Rare Metals

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Statistics of oxidation resistance of Ni–(0–15)Co–(8–15)Cr–(0–5)Mo–(0–10)W–(3–8)Al–(0–5)Ti–(0–10)Ta–0.1C–0.01B superalloys at 1000 °C by compositional variations

  • Si-Jun Park
  • Kyu-Hyuk Lee
  • Seong-Moon Seo
  • Hi-Won Jeong
  • Young-Soo Yoo
  • HeeJin Jang
Article
  • 15 Downloads

Abstract

The effects of alloying elements (Co, Cr, Mo, W, Al, Ti, and Ta) on the oxidation resistance of Ni–(0–15)Co–(8–15)Cr–(0–5)Mo–(0–10)W–(3–8)Al–(0–5)Ti–(0–10)Ta–0.1C–0.01B alloys were studied. The sample compositions were designed by the Box–Behnken method of design of experiments (DOE). The alloying elements show complicated effects on the mass gain due to oxidation, depending on the alloy composition. Al reduces the mass gain largely. The other elements except Al do not appear to exert a strong effect on the oxidation rate on average, but their influences are shown clearly in the alloys with a low Al content. Co, W, and Ta reduce the oxidation rate, while Cr, Mo, and Ti promote oxidation. Ta is the most effective element in reducing the oxidation rate of the alloy with a low Al concentration. It is confirmed that a continuous Al2O3 layer is essentially required for high oxidation resistance. The oxide scale of easily oxidized alloys has various oxides such as NiCr2O4, NiAl2O4, NiO, Cr2O3, CrTaO4, and TiO2.

Keywords

High temperature oxidation Alloy composition Ni-based superalloy Oxidation resistance Design of experiments 

Notes

Acknowledgements

This work was financially supported by the Fundamental R&D Program for Core Technology of Materials (No. 10041233) and the Human Resources Program in Energy Technology of the Korea Institute of Energy Technology Evaluation and Planning (KETEP) (No. 20174030201620).

References

  1. [1]
    Park SJ, Seo SM, Yoo YS, Jeong HW, Jang HJ. Statistical study of the effects of the composition on the oxidation resistance of Ni-based superalloys. J Nanomater. 2015.  https://doi.org/10.1155/2015/929546.Google Scholar
  2. [2]
    Yun DW, Seo SM, Jeong HW, Yoo YS. Effect of refractory elements and Al on the high temperature oxidation of Ni-base superalloys and modelling of their oxidation resistance. J Alloy Compd. 2017;710(5):8.CrossRefGoogle Scholar
  3. [3]
    Donachie MJ, Donachie SJ. Superalloys: A Technical Guide, vol. 2. Ohio: ASM International Ltd; 2002. 1.Google Scholar
  4. [4]
    Guo H, Li D, Zheng L, Gong S, Xu H. Effect of co-doping of two reactive elements on alumina scale growth of β-NiAl at 1200 °C. Corros Sci. 2014;88:197.CrossRefGoogle Scholar
  5. [5]
    Li D, Guo H, Wang D, Zhang T, Gong S, Xu H. Cyclic oxidation of β-NiAl with various reactive element dopants at 1200 °C. Corros Sci. 2013;66:125.CrossRefGoogle Scholar
  6. [6]
    Yan K, Guo H, Gong S. High-temperature oxidation behavior of β-NiAl with various reactive element dopants in dry and humid atmospheres. Corros Sci. 2014;83:335.CrossRefGoogle Scholar
  7. [7]
    Dong Z, Peng X, Guan Y, Li L, Wang F. Optimization of composition and structure of electrodeposited Ni–Cr composites for increasing the oxidation resistance. Corros Sci. 2012;62:147.CrossRefGoogle Scholar
  8. [8]
    Young DJ, Zurek J, Singheiser L, Quadakkers WJ. Temperature dependence of oxide scale formation on high-Cr ferritic steels in Ar–H2–H2O. Corros Sci. 2011;53(6):2131.CrossRefGoogle Scholar
  9. [9]
    Yang Z, Xia GG, Stevenson JW. Evaluation of Ni–Cr-base alloys for SOFC interconnect applications. J Power Sources. 2006;160(2):1104.CrossRefGoogle Scholar
  10. [10]
    Caplan D, Cohen M. The volatilization of chromium oxide. J Electrochem Soc. 1961;108(5):438.CrossRefGoogle Scholar
  11. [11]
    Berthod P. Kinetics of high temperature oxidation and chromia volatilization for a binary Ni–Cr alloy. Oxid Met. 2005;64(3):235.CrossRefGoogle Scholar
  12. [12]
    Tedmon CS. The effect of oxide volatilization on the oxidation kinetics of Cr and Fe–Cr alloys. J Electrochem Soc. 1966;113(8):766.CrossRefGoogle Scholar
  13. [13]
    Qin L, Pei Y, Li S, Zhao X, Gong S, Xu H. Role of volatilization of molybdenum oxides during the cyclic oxidation of high-Mo containing Ni-based single crystal superalloys. Corros Sci. 2017;129:192.CrossRefGoogle Scholar
  14. [14]
    Goebel JA, Pettit FS, Goward GW. Mechanisms for the hot corrosion of nickel-base alloys. Metall Mater Trans. 1973;4(1):261.CrossRefGoogle Scholar
  15. [15]
    Carrasco JG, Adeva P, Aballe M. The role of microstructure on oxidation of Ni–Cr–Al base alloys at 1023 and 1123 K in air. Oxid Met. 1990;33(1–2):1.CrossRefGoogle Scholar
  16. [16]
    Hashizume R, Yoshinari A, Kiyono T, Murata Y, Morinaga M. Development of Ni-based single crystal superalloys for power-generation gas turbines. In: Proceedings of the 10th international symposium on superalloys. Pennsylvania; 2004. 483.Google Scholar
  17. [17]
    Hobbs RA, Brewster GJ, Rae CM, Tin S. Evaluation of ruthenium-bearing single crystal superalloys—a design of experiments. In: Proceedings of the 11th international symposium on superalloys, Pennsylvania; 2008. 171.Google Scholar
  18. [18]
    Park SJ, Seo SM, Yoo YS, Jeong HW, Jang HJ. Effects of Al and Ta on the high temperature oxidation of Ni-based superalloys. Corros Sci. 2015;90:305.CrossRefGoogle Scholar
  19. [19]
    Park SJ, Seo SM, Yoo YS, Jeong HW, Jang HJ. Effects of Ti on high temperature oxidation of Ni-based superalloys. Corros Sci Technol. 2016;15(3):129.CrossRefGoogle Scholar
  20. [20]
    Kim HS, Park SJ, Seo SM, Yoo YS, Jeong HW, Jang HJ. High temperature oxidation resistance of Ni-(5–13) Co-(10–16) Cr-(5–9) W-5Al-(1–1.5) Ti-(3–6) Ta alloys. Met Mater Int. 2016;22(5):789.CrossRefGoogle Scholar
  21. [21]
    Jang HJ, Yun KS, Park CJ. Analysis of the Effects of Ti, Si, and Mo on the resistance to corrosion and oxidation of Fe–18Cr stainless steels by response surface methodology. Korean J Met Mater. 2010;48(8):741.Google Scholar
  22. [22]
    Yang DC, Jang IS, Jang MH, Park CN, Park CJ, Choi J. Optimization of additive compositions for anode in Ni-MH secondary battery using the response surface method. Met Mater Int. 2009;15(3):421.CrossRefGoogle Scholar
  23. [23]
    Nikrooz B, Zandrahimi M. Optimization of process variables and corrosion properties of a multi layer silica sol gel coating on AZ91D using the Box–Behnken design. J Sol–Gel Sci Technol. 2011;59(3):640.CrossRefGoogle Scholar
  24. [24]
    Leigh S, Sezer K, Li L, Grafton-Reed C, Cuttell M. Statistical analysis of recast formation in laser drilled acute blind holes in CMSX-4 nickel superalloy. Int J Adv Manuf Technol. 2009;43(11):1094.CrossRefGoogle Scholar
  25. [25]
    Kircher TA, McMordie BG, Richards K. Use of experimental designs to evaluate formation of aluminide and platinum aluminide coatings. Surf Coat Technol. 1998;108(10):24.CrossRefGoogle Scholar
  26. [26]
    Blaikie Norman. Analyzing Quantitative Data: From Description to Explanation. London: SAGE publications Ltd; 2003.CrossRefGoogle Scholar
  27. [27]
    Huang X, Li J, Hu R, Bai G, Fu H. Evolution of oxidation in Ni–Cr–W alloy at 1100 °C. Rare Met Mater Eng. 2010;39(11):1908.CrossRefGoogle Scholar
  28. [28]
    Sato A, Chiu YL, Reed RC. Oxidation of nickel-based single-crystal superalloys for industrial gas turbine applications. Acta Mater. 2011;59(1):225.CrossRefGoogle Scholar
  29. [29]
    Irving GN, Stringer J, Whittle DP. The oxidation of Co-20% Cr base alloys containing Nb or Ta. Corros Sci. 1975;15(5):337.CrossRefGoogle Scholar
  30. [30]
    Guo H, Wang D, Peng H, Gong S, Xu H. Effect of Sm, Gd, Yb, Sc and Nd as reactive elements on oxidation behaviour of β-NiAl at 1200 °C. Corros Sci. 2014;78:369.CrossRefGoogle Scholar

Copyright information

© The Nonferrous Metals Society of China and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  1. 1.Multi-Material Research Center, Gwangju-Jeonnam DivisionKorea Automotive Technology InstituteGwangjuRepublic of Korea
  2. 2.Department of Advanced Materials EngineeringChosun UniversityGwangjuRepublic of Korea
  3. 3.High Temperature Materials GroupKorea Institute of Materials ScienceChangwonRepublic of Korea
  4. 4.Department of Materials Science and EngineeringChosun UniversityGwangjuRepublic of Korea

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