Abstract
Purpose
This paper illustrates the need of using the agro waste (wheat straw) as a substitute for forest products in paper industry. It aims on using the soda-AQ pulping process for converting waste to fibrous pulp. Further, it emphasizes on use of chlorine dioxide in place of elemental chlorine and hypochlorite during bleaching with aim of reducing the wastewater load and improving the pulp quality.
Methods
Complete chemical characterization of wheat straw was performed. The soda-AQ (anthraquinone) method was opted for cooking and to make a pulp of kappa number 13. The pulp was bleached with elemental chlorine and calcium hypochlorite based sequences. To study the impact of adding chlorine dioxide on paper properties and effluent quality, elemental chlorine and hypochlorite were replaced with dioxide. The total elemental chlorine free bleaching sequence was also studied. The hand sheets were prepared to analyze the bleached and unbleached pulp properties using standard methodology. The effluent quality was studied by measuring the properties COD, BOD, TDS, TSS, TS, colour, lignin and adsorbable organic halides.
Results
Proximate chemical analysis of wheat straw showed that it contains holocellulose 67.3 ± 0.16%, hemicelluloses 39.2 ± 0.7%, cellulose 34.2 ± 0.9%, lignin content 14.9 ± 0.09% and ash 9.2% that mainly composed of silica (7.7%). With soda-AQ process a pulp with 53% yield and good strength properties was obtained. The bleached pulp of chlorine dioxide based sequences was having better strength properties in comparison to chlorine based sequences. Total replacement of elemental chlorine with chlorine dioxide reduced the BOD (52%), COD (49%), colour (43%), lignin (57%) and AOX (63%).
Conclusions
Research concluded that wheat straw can be utilized by paper mills to combat the problem of waste management, air pollution due to its burning and issues of raw material for papermaking. Soda-AQ pulping method was found to be effective for preparing the wheat straw pulp. Use of elemental chlorine free bleaching may prove to be a reliable approach for better environmental management with high pulp characteristics.
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References
Kulkarni, H.D.: Pulp and paper industry raw material scenario-ITC plantation A Case Study. IPPTA. 25(1), 79–82 (2013)
Jain, R.K.: Status of Indian paper industry. Presentation on 14th Cess Training Programme at CPPRI, Saharanpur, U.P. India (2015)
Loow, Y.L., Wu, T.Y., Jahim, J.M., Mohammad, A.W., Teoh, W.H.: Typical conversion of lignocellulosic biomass into reducing sugars using dilute acid hydrolysis and alkaline pretreatment. Cellulose. 23(3), 1491–1520 (2016)
Kaur, D., Bhardwaj, N.K., Lohchab, R.K.: Reduction in waste water load of pulp and paper industry by replacing elemental chlorine with chlorine dioxide at first stage of bleaching. In: National Workshop on Green Chemistry Practices in Teaching, Research and Industry. March 30 2016, pp. 26–30
Bhardwaj, N.K., Goyal, S.K., Gupta, A., Upadhyaya, J.S., Ray, A.K.: Soda and soda-anthraquinone pulping of rice straw. Appita J. 58(3), 180–185 (2005)
Ghosh, U.K.: Short sequence environment friendly bleaching of wheat straw pulp. J. Sci. Ind. Res. 65(1), 68–71 (2006)
Mishra, A.K., Singh, K.K., Khan, T.A., Das, M.M., Pailan, G.H.: Estimates of wheat straw availability and variation in straw quality. Range Manag. Agrofor. 34(1), 112–118 (2013)
Singh, R., Tiwari, S., Srivastva, M., Shukla, A.: Performance study of combined microwave and acid pretreatment method for enhancing enzymatic digest ability of rice straw for bio ethanol production. Plant Knowl. J. 2(4), 157–162 (2013)
Jain, N., Bhatia, A., Pathak, H.: Emission of air pollutants from crop residue burning in india. Aerosol. Air Qual. Res. 14(1), 422–430 (2014)
Tripathi, S., Singh, R.N., Sharma, S.: Emissions from crop /biomass residue burning risk to atmospheric quality. Int. J. Earth Sci. 1(1), 24–30 (2013)
Tripathi, S., Sharma, N., Alam, I., Bhardwaj, N.K.: Green chemistry approaches for pulp bleaching in paper industry. In: National Workshop on Green Chemistry Practices in Teaching, Research and Industry, March 30, 2016, pp. 26–30
Dhir, A., Prakash, N.T., Sud, D.: Studies on coupled biological and photochemical treatment of soda pulp bleaching effluents from agro residue based pulp and paper mill. J. Chem. Technol. Biotechnol. 86(12), 1508–1513 (2011)
Hart, P.W., Rudie, A.W.: Anthraquinone-A review of the rise and fall of a pulping catalyst. Rev. Process: Informally Refereed (Peer-Reviewed). 13(10), 23–31 (2014)
Kumar, S., Saha, T., Sharma, S.: Treatment of pulp and paper mill effluents using novel biodegradable polymeric flocculants based on anionic polysaccharides: a new way to treat the waste water. IRJET 2(4), 1415–1428 (2015)
Hubbe, M.A., Metts, J.R., Hermosilla, D., Blanco, M.A., Yerushalmi, L., Haghighat, F., Elliott, A.: Wastewater treatment and reclamation: a review of pulp and paper industry practices and opportunities. BioResources. 11(3), 7953–8091 (2016)
Yang, L., Fang, L., Huang, L., Zhao, Y., Liu, G.: Evaluating the effectiveness of using ClO2 bleaching as substitution of traditional Cl2 on PCDD/F reduction in a non-wood pulp and paper mill using reeds as raw materials. Green Energy Environ. (2017). https://doi.org/10.1016/j.gee.2017.07.002
Rao, N.J., Kumar, S.: Toxic effluent from pulp and paper mill. Conv. Issues IPPTA. 13(4), 47–51 (1987)
Johnson, P.: Industrial hemp: a critical review of claimed potentials for Cannabis sativa. Tappi J. 82(7), 113–123 (1999)
Savant, D.V., Abdul Rahman, R., Ranade, D.R.: Anaerobic degradation of AOX from pulp and paper industry waste water. Biores. Technol. 97(9), 1092–1104 (2006)
Teh, C.Y., Budiman, P.M., Shak, K.P.Y., Wu, T.Y.: Recent advancement of coagulation–flocculation and its application in wastewater treatment. Ind. Eng. Chem. Res. 55(16), 4363–4389 (2016)
Yao, S., Gao, C., Zhu, H., Jiang, L., Nie, S., Qin, C., Liang, C.: Absorbable organic halide reduction research in elemental chlorine-free bleaching of eucalyptus kraft pulp. J. Residuals Sci. Technol. 14(1), S1–S9 (2017)
Fang, L., Zheng, M., Liu, G., Zhao, Y., Liu, W., Huang, L., Guo, L.: Unexpected promotion of PCDD/F formation by enzyme-aided Cl2 bleaching in non-wood pulp and paper mill. Chemosphere. 168, 523–528 (2017)
Wise, R.E., Murphy, M., D’Addieco, A.A.: Chlorite holocellulose: its fractionation and bearing on summative wood analysis and on studies on the hemicelluloses. Paper Trade J. 112(2), 35–40 (1946)
Updegroff, D.M.: Semimicro determination of cellulose in biological materials. Anal. Biochem. 32(3), 420–424 (1969)
Kaur, D., Bhardwaj, N.K., Lohchab, R.K.: A study on pulping of rice straw and impact of incorporation of chlorine dioxide during bleaching on pulp properties and effluents characteristics. J. Clean. Prod. 170, 174–182 (2018)
Lal, P., Bist, V., Sharma, A., Swaroop, V.: Utilization of soda ash in pulping and bleaching operation as a substitution or partial replacement of sodium hydroxide. J. Forest Prod. Ind. 2(5), 5–12 (2013)
Sridach, W.: The environmentally benign pulping process of non-wood fibers. Suranaree J. Sci. Technol. 17(2), 105–123 (2010)
Kasmani, J.E., Samariha, A.: Some chemical and morphological properties of wheat straw. Middle-East J Sci Res. 8(4), 823–835 (2011)
Plazonić, I., Barbarić-Mikočević, Ž., Antonović, A.: Chemical composition of straw as an alternative material to wood raw material in fibre isolation. Drvna industrija: znanstveno-stručni časopis za pitanja drvne tehnologije 67(2), 119–125 (2016)
Khattak, T.M., Ghazi, J.: Suitability of some non-commercial fast growing wood yielding trees growing in Azad Kashmir for the production of pulp and paper. Pak. J Bot. 33, 729–732 (2001)
Wagner, A., Tobimatsu, Y., Phillips, L., Flint, H., Geddes, B., Lu, F., Ralph, J.: Syringyl lignin production in conifers: Proof of concept in a Pine tracheary element system. Proc. Natl. Acad. Sci. 112(19), 6218–6223 (2015)
Jakate, D.N., Rao, G.V., Swamy, V.S.R., Ch, V., Gopichand, K., Sharma, G.S.R.P.: Soda AQ pulping of rice straw. Tappi J. 64(6), 124 (1981)
Kaur, D., Bhardwaj, N.K., Lohchab, R.K.: Prospects of rice straw as a raw material for paper making. Waste Manag. 60, 127–139 (2017)
Nasser, R.A., Hiziroglu, S., Abdel-Aal, M.A., Al-Mefarrej, H.A., Shetta, N.D., Aref, I.M.: Measurement of some properties of pulp and paper made from date palm midribs and wheat straw by soda-AQ pulping process. Measurement. 62, 179–186 (2015)
Schall, N., Kruger, E., Blum, R., Rubenacker, M.: Soda-AQ pulping of wheat straw and its blending effect on old corrugated cardboard (OCC) pulp properties. Tappsa J. 35–39 (2009)
Mousavi, S.M.M., Hosseini, S.Z., Resalati, H., Mahdavi, S., Garmaroody, E.R.: Papermaking potential of rapeseed straw, a new agricultural-based fiber source. J. Clean. Prod. 52, 420–424 (2013)
Khider, T.O., Omer, S., Taha, O., Shomeina, S.K.: Suitability of Sudanese cotton stalks for alkaline pulping with additives. Iran. J. Energy Environ. 3(2), 167–172 (2012)
Lee, J.S., Shin, S.J.: Chlorine dioxide bleaching properties of sugarcane bagasse pulp and oil palm trunk pulp. J. Korea Tech. Assoc. Pulp Paper Ind. 47(4), 13–20 (2015)
Karim, M.R., Islam, M.N., Malinen, R.O.: Response of Eucalyptus camaldulensis and Acacia mangium kraft pulp in different ECF bleaching options. Wood Sci. Technol. 45(3), 473–485 (2011)
Sharma, N., Godiyal, R.D., Thapliyal, B.P., Anupam, K.: Pulping and bleaching of hydro distillation waste of citronella grass (Cymbopogon winterianus Jowitt) for papermaking. Waste Biomass Valoriz. (2017). https://doi.org/10.1007/s12649-016-9791-y
Parkash, D.: Reduction of toxicity by using chlorine dioxide in paper making. J. Sci. 1(2), 30–35 (2012)
Jain, A., Carpenter, W.:. Effect of chlorine dioxide on bleah plant effluent BOD and colour, NCASI, New York, Technical Bulletin No. 630 (1992)
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Kaur, D., Bhardwaj, N.K. & Lohchab, R.K. Environmental Aspect of Using Chlorine Dioxide to Improve Effluent and Pulp Quality During Wheat Straw Bleaching. Waste Biomass Valor 10, 1231–1239 (2019). https://doi.org/10.1007/s12649-017-0193-6
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DOI: https://doi.org/10.1007/s12649-017-0193-6