Skip to main content

Advertisement

Log in

Quality of Groundwater in an Area with Intensive Agricultural Activity

  • Original Paper
  • Published:
Exposure and Health Aims and scope Submit manuscript

Abstract

The main objectives of this study were the application of principal component analysis (PCA) for variable selection of an aquifer with a large amount of data record and assessment of the overall quality and the extent of groundwater contamination in Andimeshk, Iran. For this purpose, 17 groundwater quality variables in 46 sampling wells and springs during an eight-year time period (2006–2013) were considered. A PCA was conducted for dry and wet seasons to find out associations between variables, thus reducing the dimensionality of the data. PCA resulted in the reduction of original data to nine variables in wet season encompassing 94.35 % of the total variance and eight variables in dry season accounting for 92.03 % of the total variance. A Procrustes Analysis on the reduced data set showed a high similarity between the original and reduced variables. Groundwater quality index indicated that the most polluted parts of the study area are located in areas of intensive agricultural activities. The results of water quality proved that the effect of geological formations on groundwater quality is mainly due to the influence of EC in terms of TDS, Mg, Ca, Sulfate, and Cu rather than other parameters. The application of animal manure at excessively high rates or the combined application of high rates of manure and nitrogen fertilizer has increased nitrate levels in recent years. Fertilizers may also have an impact on the levels of copper in ground water as it is one of the impurities in these inorganic fertilizers.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Fig. 1
Fig. 2

Similar content being viewed by others

References

  • Akkaraboyina MK, Raju BSN (2012) Assessment of water quality index of river Godavari at Rajahmundry. Univ J Environ Res Technol 2(3):161–167

    CAS  Google Scholar 

  • Al-Kandari NM, Jolliffe IT (2001) Variable selection and interpretation of covariance principal components. Commun Stat 30:339–354

    Article  Google Scholar 

  • Ashori M, Rozbahani A (2004) National necessity for production and development of new and native chemical fertilizers in Iran. In: 1st. Iranian National Seminar on Development of Agrochemical Industries, pp 8–10

  • Becquer T, Quantin C, Sicot M, Boudot JP (2003) Chromium availability in ultramafic soils from New Caledonia. Sci Total Environ 301:251–261

    Article  CAS  Google Scholar 

  • BIS IS 10500 (2012) Indian standard for drinking water. Bureau on Indian standards, 2nd edn. New Delhi

  • Bolan NS, Szgozy AA, Seshadri MJ, Chuasavathi T, Rothrock JR, Panneerselvam P (2010) Uses and management of poultry litter. World Poult Sci J 66:673–698

    Article  Google Scholar 

  • Boy-Roura M, Menció A, Mas-Pla J (2013) Temporal analysis of spring water data to assess nitrate inputs to groundwater in an agricultural area (Osona, NE Spain). Sci Total Environ 452–453:433–445

    Article  Google Scholar 

  • Brindha K, Rajesh R, Murugan R, Elango L (2012) Nitrate pollution in groundwater in some rural area of Nalgonda District, Andhra Pradesh. India. J Env Sci Eng 54(1):64–70

    CAS  Google Scholar 

  • Brown RM, McClelland NI, Deininger RA, Tozer RG (1970) A water quality index: do we dare? Water Sew Works 117:339–343

    Google Scholar 

  • Cadima JFCL, Jolliffe IT (2001) Variable selection and the interpretation of principal subspaces. J Agric Biol Environ Stat 6:62–79

    Article  Google Scholar 

  • Camacho JR, Armienta MA (2000) Natural chromium contamination of groundwater at León Valley, México. J Geochem Explor 68(3):167–181

    Article  Google Scholar 

  • Castilho PD, Chardon WJ, Salomons W (1992) Influence of cattle-manure slurry application on the solubility of cadmium, copper, and zinc in a manured acidic, loamy-sand soil. J Environ Qual 22:689–697

    Article  Google Scholar 

  • Chae GT, Kim K, Yun ST, Kim KH, Kim SO et al (2004) Hydrogeochemistry of alluvial groundwaters in an agricultural area: an implication for groundwater contamination susceptibility. Chemosphere 55:369–378

    Article  CAS  Google Scholar 

  • Chaudhuri S, Ale S, DeLaune P, Rajan N (2012) Spatio-temporal variability of groundwater nitrate concentration in Texas: 1960–2010. J Environ Qual 41:1806–1817

    Article  CAS  Google Scholar 

  • Chitsazan M, Faryabi M, Zarrasvandi AR (2014) Evaluation of river–aquifer interaction in the north part of Dezful–Andimeshk district, SW of Iran. Arab J Geosci 8:1–13

  • Cox TF, Cox MAA (2001) Multidimensional scaling, 2nd edn. Chapman and Hall, Boca Raton

    Google Scholar 

  • Cruz JV, Silva MO, Dias MI, Prudêncio MI (2013) Groundwater composition and pollution due to agricultural practices at Sete Cidades volcano (Azores, Portugal). Appl Geochem 29:162–173

    Article  Google Scholar 

  • Dunteman GH (1989) Principal components analysis. SAGE publications, Newbury Park, pp 1–96

    Google Scholar 

  • Dwivedi SL, Pathak V (2007) A preliminary assignment of water quality index to Mandakini River, Chitrakoot. Indian J Environ Prot 27:1036–1038

    CAS  Google Scholar 

  • European Union’s drinking water standards (1998) Council directive 98/83/EC on the quality of water for human consumption

  • Fraters B, Boumans LJM, Prins HP (2001) Background concentrations of 17 trace metals in Dutch groundwater bodies. RIVM report no. 711701017

  • Frimmel FH, Abbt-Braun G (1999) Basic characterization of reference NOM from central Europe-similarities and differences. Environ Int 25:161–180

    Article  Google Scholar 

  • Garcia EG, Boluda R, Andreu V (1995) Heavy metals incidence in the application of inorganic fertilizers and pesticides to rice farming soils. Environ Pollut 92:19–25

    Article  Google Scholar 

  • Gower JC, Dijksterhuis GB (2004) Procrustes problems. Oxford University Press, Oxford

    Book  Google Scholar 

  • Harilal CC, Hashim A, Arun PR, Baji S (2004) Hydrogeochemistry of two rivers of Kerala with special reference to drinking water quality. J Ecol Environ Conserv 10:187–192

    CAS  Google Scholar 

  • Herrera ML, Espinosa RJ (2008) Impact of agricultural activity and geologic controls on groundwater quality of the alluvial aquifer of the Guadalquivir River (province of Jae´n, Spain): a case study. Environ Geol 54:1391–1402

    Article  Google Scholar 

  • Horton RK (1965) An index number system for rating water quality. J Water Pollut Control Fed 37(3):300–306

    Google Scholar 

  • Jackson JE (1991) A user’s guide to principal components. Wiley, New York, pp 1–563

    Book  Google Scholar 

  • Jackson DA (1995) PROTEST: a Procrustean randomization test of community environment. Ecoscience 2:297–303

    Google Scholar 

  • Jalali M (2005a) Major ion chemistry of groundwaters in the Bahar area, Hamadan, western Iran. Environ Geol 47:763–772

    Article  CAS  Google Scholar 

  • Jalali M (2005b) Nitrates leaching from agricultural land in Hamadan, western Iran. Agr Ecosyst Environ 110:210–218

    Article  CAS  Google Scholar 

  • Jazayeri GR (2004) Production and application economy of chemical N-fertilizers in Iran. In: 1st. Iranian national seminar on development of agrochemical industries, pp 8–10

  • Jolliffe IT (1972) Discarding variables in principal component analysis. I: artificial data. Appl Stat 21:160–173

    Article  Google Scholar 

  • Jolliffe IT (1973) Discarding variables in principal component analysis. II: real data. Appl Stat 22:21–31

    Article  Google Scholar 

  • Jolliffe IT (2002) Principal component analysis, 2nd edn. Springer, New York, pp 1–478

    Google Scholar 

  • Kaown D, Hyun Y, Bae GO, Lee KK (2007) Factors affecting the spatial pattern of nitrate contamination in shallow groundwater. J Environ Qual 36:1479–1487

    Article  CAS  Google Scholar 

  • Khodaei K, Mohamadzadeh H, Naseri HR, Shahsavari AR (2012) An Investigation on nitrate pollution in Dezful-Andimeshk plain and pollution sourcing using 14 N and 18O radioisotopes. Iran J Geol 27:93–111 (in Persian)

    Google Scholar 

  • Ki MG, Koh DC, Yoon H, Kim HS (2015) Temporal variability of nitrate concentration in groundwater affected by intensive agricultural activities in a rural area of Hongseong, South Korea. Environ Earth Sci 74:6147–6161

    Article  CAS  Google Scholar 

  • King JR, Jackson DA (1999) Variable selection in large environmental data sets using principal components analysis. Environmetrics 10:67–77

    Article  Google Scholar 

  • Koh EH, Kaown D, Mayer B, Kang BR, Moon HS, Lee KK (2012) Hydrogeochemistry and Isotopic Tracing of Nitrate Contamination of Two Aquifer Systems on Jeju Island, Korea. J Environ Qual 41:1835–1845

    Article  CAS  Google Scholar 

  • Krishna AK, Satyanarayanan M, Govil PK (2009) Assessment of heavy metal pollution in water using multivariate statistical techniques in an industrial area: a case study from Patancheru, Medak District, Andhra Pradesh, India. J Hazard Mater 167(1–3):366–373

    Article  CAS  Google Scholar 

  • Krzanowski WJ (1987) Selection of variables to preserve multivariate data structure, using principal components. Appl Stat 36(1):22–33

    Article  Google Scholar 

  • Lockhart KM, King AM, Harter T (2013) Identifying sources of groundwater nitrate contamination in a large alluvial groundwater basin with highly diversified intensive agricultural production. J Contam Hydrol 151:140–151

    Article  CAS  Google Scholar 

  • Mahvi AH, Nouri J, Babaei AA, Nabizadeh R (2005) Agricultural activities impact on groundwater nitrate pollution. Int J Environ Sci Technol 2:41–47

    Article  CAS  Google Scholar 

  • Moezzi AA, Torfi K, Albaji M, Mahjoobi M (2009) Optimal application of irrigation water with drip-tape method for Pashmineh Zar croplands, Andimeshk, Southwest Iran. J Food Agric Environ 7:646–650

    Google Scholar 

  • Moncaster SJ, Bottrell SH, Tellam JH, Lloyd JW, Konhauser KO (2000) Migration and attenuation of agrochemical pollutants: insights from isotopic analysis of groundwater sulphate. J Contam Hydrol 43:147–163

    Article  CAS  Google Scholar 

  • Nabi Bidhendi GR, Karbassi AR, Nasrabadi T, Hoveidi H (2007) Influence of copper mine on surface water quality. Int J Environ Res Te 4(1):85–91

    Article  Google Scholar 

  • Nasrabadi T, Abbasi P (2014) Groundwater quality assessment in southern parts of Tehran plain. Iran. Environ Earth Sci 71:2077–2086

    Article  CAS  Google Scholar 

  • Nouri J, Mahvi AH, Babaei AA, Jahed GR, Ahmadpour E (2006) Investigations of heavy metals in groundwater. Pak J Biol Sci 9(3):377–384

    Article  CAS  Google Scholar 

  • Nouri J, Mahvi AH, Jahed GR, Babaei AA (2008) Regional distribution pattern of groundwater heavy metals resulting from agricultural activities. Environ Geol 55:1337–1343

    Article  CAS  Google Scholar 

  • Ooenema O, Liewe LV, Shouman O (2005) Effect of lowering nitrogen and phosphorus surpluses in agriculture on the quality of groundwater and surface water in the Netherlands. J Hydrol 304:289–301

    Article  Google Scholar 

  • Ouyang Y (2005) Evaluation of river water quality monitoring stations by principal component analysis. Water Res 39:2621–2635

    Article  CAS  Google Scholar 

  • Oze C, Bird DK, Fendorf S (2007) Genesis of hexavalent chromium from natural sources in soil and groundwater. Proc Natl Acad Sci USA 104:6544–6549

    Article  CAS  Google Scholar 

  • Patel S, Desai KK (2006) Studies on water quality index of some villages of Surat district. Pollut Res 25:281–285

    Google Scholar 

  • Paul JW (1991) Corn yields and potential for nitrate leaching from manures and inorganic N fertilizer. Ph. D Thesis, University of Guelph, Guelph

  • Pozo C, Ruız-Femenia R, Caballero J, Guillen-Gosalbez G, Jimenez L (2012) On the use of Principal Component Analysis for reducing the number of environmental objectives in multi-objective optimization: application to the design of chemical supply chains. Chem Eng Sci 69:146–158

    Article  CAS  Google Scholar 

  • Pritchard M, Nkandawire T, O’neill JG (2007) Biological, chemical and physical drinking water quality from shallow wells in Malawi: case study of Blantyre, Chiradzulu and Mulanje. Phys Chem Earth 32:1167–1177

    Article  Google Scholar 

  • Rezania AR, Naseri AA, Albaji M (2009) Assessment of soil properties for irrigation methods in North Andimeshk plain, Iran. J Food Agric Environ 7:728–733

    Google Scholar 

  • Rupal M, Tanushree B, Sukalyan C (2012) Quality characterization of groundwater using water quality index in Surat city, Gujarat, India. Int Res J Environ Sci 1:14–23

    Google Scholar 

  • Saad DA (2008) Agriculture-related trends in groundwater quality of the glacial deposits aquifer. Central Wis. doi:10.2134/jeq2007.0053

    Google Scholar 

  • Saeedi M, Abessi O, Sharifi F, Meraji H (2010) Development of groundwater quality index. Environ Monit Assess 163:327–335

    Article  CAS  Google Scholar 

  • Sanchez-Pérez JM, Antiguedad I, Arrate I, Linares CG, Morell I (2003) The influence of nitrate leaching through unsaturated soil on groundwater pollution in an agricultural area of the Basque country: a case study. Sci Total Environ 317:173–187

    Article  Google Scholar 

  • Stamatis G, Parpodis K, Filintas A, Zagana E (2011) Groundwater quality, nitrate pollution and irrigation environmental management in the Neogene sediments of an agricultural region in central Thessaly (Greece). Environ Earth Sci 64:1081–1105

    Article  CAS  Google Scholar 

  • Stevenson FJ (1994) Humus chemistry, genesis, composition, reactions. Wiley, New York

    Google Scholar 

  • Stigter TY, Ribeiro L, Carvalho Dill AMM (2006) Application of a groundwater quality index as an assessment and communication tool in agro-environmental policies–Two Portuguese case studies. J Hydrol 327:578–591

    Article  Google Scholar 

  • Sue X, Wang H, Zhang Y (2013) Health risk assessment of nitrate contamination in groundwater: a case study of an agricultural area in northeast China. Water Resour Manag 27:3025–3034

    Article  Google Scholar 

  • Tizro AT, Voudouris KS (2008) Groundwater quality in the semi-arid region of the Chahardouly basin, West Iran. Hydrol Process 22:3066–3078

    Article  CAS  Google Scholar 

  • Weiner ER (2000) Applications of environmental chemistry, a practical guide to environmental professionals. Lewis Publishers, New York

    Book  Google Scholar 

  • Weng L, Temminghoff EJM, Lofts S, Tipping E, Riemsdijk WHV (2002) Complexation with dissolved organic matter and solubility control of heavy metals in a sandy soil. Environ Sci Technol 36:4804–4810

    Article  CAS  Google Scholar 

  • WHO (1998) Guidelines for drinking water. Second edition, Vol 2

  • Wong SC, Li XD, Zhang G, Qi SH, Min YS (2002) Heavy metals in agricultural soils of the Pearl River Delta, South China. Environ Pollut 119:33–44

    Article  CAS  Google Scholar 

  • Younie MF, Burton DL, Kachanoski RG, Beauchamp EG, Gillham RW (1996) Impact of livestock manure and fertilizer application on nitrate contamination of groundwater final report. RAC project No. 488G, Ontario Ministry of Environment and Energy

  • Zarasvandi A, Mirzaee SY (2009) Geochemistry of Karkheh River sediments, Khuzestan Province, Iran: evidence for natural contamination. Res J Appl Sci 4(1):35–40

    CAS  Google Scholar 

  • Zhang X, Xu Z, Sun X, Dong W, Ballantine D (2013) Nitrate in shallow groundwater in typical agricultural and forest ecosystems in China, 2004–2010. J Environ Sci 25(5): 1007–1014

Download references

Acknowledgments

The authors are grateful to the help of Andimeshk Health Network and Iran Ministry of Energy for providing us with water quality data.

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Mohamad Sakizadeh.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Sakizadeh, M., Faraji, F. & Pouraghniyayi, M.J. Quality of Groundwater in an Area with Intensive Agricultural Activity. Expo Health 8, 93–105 (2016). https://doi.org/10.1007/s12403-015-0185-3

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12403-015-0185-3

Keywords

Navigation