Skip to main content
Log in

Microstructure and Properties of Novel Heat Resistant Al–Ce–Cu Alloy for Additive Manufacturing

  • Published:
Metals and Materials International Aims and scope Submit manuscript

Abstract

The microstructure and properties of the novel heat resistant Al–3Ce–7Cu alloy produced by selective laser melting were investigated. Fine Al11Ce3 and Al6.5CeCu6.5 eutectic phases were found in the microstructure. Annealing at temperatures in the 250–400 °C range leads to a decrease in the hardness. Hardness has larger values after annealing at 350 and 400 °C than at 250 °C due to the precipitation of nanosized particles. The low hardness after quenching and aging at 190 °C is caused by quench stress relief and the absence of aging hardening because of poor solid solution. The as-printed yield strength, ultimate tensile strength and elongation are 274 MPa, 456 MPa and 4.4%, respectively. High mechanical properties of the Al–3Ce–7Cu alloy were demonstrated by high temperature tension and compression tests.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10

Similar content being viewed by others

References

  1. E.O. Olakanmi, R.F. Cochrane, K.W. Dalgarno, A review on selective laser sintering/melting (SLS/SLM) of aluminium alloy powders: processing, microstructure, and properties. Prog. Mater. Sci. 74, 401–477 (2015)

    Article  Google Scholar 

  2. C. Galy, E. Le Guen, E. Lacoste, C. Arvieu, Main defects observed in aluminum alloy parts produced by SLM: from causes to consequences. Addit. Manuf. 22, 165–175 (2018)

    Article  Google Scholar 

  3. K. Bartkowiak, S. Ullrich, T. Frick, M. Schmidt, New developments of laser processing aluminium alloys via additive manufacturing technique. Phys. Procedia A 12A, 393–401 (2011)

    Article  Google Scholar 

  4. E. Brandl, U. Heckenberger, V. Holzinger, D. Buchbinder, Additive manufactured AlSi10Mg samples using selective laser melting (SLM): microstructure, high cycle fatigue, and fracture behavior. Mater. Des. 34, 159–169 (2012)

    Article  Google Scholar 

  5. L. Thijs, K. Kempen, J.-P. Kruth, J. van Humbeeck, Fine-structured aluminium products with controllable texture by selective laser melting of pre-alloyed AlSi10Mg powder. Acta Mater. 61(5), 1809–1819 (2013)

    Article  Google Scholar 

  6. F. Calignano, D. Manfredi, E.P. Ambrosio, L. Iuliano, P. Fino, Influence of process parameters on surface roughness of aluminum parts produced by DMLS. Int. J. Adv. Manuf. Technol. 67(9–12), 2743–2751 (2013)

    Article  Google Scholar 

  7. N.T. Aboulkhair, N.M. Everitt, I. Ashcroft, C. Tuck, Reducing porosity in AlSi10Mg parts processed by selective laser melting. Addit. Manuf. 1–4, 77–86 (2014)

    Article  Google Scholar 

  8. N. Read, W. Wang, K. Essa, M.M. Attallah, Selective laser melting of AlSi10Mg alloy: process optimisation and mechanical properties development. Mater. Des. 65, 417–424 (2015)

    Article  Google Scholar 

  9. P. Ma, Y. Jia, K.G. Prashanth, S. Scudino, Z. Yu, J. Eckert, Microstructure and phase formation in Ale20Sie5Fee3Cue1Mg synthesized by selective laser melting. J. Alloys Compd. 657, 430–435 (2016)

    Article  Google Scholar 

  10. K. Schmidtke, F. Palm, A. Hawkins, C. Emmelmann, Process and mechanical properties: applicability of a scandium modified Al-alloy for laser additive manufacturing. Phys. Procedia 12, 369–374 (2011)

    Article  Google Scholar 

  11. A.B. Spierings, K. Dawson, P. Dumitraschkewitz, S. Pogatscher, K. Wegener, Microstructure characterization of SLM-processed Al–Mg–Sc–Zr alloy in the heat treated and HIPed condition. Addit. Manuf. 20, 173–181 (2018)

    Article  Google Scholar 

  12. Y. Shi, P. Rometsch, K. Yang, F. Palm, X. Wu, Characterisation of a novel Sc and Zr modified Al–Mg alloy fabricated by selective laser melting. Mater. Lett. 196, 347–350 (2017)

    Article  Google Scholar 

  13. A.V. Pozdniakov, A.Yu. Churyumov, I.S. Loginova, D.K. Daubarayte, D.K. Ryabov, V.A. Korolev, Microstructure and properties of novel AlSi11CuMn alloy manufactured by selective laser melting. Mater. Lett. 225, 33–36 (2018)

    Article  Google Scholar 

  14. I.I. Novikov, Goryachelomkosttsvetnykhmetallovisplavov (Hot Shortness of Non-ferrous Metals and Alloys) (Nauka, Moscow, 1966)

    Google Scholar 

  15. D.G. Eskin, Suyitno, L. Katgerman, Mechanical properties in the semi-solid state and hot tearing of aluminium alloys. Prog. Mater. Sci. 49, 629–711 (2004)

    Article  Google Scholar 

  16. V.S. Zolotorevsky, N.A. Belov, M.V. Glazoff, Casting Aluminum Alloys (Alcoa Technical Center, Alcoa Center, 2007), p. 530p

    Google Scholar 

  17. ASM International, ASM Handbook. Properties and Selection: Nonferrous Alloys and Special-Purpose Materials, vol. 2 (The Materials Information Company, Materials Park, 2010)

    Google Scholar 

  18. V.S. Zolotorevskiy, A.V. Pozdniakov, Determining the hot cracking index of Al–Si–Cu–Mg casting alloys calculated using the effective solidification range. Int. J. Cast Metals Res. 27(4), 193–198 (2014)

    Article  Google Scholar 

  19. A.V. Pozdniakov, V.S. Zolotorevskiy, O.I. Mamzurina, Determining the hot cracking index of Al–Mg–Zn casting alloys calculated using the effective solidification range. Int. J. Cast Metals Res. 28(5), 318–321 (2015)

    Article  Google Scholar 

  20. C. Brice, R. Shenoy, M. Kral, K. Buchannan, Precipitation behavior of aluminum alloy 2139 fabricated using additive manufacturing. Mater. Sci. Eng. A 648, 9–14 (2015)

    Article  Google Scholar 

  21. A. Plotkowski, O. Rios, N. Sridharan, Z. Sims, K. Unocic, R.T. Ott, R.R. Dehoff, S.S. Babu, Evaluation of an Al–Ce alloy for laser additive manufacturing. Acta Mater. 126, 507–519 (2017)

    Article  Google Scholar 

  22. V.S. Zolotorevskiy, A.V. Pozdniakov, A.Yu. Churyumov, Search for promising compositions for developing new multiphase casting alloys based on Al–Cu–Mg matrix using thermodynamic calculations and mathematic simulation. Phys. Metals Metallogr. 113(11), 1052–1060 (2012)

    Article  Google Scholar 

  23. N.A. Belov, A.V. Khvan, A.N. Alabin, Microstructure and phase composition of Al–Ce–Cu alloys in the Al-rich corner. Mater. Sci. Forum 519–521, 395–400 (2006)

    Article  Google Scholar 

  24. N.A. Belov, A.V. Khvan, The ternary Al–Ce–Cu phase diagram in the aluminum-rich corner. Acta Mater. 55, 5473–5482 (2007)

    Article  Google Scholar 

  25. A.V. Khvan, Optimization of the phase composition of high-tech aluminum alloys with a composite structure based on Ce- and Ca-containing eutectics, Ph.D. thesis, NUST MISIS, Moscow, 2008

Download references

Funding

This work was supported by the Ministry of Education and Science of the Russian Federation in the framework of Increase Competitiveness Program of NUST ‘‘MISiS” and within the framework of the project for creation of high-tech manufacturing ‘‘Creation of material-effective manufacturing of aluminum alloy powders and development of additive technologies for the produce of parts for aircraft control systems”.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to A. Yu. Churyumov.

Ethics declarations

Conflict of interest

No potential conflict of interest was reported by the authors.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Manca, D.R., Churyumov, A.Y., Pozdniakov, A.V. et al. Microstructure and Properties of Novel Heat Resistant Al–Ce–Cu Alloy for Additive Manufacturing. Met. Mater. Int. 25, 633–640 (2019). https://doi.org/10.1007/s12540-018-00211-0

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12540-018-00211-0

Keywords

Navigation