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Sonochemistry: a simple and efficient route for biodiesel production from neat and blended vegetable oils using LDH-derived base catalysts

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Abstract

Different layered double hydroxides were synthesized by coprecipitation under low supersaturation and calcined to obtain mixed metal oxides that were tested as heterogeneous catalysts for ultrasound assisted transesterification of oils with methanol for the preparation of fatty acid methyl esters (or) biodiesel using <6:1 methanol:oil molar ratio. Among them, mixed oxides derived by calcining CaAl2-LDH at 700 °C (CaAl2700-CLDH) was the most active catalyst as inferred from its maximum basicity, elucidated by Hammett studies. Various vegetable oils (edible, non-edible and used cooking oils) were successfully transesterified with 80–90 % yield of FAME under ultrasound at 40 °C within 90 min. Under equivalent conditions, the yield of FAME (for sunflower oil) through conventional heating was only 9 % while under ultrasound was 63 %. A single step process was developed for biodiesel production from high free fatty acids (FFA) containing oils such as Jatropha oil by blending it with sunflower oil or used cooking oil (60/40 weight ratio) that gave 89 % yield of FAME in both cases under the optimized reaction conditions. CaAl2700-CLDH showed moderate reusability up to two cycles and decreased thereafter while its activity could be restored by recalcining the recovered catalyst at 700 °C.

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References

  1. Peuker, U.A., Hoffmann, U., Wietelmann, U., Bandelin, S., Jung, R.: Sonochemistry. Ullmann encyclopaedia of industrial chemistry, vol. 33, pp. 689–714. Wiley, Hoboken (2012)

    Google Scholar 

  2. Ma, F., Hanna, M.A.: Biodiesel production: a review1. Bioresour. Technol. 70, 1–15 (1999)

    Article  Google Scholar 

  3. Knothe, G.: Dependence of biodiesel fuel properties on the structure of fatty acid alkyl esters. Fuel Process. Technol. 86, 1059–1070 (2005)

    Article  Google Scholar 

  4. Patil, P.D., Deng, S.: Transesterification of camelina sativa oil using heterogeneous metal oxide catalysts. Energy Fuels 23, 4619–4624 (2009)

    Article  Google Scholar 

  5. Xie, W., Huang, X.: Synthesis of biodiesel from soybean oil using heterogeneous KF/ZnO catalyst. Catal. Lett. 107, 53–59 (2006)

    Article  Google Scholar 

  6. Suppes, G.J., Dasari, M.A., Doskocil, E.J., Mankidy, P.J., Goff, M.J.: Transesterification of soybean oil with zeolite and metal catalysts. Appl. Catal. A: Gen. 257, 213–223 (2004)

    Google Scholar 

  7. Sercheli, R., Vargas, R.M., Schuchardt, U.: Alkylguanidine-catalyzed heterogeneous transesterification of soybean oil. J. Am. Oil Chem. Soc. 76(10), 1207–1210 (1999)

    Article  Google Scholar 

  8. Kannan, S.: Catalytic applications of hydrotalcite-like materials and their derived forms. Catal. Surv. Asia 10(3/4), 117–137 (2006)

    Article  Google Scholar 

  9. Raki, L., Beaudoin, J.J., Mitchell, L.: Layered double hydroxide-like materials: nanocomposites for use in concrete. Cem. Concr. Res. 34, 1717–1724 (2004)

    Article  Google Scholar 

  10. Mora, M., Lopez, M.I., Jimenez-Sanchidrian, C., Ruiz, J.R.: Ca/Al mixed oxides as catalysts for the Meerwein–Ponndorf–Verley reaction. Catal. Lett. 136, 192–198 (2010)

    Article  Google Scholar 

  11. Shumaker, J.L., Crofcheck, C., Tackett, S.A., Santillan-Jimenez, E., Crocker, M.: Biodiesel production from soybean oil using calcined Li–Al layered double hydroxide catalysts. Catal. Lett. 115(1–2), 56–61 (2007)

    Article  Google Scholar 

  12. Sankaranarayanan, S., Antonyraj, C.A., Kannan, S.: Transesterification of edible, non-edible and used cooking oils for biodiesel production using calcined layered double hydroxides as reusable base catalysts. Bioresour. Technol. 109, 57–62 (2012)

    Article  Google Scholar 

  13. Gude, V.G., Patil, P., Martinez-Guerra, E., Deng, S., Nirmalakhandan, N.:Microwave energy potential for biodiesel production. Sustain Chem. Process, 1(5) (2013)

  14. Salamatinia, B., Mootabadi, H., Bhatia, S., Abdullah, A.Z.: Optimization of ultrasonic-assisted heterogeneous biodiesel production from palm oil: a response surface methodology approach. Fuel Process. Technol. 91, 441–448 (2010)

    Article  Google Scholar 

  15. Mootabadi, H., Salamatinia, B., Bhatia, S., Abdullah, A.Z.: Ultrasonic-assisted biodiesel production process from palm oil using alkaline earth metal oxides as the heterogeneous catalysts. Fuel 89, 1818–1825 (2010)

    Article  Google Scholar 

  16. Gelbard, G., Bres, O., Vargas, R.M., Vielfaure, F., Schuchardt, U.E.: 1H nuclear magnetic resonance determination of the yield of the transesterification of rapeseed oil with methanol. J. Am. Oil Chem. Soc. 72(10), 1239–1241 (1995)

    Article  Google Scholar 

  17. Wang, L., Wang, Y., Liu, S., Lu, L., Ma, X., Deng, Y.: Efficient synthesis of dimethyl carbonate via transesterification of ethylene carbonate with methanol over binary zinc-yttrium oxides. Catal. Commun. 16, 45–49 (2011)

    Article  Google Scholar 

  18. Tantirungrotechai, J., Thananupappaisal, P., Yoosuk, B., Viriya-empikul, N., Faungnawakij, K.: One-pot synthesis of calcium-incorporated MCM-41 as a solid base catalyst for transesterification of palm olein. Catal. Commun. 16, 25–29 (2011)

    Article  Google Scholar 

  19. Lee, D., Park, Y., Lee, K.: Heterogeneous base catalysts for transesterification in biodiesel synthesis. Catal. Surv. Asia 13, 63–77 (2009)

    Article  Google Scholar 

  20. Stavarache, C., Vinatoru, M., Maeda, Y., Bandow, H.: Ultrasonically driven continuous process for vegetable oil transesterification. Ultrason. Sonochem. 14, 413–417 (2007)

    Article  Google Scholar 

  21. Thanh, L.T., Okitsu, K., Sadanaga, Y., Takenaka, N., Maeda, Y., Bandow, H.: Ultrasound-assisted production of biodiesel fuel from vegetable oils in a small scale circulation process. Bioresour. Technol. 101, 639–645 (2010)

    Article  Google Scholar 

  22. Georgogianni, K.G., Katsoulidis, A.P., Pomonis, P.J., Kontominas, M.G.: Transesterification of soybean frying oil to biodiesel using heterogeneous catalysts. Fuel Process. Technol. 90, 671–676 (2009)

    Article  Google Scholar 

  23. Ramachandran, K.B., Al-Zuhair, S., Fong, C.S., Gak, C.W.: Kinetic study on hydrolysis of oils by lipase with ultrasonic emulsification. Biochem. Eng. J. 32, 19–24 (2006)

    Article  Google Scholar 

  24. Hingu, S.M., Gogate, P.R., Rathod, V.K.: Synthesis of biodiesel from waste cooking oil using sonochemical reactors. Ultrason. Sonochem. 17, 827–832 (2010)

    Article  Google Scholar 

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Acknowledgments

Authors thank the Ministry of Environment & Forests, New Delhi (F. No. 19/55/2005-RE) and Council of Scientific and Industrial Research, New Delhi for their financial support.

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Authors and Affiliations

  1. Discipline of Inorganic Materials and Catalysis, Central Salt and Marine Chemicals Research Institute (Council of Scientific and Industrial Research), G.B. Marg, Bhavnagar, 364002, India

    Sivashunmugam Sankaranarayanan & S. Kannan

  2. Academy of Scientific and Innovative Research, Central Salt and Marine Chemicals Research Institute, G.B. Marg, Bhavnagar, 364002, India

    Sivashunmugam Sankaranarayanan & S. Kannan

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  1. Sivashunmugam Sankaranarayanan
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  2. S. Kannan
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Correspondence to S. Kannan.

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Sankaranarayanan, S., Kannan, S. Sonochemistry: a simple and efficient route for biodiesel production from neat and blended vegetable oils using LDH-derived base catalysts. Int J Adv Eng Sci Appl Math 5, 210–218 (2013). https://doi.org/10.1007/s12572-013-0098-y

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