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Water Quality, Exposure and Health

, Volume 7, Issue 4, pp 545–556 | Cite as

Assessment of Fluoride Pollution in Groundwaters of Arid and Semi-arid Regions of Tonalite–Trondjhemite Series in Central India

  • Asmaa Naaz
  • Bijendar Kumar
  • Chandravir Narayan
  • Kriti Shukla
  • AnshumaliEmail author
Original Paper

Abstract

The systematic and comprehensive geochemical analysis of dissolved fluoride (F) in thirty-nine groundwater samples were carried out to understand the spatial and temporal variability, areas of potential risk, and mechanism of fluoride precipitation/solubility in Central India. The dissolved ions showed weathering of carbonate minerals in the study area. Fluoride concentrations were beyond the permissible limit (>1.5 mg/l) in the pre-monsoon and monsoon seasons. The fluoride concentrations showed following spatial variations: urban area > village in agricultural area > village in forest area. The human population living in village, urban, and forest areas reported skin, mouth, and stomach problems due to high fluoride in the groundwater. Rainfall shifted the unsaturated to saturated values of SIC and SIF in the monsoon season. Strong indicators of alkaline condition were effective-CO2 pressure (\( { \log }P_{{{\text{CO}}_{ 2} }} \)) and HCO3 /Ca+2 ratio. The dissolved fluoride showed positive relationship with pH, TDS, and HCO3 /Ca+2 explaining the global variability observed in ground water fluoride.

Keywords

Fluorosis \( { \log }P_{{{\text{CO}}_{ 2} }} \) Archean Saturation index Seasonal variation 

Notes

Acknowledgments

The authors are grateful to Ministry of Human Resource Development, Government of India and Indian School of Mines, Dhanbad for funding the Ph.D. thesis of Ms. Asmaa Naaz (Registration no. 2013DR0060). We are also thankful to the department of Environmental Science and Engineering Dhanbad for providing the logistic support to carry out field monitoring and laboratory analysis. We greatly appreciate the anonymous reviewers for their valuable comments, criticism, and suggestions.

References

  1. Abu Rukah Y, Alsokhny K (2004) Geochemical assessment of groundwater contamination with special emphasis on fluoride concentration, North Jordan. Chemic der Erde 64:171–181CrossRefGoogle Scholar
  2. APHA (1995) Standard methods for the examination of water and wastewater, 19th edn. American Public Health Association, New YorkGoogle Scholar
  3. Ayoob S, Gupta AK (2006) Fluoride in drinking water: a review on the status and stress effects. Crit Rev Environ Sci Technol 36(6):433–487CrossRefGoogle Scholar
  4. Banerjee R, Agarwal M, Mathanwar SR, Roy MK, Maithani PB, Chaki A (2010) Shear-controlled hydrothermal polymetallic mineralisation in southeastern part of Vindhyan–Mahakoshal Basin, Sidhi district, Madhya Pradesh. Gondwana Geol Mag 12:1–18Google Scholar
  5. Carrillo-Rivera JJ, Cardona A, Edmunds WM (2002) Use of abstraction regime and knowledge of hydrogeological conditions to control high-fluoride concentration in abstracted groundwater: San Luis Potosí basin, Mexico. J Hydrol 261(1–4):24–47CrossRefGoogle Scholar
  6. Census of India (2011) Provisional population totals. Ministry of home affairs. Government of IndiaGoogle Scholar
  7. CGWB (2010) Report on ground water quality in shallow aquifers of India. Central Ground Water Board Ministry of Water Resources, Government of IndiaGoogle Scholar
  8. Chae GT, Yun ST, Mayer B, Kim KH, Kim SY, Kwon JS, Kim K, Koh YK (2007) Fluorine geochemistry in bedrock ground water of South Korea. Sci Total Environ 385:272–283CrossRefGoogle Scholar
  9. Chidambaram S, Prasad MBK, Manivannan R, Karmegam U, Singaraja C, Anandhan P, Prasanna MV, Manikandan S (2013) Environmental hydrogeochemistry and genesis of fluoride in groundwaters of Dindigul district, Tamilnadu (India). Environ Earth Sci 68(2):333–342CrossRefGoogle Scholar
  10. Edmond JM, Palmer MR, Measures CI, Grant B, Stallard RF (1995) The fluvial geochemistry and denudation rate of the Guayana Shield in Venezuela, Colombia, and Brazil Geochim. Cosmochim Acta 59:3301–3325CrossRefGoogle Scholar
  11. Edmunds WM, Andrews JN, Burgess WG, Kay RLF, Lee DJ (1984) The evolution of saline and thermal groundwater in the Carnemenellis granite. Miner Mag 48:407–424CrossRefGoogle Scholar
  12. Falvey DA (1999) Groundwater geochemistry. In: Thomas J (ed) Sustainability. Earthwise Magazine- British Geological Survey, New Basford, Nottigham, 13:22Google Scholar
  13. Farooqi A, Masuda H, Kusakabe M, Naseem M, Firdous N (2007) Distribution of highly arsenic and fluoride contaminated groundwater from east Punjab, Pakistan, and the controlling role of anthropogenic pollutants in the natural hydrological cycle. J Geochem 41:213–234CrossRefGoogle Scholar
  14. Gaciri SJ, Davies TC (1993) The occurrence and geochemistry of fluoride in some natural waters of Kenya. J Hydrol 143:395–412CrossRefGoogle Scholar
  15. Godfrey S, Wate S, Kumar P, Swami A, Rayalu S, Rooney R (2006) Health-based risk targets for fluorosis in tribal children of rural Madhya Pradesh. In: India 32nd WEDC international conference, ColomboGoogle Scholar
  16. Handa BK (1975) Geochemistry and genesis of fluoride containing ground waters in India. Ground Water 13(3):275–281CrossRefGoogle Scholar
  17. Hem JD (1970) Study and interpretation of the chemical characteristics of natural water, 2nd edn. US Geological Survey Water Supply Paper 1473Google Scholar
  18. Hitchon B (1995) Fluoride in formation waters. Alberta basin, Canada. Appl Geochem 10:357–367CrossRefGoogle Scholar
  19. Huh Y, Tsoi MY, Zaitsev A, Edmond JM (1998) The fluvial geochemistry of the rivers of Eastern Siberia: I. tributaries of the Lena River draining the sedimentary platform of the Siberian Craton. Geochim Cosmochim Acta 62:1657–1676CrossRefGoogle Scholar
  20. Kabata-Pendias A, Pendias H (2001) Trace element in soils and plants, 3rd edn. CRC Press, Boca RatonGoogle Scholar
  21. Karunakaran, C (1974) Fluorine bearing minerals in India, their geology, mineralogy and geochemistry. Indian Academy of Geological Science, proceedings, symposium on fluorosis, Hyderabad, pp 3–18Google Scholar
  22. Khaiwal R, Garg VK (2007) Hydro-chemical survey of groundwater of Hisar City and assessment of defluoridation methods used in India. Environ Monit Assess 132(1–3):33–43Google Scholar
  23. Kim K, Jeong GY (2005) Factors influencing natural occurrence of fluoride-rich groundwaters: a case study in the southeastern part of the Korean peninsula. Chemosphere 58:1399–1408CrossRefGoogle Scholar
  24. Lee JU, Chon HT, John YW (1997) Geochemical characteristics of deep granitic groundwater in Korea. J Korea Soc Groundw Environ 4:199–211Google Scholar
  25. Mehrotra RC, Verma S, Singh BK (1979) Physico-chemical behavior of hydrated aluminum oxides and associated clay minerals occurring around Pipra, district Sidhi, India. J Therm Anal 16:453–462CrossRefGoogle Scholar
  26. Naseem S, Rfique T, Bshir E, Bhanger MI, Laghari A, Usmani TH (2010) Lithological influences on occurrence of high-fluoride groundwater in Nagar Parkar area, Thar Desert, Pakistan. Chemosphere 78:1313–1321CrossRefGoogle Scholar
  27. Nordstrom DK, Jenne EA (1977) Fluorite solubility equilibria in selected geothermal waters. Geochim Cosmochim Acta 41:175–188CrossRefGoogle Scholar
  28. Panigrahy BK, Raymahashay B (2005) River water quality in weathered limestone: a case study in upper Mahanadi basin, India. J. Earth Syst Sci 111(5):533–543CrossRefGoogle Scholar
  29. Parkhurst DL, Appelo CAJ (1999) User’s guide to phreeqc (version 2)—a computer program for speciation, batch-reaction, one-dimensional transport, and inverse geochemical calculations. USGS water resources investigation report 99-4259. Denver: U.S. Geological Survey. 312Google Scholar
  30. Patel SC, Khalkho R, Patel SK, Sheikh JM, Behera D, Chaudhari S, Prabhakar N (2014) Fluoride contamination of groundwater in parts of eastern India and a preliminary experimental study of fluoride adsorption by natural haematite iron ore and synthetic magnetite. Environ Earth Sci 72:2033–2049CrossRefGoogle Scholar
  31. Pertti L, Backman B (1995) The occurrence and geochemistry of fluorides with special reference to natural waters in Finland. Report of investigation Geological Survey of FinlandGoogle Scholar
  32. Raiswell R, Thomas AG (1984) Solute acquisition in glacial melt waters Fjallsjokull (south-east Iceland), bulk melt waters with closed-system characteristics. J Glaciol 30:35–43Google Scholar
  33. Rao NS (2009) Fluoride in groundwater, Varaha River Basin, Visakhapatnam District, Andhra Pradesh, India. Environ Monit Assess 152:47–60CrossRefGoogle Scholar
  34. Rao NS, Devadas DJ (2003) Fluoride incidence in groundwater in an area of Peninsular India. Environ Geol 45:243–251CrossRefGoogle Scholar
  35. Rao NVR, Rao KS, Schuiling RD (1993) Fluorine distribution in waters of Nalgonda district, Andhra Pradesh, India. Environ Geol 21:84–89CrossRefGoogle Scholar
  36. Robertson FN (1986) Occurrence and solubility controls of trace elements in groundwater in alluvial basins. Regional aquifer systems in the US. Am Water Res Assoc 7:69–80Google Scholar
  37. Roy A, Bandyopadhyay BK (1990) Cleavage development in Mahakoshal Group of rocks of leemanabad-Sihora area, Jabalpur District, Madhya Pradesh. Indian Miner 44(2–3):111–128Google Scholar
  38. Saxena VK, Ahmed S (2003) Dissolution of fluoride in ground water: a water–rock interaction study. Environ Geol 40:1084–1087Google Scholar
  39. Short HE, McRobert GR, Bernard TW, Mannadiyar AS (1937) Mannadinagar endemic fluorosis in Madras presidency. Ind J Med Res 25:553–561Google Scholar
  40. Stumm W, Morgan JJ (1970) Aquatic chemistry. Wiley Interscience, New YorkGoogle Scholar
  41. Susheela AK (1999) Fluorosis management programme in India. An assessment of fluoride in the coastal aquifer of the Bara tract in Bharuch district, Gujarat, India. Curr Sci 77(10):1250–1256Google Scholar
  42. WHO (2004) Guidelines for drinking water quality, 3rd edn. World Health Organization, GenevaGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  • Asmaa Naaz
    • 1
  • Bijendar Kumar
    • 1
  • Chandravir Narayan
    • 1
  • Kriti Shukla
    • 1
  • Anshumali
    • 1
    Email author
  1. 1.Laboratory of Biogeochemistry, Department of Environmental Science and EngineeringIndian School of MinesDhanbadIndia

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