated that soil and groundwater were contaminated with petroleum hydrocarbons over an area of 10,000 m2. Groundwater investigations and modelling were undertaken to determine the characteristics of aquifers beneath the site, including the direction and rate of groundwater flow and the extent of dispersion of total petroleum hydrocarbon contamination. To identify petroleum products residing in contaminated soils, the hump of an unresolved complex mixture on the baseline found in the data of gas chromatography was used as a new method. Based on objective facts obtained from basic investigation, the current state of contamination, and discrimination of oil species, the polluter as specified in the Korean Soil Environment Conservation Act was identified.
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References
Alimi H, Ertel T, Schug B (2003) Fingerprinting of hydrocarbon fuel contaminants: literature review. Environ Forensics 4(1):25–38. https://doi.org/10.1080/15275920303489
Booth AM, Sutton PA, Lewis CA, Lewis AC, Scarlett A, Chau W et al (2007) Unresolved complex mixtures of aromatic hydrocarbons: thousands of overlooked persistent, bioaccumulative, and toxic contaminants in mussels. Environ Sci Technol 41(2):457–464. https://doi.org/10.1021/es0615829
Christensen LB, Larsen TH (1993) Method for determining the age of diesel oil spills in the soil. Groundwater Monit Remed 13(4):142–149. https://doi.org/10.1111/j.1745-6592.1993.tb00458.x
Freeze RA, Cherry JA (1982) Groundwater. Prentice-Hall, Englewood Cliffs
Jeon SK, Kwon D, Lee S (2017) Identification of weathered multiple petroleum products in contaminated soils by characterizing unresolved complex mixture hump in gas chromatograph data. Sci Total Environ 607–608:42–52. https://doi.org/10.1016/j.scitotenv.2017.06.251
Kaplan IR, Galperin Y, Lu S, Lee R (1997) Forensic environmental geochemistry: differentiation of fuel-types, their sources and release time. Org Geochem 27(5–6):289–317. https://doi.org/10.1016/s0146-6380(97)87941-7
Lee JY (2007) A review on forensic investigations for tracing contamination sources of petroleum hydrocarbons. J Geol Soc Korea 43(3):369–380
Mercado A (1966) Recharge and mixing tests at Yavne-20 well field, Underground Water Storage Study Tech. Rept. 12, TAHAL-Water Planning for Israel Ltd., Tel Aviv, Publ. 611, p 62
Ren DJ, Shen SL, Cheng WC, Zhang N, Wang ZF (2016) Geological formation and geohazards during subway construction in Guangzhou. Environ Earth Sci 75(11):934. https://doi.org/10.1007/s12665-016-5710-6
Sauer TC, Uhler AD (1994) Pollutant source identification and allocation: advances in hydrocarbon fingerprinting. Remed J 5(1):25–50. https://doi.org/10.1002/rem.3440050104
Shin EC, Lee SC, Park JJ (2011) The comparison of remediation efficiency for contaminated soils under vertical drain system by numerical analysis method. J Korean Geosynth Soc 10(1):1–8
Teng Y, Zhou Q, Miao X, Chen Y (2015) Assessment of soil organic contamination in a typical petrochemical industry park in China. Environ Sci Pollut Res 22:10227–10234. https://doi.org/10.1007/s11356-015-4219-y
Tissot B, Welte D (2013) Petroleum formation and occurrence. Springer, Berlin
Wang Z (2003) Fate and identification of spilled oils and petroleum products in the environment by GC-MS and GC-FID. Energ Sources 25(6):491–508. https://doi.org/10.1080/00908310390195570
Wang Z, Stout S (2010) Oil spill environmental forensics fingerprinting and source identification. Elsevier Science, Burlington
Wang Z, Fingas M, Page DS (1999) Oil spill identification. J Chromatogr A 843(1–2):36–411. https://doi.org/10.1016/S0021-9673(99)00120-X
Wang Y, Liang J, Wang J, Gao S (2018) Combining stable carbon isotope analysis and petroleum-fingerprinting to evaluate petroleum contamination in the Yanchang oilfield located on loess plateau in China. Environ Sci Pollut Res 25:2830–2841. https://doi.org/10.1007/s11356-017-0500-6
Wu YX, Lyu HM, Shen JS, Arulrajah A (2018) Geological and hydrogeological environment in Tianjin with potential geohazards and groundwater control during excavation. Environ Earth Sci 77(10):392. https://doi.org/10.1007/s12665-018-7555-7
Zheng C (1990) MT3D: a modular three-dimensional transport model for simulation of adjection, dispersion and chemical reactions of contaminants in ground water systems. S.S. Papadopulos & Associates, Inc., Bethesda
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Park, J.J., Kim, H.J. Use of a forensic geochemical technique and a hydrogeological assessment to determine the source of petroleum hydrocarbon contamination at a foreshore site in Korea. Environ Earth Sci 77, 742 (2018). https://doi.org/10.1007/s12665-018-7928-y
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DOI: https://doi.org/10.1007/s12665-018-7928-y