Assessing groundwater hydrochemistry of Malwa Punjab, India

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Abstract

This study investigates the groundwater hydrochemistry (pH, EC, TDS, TH, SO42−, PO43−, NO3, Na2+, K+, Mg2+, Ca2+, F and Cl) of intensively cultivated belt of Malwa Punjab, India. The groundwater was collected from 76 representative sites and analysed for different parameters. Results suggested that in the majority of locations, the TH, TDS, K+, Mg2+, Ca2+ and Cl were within the limit as decided by Bureau of Indian Standards (BIS) for drinking purposes. The proportion of SO42− and PO43− was SO42− > PO43− mg/L in the majority of sampling locations. The Na+ was recorded in a high range 26.05 to 735.5 mg/L indicating Na-rich groundwater in this area. Fluoride ranged 1.59 to 5.07 mg/L in this region, higher than the than permissible range (1.5 mg/L). The NO3 was prominent anthropogenic mineral in groundwater. The suitability of groundwater for drinking and irrigation purposes was also calculated. The water quality index (WQI) suggests that about 80.3% sites have low quality water, unsuitable for drinking purposes. The suitability of groundwater for irrigation purposes was evaluated using SAR and LSI value, which revealed that in the majority of areas, the groundwater is unfit for surface irrigations. This study revealed that overall groundwater of Malwa Punjab is not suitable for drinking as well as agricultural purposes due to excess of some natural and anthropogenic chemicals. The long-term uses of such water could pose serious soil and human health issues in this regions.

Keywords

Groundwater pollution Agricultural contaminants Health impacts Run-off Water quality 

Notes

Acknowledgements

S. Suthar is highly thankful to DST, Govt. of India, New Delhi, for providing financial assistance (No. SR/FTP/ES-28/2012) under Fast Track Young Scientist Scheme. Authors also acknowledge the facility provided by Doon University to conduct this research program.

Supplementary material

12517_2017_3355_MOESM1_ESM.docx (27 kb)
ESM 1 (DOCX 26 kb)

References

  1. Adams S, Titus R, Pietersen K, Tredoux G, Harris C (2001) Hydrochemical characteristics of aquifers near Sutherland in the western Karoo, South Africa. J Hydrol 241(1):91–103.  https://doi.org/10.1016/S0022-1694(00)00370-X CrossRefGoogle Scholar
  2. Alpers CN, Jambor JL, Nordstrom DK (eds) (2000) Sulfate minerals: crystallography, geochemistry and environmental significance. Mineralogical Society of America and the Geochemical Society, Washington, DCGoogle Scholar
  3. Andersen MS, Larsen F, Postma D (2001) Pyrite oxidation in unsaturated aquifer sediments: reaction stoichiometry and rate of oxidation. Environ Sci Technol 35(20):4074–4079.  https://doi.org/10.1021/es0105919 CrossRefGoogle Scholar
  4. APHA-AWWA-WPCF (1994) Satndard methods for the examoination of water and wastewater, 15th edn. American Public Health Association, Washingaton D.C.Google Scholar
  5. BIS (2012) Indian standards—drinking water specifications (2nd revison). Bureau of Indian Standards, New Delhi, p 15Google Scholar
  6. Bishnoi M, Arora S (2007) Potable groundwater quality in some villages of Haryana, India: focus on fluoride. J Environ Biol 28(2):291–294Google Scholar
  7. Bocanegra, E., Hernández, M., Usunoff, E. (eds.) (2005). Groundwater and human development. International Association of Hydrogeologists. Selected Papers on Hydrogeology 6. Heise, Hannover, Germany: 1–278Google Scholar
  8. Brindha K, Elango L, Rajesh VG (2010) Occurrence of chromium and copper in groundwater around tanneries in Chromepet area of Tamil Nadu, India. Indian J Environ Prot 30(10):818–822Google Scholar
  9. CGWB Report (2001) Unpublished report on ground water resources and development potentials of Muktsar district, PunjabGoogle Scholar
  10. Chae GT, Yun ST, Mayer B, Kim KH, Kim SY, Kwon JS, Kim K, Koh YK (2007) Fluorine geochemistry in bedrock groundwater of South Korea. Sci Tot Environ 385(1-3):272–283.  https://doi.org/10.1016/j.scitotenv.2007.06.038 CrossRefGoogle Scholar
  11. Chapman DV (ed) (1996) Water quality assessments: a guide to the use of biota, sediments and water in environmental monitoring (p. 626). E & Fn Spon, London.  https://doi.org/10.4324/NOE0419216001 Google Scholar
  12. Chotpantarat S, Ong SK, Sutthirat C, Osathaphan K (2011) Effect of pH on transport of Pb2+, Mn2+, Zn2+ and Ni2+ through lateritic soil: column experiments and transport modelling. J Environ Sci 23(4):640–648.  https://doi.org/10.1016/S1001-0742(10)60417-2 CrossRefGoogle Scholar
  13. Clarke R, Lawrence A, Foster S (1996) Groundwater: a threatened resource. United Nations Environment Programme. Library:15Google Scholar
  14. Datta SP, Biswas DR, Saharan N, Ghosh SK, Rattan RK (2000) Effect of long-term application of sewage effluents on organic carbon, bioavailable phosphorus, potassium and heavy metal status of soils and content of heavy metals in crops grown thereon. J Indian Soc Soil Sci 48(4):836–839Google Scholar
  15. Dhar BB, Ratan S, Jamal A (1986) Impact of opencast coal mining on water environment—a case study. J Mines Metals Fuels 34(12):596–601Google Scholar
  16. Domagalski JL, Johnson H (2012) Phosphorus and groundwater: establishing links between agricultural use and transport to streams. U.S. Geological Survey, California Water Science Center, Sacramento, Google Scholar
  17. Domenico PA, Schwartz FW (1990) Physical and chemical hydrogeology. Wiley, New York, p 824Google Scholar
  18. Doneen LD (1964) Water quality for agriculture. Department of Irrigation. University of California, Davis, p 48Google Scholar
  19. IPNI (2017) International Plant Nutrition Institute. Punjab—Region Profile. IPNI, 3500 Parkway Lane, Suite 550, Peachtree Corners, Georgia 30092–2844 USAGoogle Scholar
  20. Kabata-Pendias A, Pendias H (1984) Trace elements in soils plants. CRC Press, Boca Raton, FLGoogle Scholar
  21. Kaur R, Bhardwaj R, Arora S (2017) Assessment of groundwater quality for drinking and irrigation purposes using hydrochemical studies in Malwa region, southwestern part of Punjab. India App Wat Sci 7(6):3301–3316.  https://doi.org/10.1007/s13201-016-0476-2 CrossRefGoogle Scholar
  22. Kelley WP (1951) Alkali soils: their formation properties and reclamations. Reinhold, New YorkGoogle Scholar
  23. Kelly WP (1963) Use of saline irrigation water. Soil Sci 95(4):355–391Google Scholar
  24. Krishan G, Rao MS, Kumar CP, Kumar S, Loyal RS, Gill GS, Semwal P (2017) Assessment of salinity and fluoride in groundwater of semi-arid region of Punjab. India Curr World Environ 12(1):34–41.  https://doi.org/10.12944/CWE.12.1.05 CrossRefGoogle Scholar
  25. Kumar M, Ramanathan AL, Rao MS, Kumar B (2006) Identification and evaluation of hydrogeochemical processes in the groundwater environment of Delhi, India. Environ Geol 50(7):1025–1039.  https://doi.org/10.1007/s00254-006-0275-4 CrossRefGoogle Scholar
  26. Kumar M, Kumari K, Singh UK, Ramanathan AL (2009) Hydrogeochemical processes in the groundwater environment of Muktsar, Punjab: conventional graphical and multivariate statistical approach. Environ Geol 57(4):873–884.  https://doi.org/10.1007/s00254-008-1367-0 CrossRefGoogle Scholar
  27. Kumar P, Bansod BK, Debnath SK, Thakur PK, Ghanshyam C (2015) Index-based groundwater vulnerability mapping models using hydrogeological settings: a critical evaluation. Environ Impac Assess Rev 51:38–49.  https://doi.org/10.1016/j.eiar.2015.02.001 CrossRefGoogle Scholar
  28. Kumar P, Thakur PK, Bansod BK, Debnath SK (2016a) Assessment of the effectiveness of DRASTIC in predicting the vulnerability of groundwater to contamination: a case study from Fatehgarh Sahib district in Punjab. India Environ Eart Sci 75(10):879.  https://doi.org/10.1007/s12665-016-5712-4 CrossRefGoogle Scholar
  29. Kumar P, Thakur P K, Bansod B K, Debnath S K (2016b) Groundwater vulnerability assessment of Fatehgarh Sahib district, Punjab, India. Proceedings of India international science festival (IISF)—young scientists’ conclave (YSC), 8–11Google Scholar
  30. Kumar P, Thakur PK, Bansod BK, Debnath SK (2017) Groundwater: a regional resource and a regional governance. Environ Dev Sustain:1–19Google Scholar
  31. Kundu MC, Mandal B (2009) Agricultural activities influence nitrate and fluoride contamination in drinking groundwater of an intensively cultivated district in India. Water, Air, Soil Poll 198(1–4):243–252.  https://doi.org/10.1007/s11270-008-9842-5 CrossRefGoogle Scholar
  32. Liu CW, Jang CS, Chen CP, Lin CN, Lou KL (2008) Characterization of groundwater quality in Kinmen Island using multivariate analysis and geochemical modelling. Hydrolog Proce 22(3):376–383.  https://doi.org/10.1002/hyp.6606 CrossRefGoogle Scholar
  33. Margat J, van der Gun J (2013) Groundwater around the world. Press/Balkema, CRCGoogle Scholar
  34. Naik PK, Awasthi AK, Anand AVSS, Behera PN (2009) Hydrogeochemistry of the Koyna River basin, India. Environ Earth Sci 59(3):613–629.  https://doi.org/10.1007/s12665-009-0059-8 CrossRefGoogle Scholar
  35. Nakadaira H, Nakamura K, Mutoh K, Yamamoto M, Katoh K (2000) Arsenic residues in well water 36 y after endemic arsenic poisoning. Arch. Environ. Health 55(5):364CrossRefGoogle Scholar
  36. Parmar KS, Bhardwaj R (2013) Water quality index and fractal dimension analysis of water parameters. Int J Environ Sci Technol 10(1):151–164.  https://doi.org/10.1007/s13762-012-0086-y CrossRefGoogle Scholar
  37. Patel KP, Pandya RR, Maliwal GL, Patel KC, Ramani VP, George V (2004) Heavy metal content of different effluents and their relative availability in soils irrigated with effluent waters around major industrial cities of Gujarat. J Indian Soc Soil Sci 52(1):89–94Google Scholar
  38. Piper AM (1944) A graphic procedure in the geochemical interpretation of water-analyses. Eos, Trans. Americ. Geophys Union 25(6):914–928CrossRefGoogle Scholar
  39. Raghunath IIM (1987) Groundwater, second (ed). Wiley Eastern Ltd., New Delhi, pp 344–369Google Scholar
  40. Ragone, S., de la Hera, A., Hernández–Mora, N., 2007. The global importance of groundwater in the 21th Century. Proceedings of the International Sysmposium on Groundwater Sustainability. Alicante, Spain, 2006. National Ground Water Association Press, Westerville, Ohio: 1–382Google Scholar
  41. Rajesh R, Brindha K, Murugan R, Elango L (2012) Influence of hydrogeochemical processes on temporal changes in groundwater quality in a part of Nalgonda district, Andhra Pradesh. India. Environ. Earth Sci. 65(4):1203–1213.  https://doi.org/10.1007/s12665-011-1368-2 CrossRefGoogle Scholar
  42. Rajmohan N, Elango L (2005) Nutrient chemistry of groundwater in an intensively irrigated region of southern India. Environ Geol 47(6):820–830.  https://doi.org/10.1007/s00254-004-1212-z CrossRefGoogle Scholar
  43. Rashed MN (2010) Monitoring of contaminated toxic and heavy metals from mine tailings through age accumulation in soil and some wild plants at southeast Egypt. J. Haz. Mat. 178(1–3):739–746.  https://doi.org/10.1016/j.jhazmat.2010.01.147 CrossRefGoogle Scholar
  44. Rabinove CJ, Long Ford RH, Brook Hart JW (1958) Saline water sources of North Dakota. US Geological Survey Water Supply Paper 1428:72Google Scholar
  45. Reddy DV, Nagabhushanam P, Sukhija BS, Reddy AGS, Smedley PL (2010) Fluoride dynamics in the granitic aquifer of the Wailapally watershed, Nalgonda District, India. Chem Geolog 269(3):278–289.  https://doi.org/10.1016/j.chemgeo.2009.10.003 CrossRefGoogle Scholar
  46. Richards LA (1954) Diagnosis and improvement of saline and alkali soils. Agricultural Handbook 60, USDA and IBH Publishing Co. Ltd, New Delhi, India, pp. 98–99Google Scholar
  47. Samborska K, Halas S, Bottrell SH (2013) Sources and impact of sulphate on groundwaters of Triassic carbonate aquifers, Upper Silesia, Poland. J Hydrol 486:136–150.  https://doi.org/10.1016/j.jhydrol.2013.01.017 CrossRefGoogle Scholar
  48. Shivran HS, Kumar D, Singh RV (2006) Improvement of water quality through biological denitrification. J Environ Sci Eng 48(1):57–60Google Scholar
  49. Singh B, Sekhon GS (1976) Nitrate pollution of groundwater from nitrogen fertilizer and animal wastes in the Punjab. India Agricult Environ 3(1):57–67.  https://doi.org/10.1016/0304-1131(76)90007-2 CrossRefGoogle Scholar
  50. Singh CK, Shashtri S, Mukherjee S (2011) Integrating multivariate statistical analysis with GIS for geochemical assessment of groundwater quality in Shiwaliks of Punjab. India Environ Earth Sci 62(7):1387–1405.  https://doi.org/10.1007/s12665-010-0625-0 CrossRefGoogle Scholar
  51. Singh K, Singh D, Hundal HS, Khurana MPS (2013) An appraisal of groundwater quality for drinking and irrigation purposes in southern part of Bathinda district of Punjab, northwest India. Environ Earth Sci 70(4):1841–1851.  https://doi.org/10.1007/s12665-013-2272-8 CrossRefGoogle Scholar
  52. Singh VK, Bikundia DS, Sarswat A, Mohan D (2012) Groundwater quality assessment in the village of Lutfullapur Nawada, Loni, district Ghaziabad, Uttar Pradesh, India. Environ Monitor Assess 184(7):4473–4488.  https://doi.org/10.1007/s10661-011-2279-0 CrossRefGoogle Scholar
  53. Srinivasan JT, Reddy VR (2009) Impact of irrigation water quality on human health: a case study in India. Ecol Econom 68(11):2800–2807.  https://doi.org/10.1016/j.ecolecon.2009.04.019 CrossRefGoogle Scholar
  54. Subba Rao N (2002) Geochemistry of groundwater in parts of Guntur District, Andhra Pradesh, India. Environ Geol 41(5):552–562.  https://doi.org/10.1007/s002540100431 CrossRefGoogle Scholar
  55. Suthar S, Bishnoi P, Singh S, Mutiyar PK, Nema AK, Patil NS (2009) Nitrate contamination in groundwater of some rural areas of Rajasthan, India. J Haz Mat 171(1):189–199.  https://doi.org/10.1016/j.jhazmat.2009.05.111 CrossRefGoogle Scholar
  56. Tamma Rao G, Srinivasa Rao Y, Mahesh J, Surinaidu L, Ratnakar D, Gurunadha Rao VVS, Durga Prasad M (2015) Hydrochemical assessment of groundwater in alluvial aquifer region, Jalandhar District, Punjab, India. Environ Earth Sci 73:8145–8153CrossRefGoogle Scholar
  57. Thankur T, Rishi MS, Naik PK, Sharma P (2016) Elucidating hydrochemical properties of groundwater for drinking and agriculture in parts of Punjab. India. Environ. Earth Sci. 75(6):467–482.  https://doi.org/10.1007/s12665-016-5306-1 CrossRefGoogle Scholar
  58. Thapa R, Gupta S, Reddy DV (2016) Application of geospatial modelling technique in delineation of fluoride contamination zones within Dwarka Basin, Birbhum, India. Geoscience Frontiers.  https://doi.org/10.1016/j.gsf.2016.11.006
  59. Wcislo E, Ioven D, Kucharski R, Szdzui J (2002) Human health risk assessment case study: an abandoned metal smelter site in Poland. Chemosphere 47(5):507–515.  https://doi.org/10.1016/S0045-6535(01)00301-0 CrossRefGoogle Scholar
  60. Wilcox LV (1955) Classification and use of irrigation waters. USDA, Circular 969, Washington, DC, USAGoogle Scholar
  61. Wick K, Heumesser C, Schmid E (2012) Groundwater nitrate contamination: factors and indicators. J Environ Manag 111:178–186.  https://doi.org/10.1016/j.jenvman.2012.06.030 CrossRefGoogle Scholar
  62. WQAA (Water Quality Assessment Authority) (2008) Ground water quality in Bathinda, Mansa and Patiala districts of Punjab. Water Quality Assessment Authority, Ministry of Water Resources, New DelhiGoogle Scholar

Copyright information

© Saudi Society for Geosciences 2018

Authors and Affiliations

  1. 1.School of Environment & Natural ResourcesDoon UniversityDehradunIndia

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