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Petrogenesis and Ore Genesis of the Late Yanshanian Granites and Associated Porphyry-Skarn W-Mo Deposits from the Yunkai Area of South China: Evidence from the Zircon U-Pb Ages, Hf Isotopes and Sulfide S-Fe Isotopes

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Abstract

There are a wide range of magmatism and mineralization in the Yunkai area of South China during the Late Yanshanian Period, including the newly discovered Michang, Youmapo, Sanchachong and Songwang porphyry-skarn W-Mo deposits. In this study, we obtained zircon U-Pb ages of the ore-bearing biotite granites and their mafic enclaves from 88±1 to 110±1 Ma. Zircons from the granites show Hf isotopic compositions with negative εHf(t) values of -5.9 to -0.6 and calculated Hf model ages (TDM2) of 1.5-1.2 Ga; indicating that the Middle Proterozoic crustal materials may have provided an important source for the magmatic rocks in this district during the Late Yanshanian Period, whereas zircons from the mafic enclaves show positive εHf(t) values of 1.3 to 10.1 with younger Hf model ages (TDM2) of 0.5-1.1 Ga, suggesting a mantle component may have involved in the granitic magma generation. Sulfur isotope study of the sulfide minerals from the W-Mo deposits show a narrow δ34S distribution with most data ranging from -4.2‰ to 5.2‰. In addition, this study reports the first Fe isotopic compositions of pyrite in the W-Mo deposits, which show a uniform distribution range with the values near zero (δ56Fe=0.16‰-0.58‰, average 0.35‰; δ57Fe=0.02‰-0.54‰, average 0.48‰). These data indicate that the ore-forming materials may come from the deep-sourced granitic magma, and the mineralizations show a close relationship with the granitic magmatism during the Late Yanshanian Period. Combining with previous results, we suggest that there is a widespread porphyry-skarn W-Mo mineralization in the Yunkai area during the Late Cretaceous (80-110 Ma), which has a close relationship with the Late Yanshanian magmatism that may have formed during the rollback of the subducted Pacific Plate.

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Acknowledgments

This work was supported by the Fundamental Research Funds for the Central Universities (No. CUG120702). The final publication is available at Springer via https://doi.org/10.1007/s12583-017-0901-1..

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Authors and Affiliations

  1. School of Earth Sciences, China University of Geosciences, Wuhan, 430074, China

    Xinyu Wang & Nengsong Chen

  2. Geological Prospecting Institute of Guangxi Zhuang Autonomous Region, Nanning, 530023, China

    Xinyu Wang

  3. Faculty of Earth Resources, China University of Geosciences, Wuhan, 430074, China

    Zhen Yang & Rui Liu

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  1. Xinyu Wang
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Wang, X., Yang, Z., Chen, N. et al. Petrogenesis and Ore Genesis of the Late Yanshanian Granites and Associated Porphyry-Skarn W-Mo Deposits from the Yunkai Area of South China: Evidence from the Zircon U-Pb Ages, Hf Isotopes and Sulfide S-Fe Isotopes. J. Earth Sci. 29, 939–959 (2018). https://doi.org/10.1007/s12583-017-0901-1

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