Recovery of Ammonium in Urine by Biochar Derived from Faecal Sludge and its Application as Soil Conditioner

  • Xiaofeng Bai
  • Zifu Li
  • Yaozhong Zhang
  • Jiewen Ni
  • Xuemei Wang
  • Xiaoqin Zhou
Original Paper
  • 109 Downloads

Abstract

Recovery of ammonium from source-separated urine was achieved through biochar adsorption. Fecal sludge was used to produce biochar by pyrolysis. This method allows for self-treatment of human excrement. Biochar saturated with ammonium was applied to the soil as a conditioner. Results showed that the adsorption capacity of biochar increased with the decrease in particle size and increase in temperature. Kinetic experiments showed that adsorption of ammonium by biochar was in accordance with the pseudo second-order kinetic model, and equilibrium data agreed well with data from the Freundlich isotherm model. Dynamic adsorption experiments showed that biochar could be effectively used as an adsorbent to recover ammonium from actual urine. When the saturated biochar was used as a soil conditioner, the cation exchange capacity of the soil increased from 8.4 cmol/kg (weak nutrient retention and supply capacity) in the beginning of the experiments to 13.6 cmol/kg (medium nutrient retention and supply capacity) at the end of the experiments (140 days). Soil pH increased by 0.9 units compared with that in the blank test.

Keywords

Biochar Urine Fecal sludge Soil conditioner Ammonium adsorption 

Notes

Acknowledgements

The authors express their sincere appreciation for the support of the National Environment and Energy International Science and Technology Cooperation Base, Fundamental Research Funds for the Central Universities (2302014FRF-IC-14-004), the Beijing Science and Technology Program (D141100001214003), the National Key Research and Development Program of China (2016YFD0501402) and National Key Research and Development Plan (2016YFE0115600).

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Copyright information

© Springer Science+Business Media Dordrecht 2017

Authors and Affiliations

  • Xiaofeng Bai
    • 1
  • Zifu Li
    • 1
  • Yaozhong Zhang
    • 1
  • Jiewen Ni
    • 1
  • Xuemei Wang
    • 1
  • Xiaoqin Zhou
    • 1
  1. 1.School of Energy and Environmental Engineering, Beijing Key Laboratory of Resource-oriented Treatment of Industrial PollutantsUniversity of Science and Technology BeijingBeijingChina

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