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Water Quality, Exposure and Health

, Volume 7, Issue 4, pp 459–467 | Cite as

A Study on Assessment of Credible Sources of Heavy Metal Pollution Vulnerability in Groundwater of Thoothukudi Districts, Tamilnadu, India

  • C. SingarajaEmail author
  • S. Chidambaram
  • K. Srinivasamoorthy
  • P. Anandhan
  • S. Selvam
Original Paper

Abstract

The study investigates the Heavy Metal Pollution vulnerability of the groundwater in the coastal aquifers of Thoothukudi District, Tamilnadu, India. A total of 80 groundwater samples were collected throughout the entire district. Integrated approach includes pollution evaluation indices, principal component analysis (PCA), and correlation matrix (CM) to evaluate the intensity and source of pollution in groundwater. The average abundance order of heavy metal contents in groundwater samples are: Cr > Cu > Pb > Fe > Zn > Ni > Mn > Cd. These values were calculated for heavy metal pollution index (HPI), heavy metal evaluation index (HEI), and degree of contamination (C d). Spatial distribution map of HPI, HEI, C d indicates that higher indices are observed in the north eastern part of Industrial area (SIPCOT). The Factor score maps suggest that the activities of industries and landfill leachate are pervasive processes. Correlation matrix of heavy metal elements clearly indicates that the groundwater has assimilated with various contaminants from the processes of chemical industries, landfill leachate, and municipal sewage systems in the study area. This study has provided the evidence of effluents discharged from the tannery and auxiliary industries and landfill leachate are the main sources of heavy metal pollution in the groundwater. The current distribution level of heavy metal in the groundwater is of environmental and health concerns and requires attention.

Keywords

Pollution evaluation indices Correlation matrix Heavy metal pollution index Heavy metal evaluation index Degree of contamination 

Notes

Acknowledgments

The authors acknowledge the valuable suggestions given by Prof. Al. Ramanathan, School of Environmental Sciences Jawaharlal Nehru University, New Delhi - 110067, which greatly helped in the final presentation of the paper. The authors are grateful to anonymous referee for the constructive comments and suggestions which led to significant improvements to the manuscript. The authors would also like to thank the results generated by ICP-MS, Department of Earth Sciences, Pondicherry University, Pondicherry, India.

References

  1. Al-Ami MY, Al-Nakib SM, Ritha NM, Nouri AM, Al-Assina A (1987) Water quality index applied to the classification and zoning of Al-Jatsh canal, Bagdad, Iraq. J Environ Sci Health A 22:305–319Google Scholar
  2. Alloway BJ, Ayres DC (1997) Chemical principles of environmental pollution. In: Wastes and their disposal, 2nd edn. Blackie Acad. Professional, London, pp 353–357Google Scholar
  3. Backman B, Bodis D, Lahermo P, Rapant S, Tarvainen T (1997) Application of a groundwater contamination index in Finland and Slovakia. Environ Geo 36:55–64. doi: 10.1007/s002540050320 CrossRefGoogle Scholar
  4. Bhuiyan MAH, Islam MA, Dampare SB, Parvez L, Suzuki S (2010) Evaluation of hazardous metal pollution in irrigation and drinking water systems in the vicinity of a coal mine area of northwestern Bangladesh. J Hazard Mater 179(1–3):1065–1077CrossRefGoogle Scholar
  5. Bhuiyan MAH, Suruvi NI, Dampare SB, Islam MA, Quraishi SB, Ganyaglo S, Suzuki S (2011) Investigation of the possible sources of heavy metal contamination in lagoon and canal water in the tannery industrial area in Dhaka, Bangladesh. Environ Monit Assess 175(1–4):633–649CrossRefGoogle Scholar
  6. Butow E, Holzbecher E, Kob E (1989) Approach to model the transport of leachates from a landfill site including geochemical processes. In: Kobus HE, Kinzelbach W (eds) Contaminant transport in groundwater. Balkema, Rotterdam, pp 183–190Google Scholar
  7. CGWB (2009) South Eastern Coastal Region, District groundwater brochure, Thoothukudi District, Tamil Nadu. Ministry of water resources, Chennai, TamilnaduGoogle Scholar
  8. Chidambaram S, Karmegam U, Prasanna MV, Sasidhar P (2012) A study on evaluation of probable sources of heavy metal pollution in groundwater of Kalpakkam region, South India. Environmentalist. doi: 10.1007/s10669-012-9398-1 Google Scholar
  9. Clark J (2006) Rivers and their catchments: impact of landfill on water quality, Earth Sci. Branch, Scottish Natural Heritage, p 2Google Scholar
  10. Cole M, Hood L, McDermott R (1984) Ecological invalidity as an axiom of experimental cognitive psychology. Harvard Univ. Press, Cambridge, MassGoogle Scholar
  11. Damodhar U, Reddy V (2012) Assessment of trace metal pollution of water and sediment of river Gadilam (Cuddalore, South East Coast of India) receiving sugar industry effluents. Cont J Environ Sci 6(3):8–24Google Scholar
  12. Dragovıć S, Mihailovıć N, Gajıć B (2008) Heavy metals in soils: distribution, relationship with soil characteristics and radionuclide’s and multivariate assessment of contamination sources. Chemosphere 72(3):491–549. doi: 10.1016/j.chemosphere.2008.02.063 CrossRefGoogle Scholar
  13. Edet AE, Offiong OE (2002) Evaluation of water quality pollution indices for heavy metal contamination monitoring. A study case from Akpabuyo–Odukpani area, Lower Cross River Basin, (southeastern Nigeria). Geo J 57:295–304. doi: 10.1023/B:GEJO.0000007250.92458.de Google Scholar
  14. Franco-Uría A, López-Mateo C, Roca E, Fernández-Marcos ML (2009) Source identification of heavy metals in pastureland by multivariate analysis in NW Spain. J Hazard Mater 165:1008–1015CrossRefGoogle Scholar
  15. Gotelli NJ, Ellison AM (2004) A primer of ecological statistics, 1st edn. Sinauer Associates, Sunder land, p 492Google Scholar
  16. Hem JD (1985) Study and interpretation of the chemical characteristics of natural water (3d ed.): U.S. Geol Surv Water-Supply Paper 2254:155–156Google Scholar
  17. Horton RK (1965) An index systems for rating water quality. J Water Pollut Control Fed 37(3):300–306Google Scholar
  18. Howitt D, Cramer D (2005) Introduction to SPSS in psychology: with supplement for releases 10, 11, 12 and 13. Pearson, HarlowGoogle Scholar
  19. Kasprzak KS, Sunderman FW, Salnikow K (2003) Nickel Carcinogenesis. Mutat Res 533:67–97CrossRefGoogle Scholar
  20. Keswick BH (1984) Sources of groundwater pollution. In: Ogbonna et al. (eds) Chemical characteristics and fertilizing value of primary sludge from tannery effluent treatment plantGoogle Scholar
  21. Mohan SV, Nithila P, Reddy SJ (1996) Estimation of heavy metal in drinking water and development of heavy metal pollution index. J Environ Sci Health A31:283–289CrossRefGoogle Scholar
  22. Prasad B, Bose JM (2001) Evaluation of the heavy metal pollution index for surface and spring water near a limestone mining area of the lower Himalayas. Environ Geol 41:183–188CrossRefGoogle Scholar
  23. Prasanna MV, Praveena SM, Chidambaram S, Nagarajan R, Elayaraja A (2012) Evaluation of water quality pollution for heavy metal contamination monitoring: a case study from Curtin Lake. Environ Earth Sci, Miri City. doi: 10.1007/s12665-012-1639-6 Google Scholar
  24. Reddy SJ (1995) Encyclopaedia of environmental pollution and control. Environ Media Karlia 1:342Google Scholar
  25. Selvam S (2014) Irrigational feasibility of groundwater and evaluation of hydrochemistry facies in the SIPCOT industrial area, South Tamilnadu, India: a GIS approach. Water Qual Expo Health. doi: 10.1007/s12403-014-0146-2 Google Scholar
  26. Singaraja C (2014) A study on the hydrogeochemistry of groundwater in Tuticorin district of Tamilnadu, India. Unpublished Ph.D thesis, Department of Earth Sciences, Annamalai UniversityGoogle Scholar
  27. Singaraja C, Chidambaram S, Anandhan P, Prasanna MV, Thivya C, Thilagavathi R (2012) A study on the status of fluoride ion in groundwater of coastal hard rock aquifers of south India. Arab J Geosci. doi: 10.1007/s12517-012-0675-6 Google Scholar
  28. Singaraja C, Chidambaram S, Anandhan P, Prasanna MV, Thivya C, Thilagavathi R, Sarathidasan J (2013a) Hydrochemistry of groundwater in a coastal region and its repercussion on quality, a case study—Thoothukudi District, Tamilnadu. Arab J Geosci, India. doi: 10.1007/s12517-012-0794-0 Google Scholar
  29. Singaraja C, Chidambaram S, Anandhan P, Prasanna MV, Thivya C, Thilagavathi R (2013b) A study on the status of saltwater intrusion in the coastal hard rock aquifer of South India. Environ Dev Sustain. doi: 10.1007/s10668-014-9554-5 Google Scholar
  30. Tariq RS, Shah MH, Shaheen N, Khalique A, Manzoor S, Jaffar M (2005) Multivariate analysis of selected metals in tannery effluents and related soil. J Hazard Mater A122:17–22CrossRefGoogle Scholar
  31. Tariq SR, Shaheen N, Khalique A, Sha MH (2010) Distribution, correlation, and source apportionment of selected metals in tannery effluents, related soils, and groundwater—a case studies from Multan, Pakistan. Environ Monit Assess 166:303–312CrossRefGoogle Scholar
  32. USEPA (1991) National primary drinking water regulations: radionuclide’s; proposed, EPA. Fed Reg 56:33050–33127Google Scholar
  33. Venkatramanan S, Chung SY, Kim TH, Prasanna MV, Hamm SY (2014) Assessment and distribution of metals contamination in groundwater: a case study of Busan City. Water Qual Expo Health, Korea. doi: 10.1007/s12403-014-0142-6 Google Scholar
  34. WHO (1996) Guidelines for drinking water, recommendations. World Health Organization, GenevaGoogle Scholar
  35. WHO (2004) Guidelines for drinking water quality Drinking water quality control in small community supplies. WHO, GenevaGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2015

Authors and Affiliations

  • C. Singaraja
    • 1
    Email author
  • S. Chidambaram
    • 2
  • K. Srinivasamoorthy
    • 3
  • P. Anandhan
    • 2
  • S. Selvam
    • 4
  1. 1.Department of GeologyPresidency CollegeChennaiIndia
  2. 2.Department of Earth SciencesAnnamalai UniversityAnnamalai NagarIndia
  3. 3.Department of Earth SciencesPondicherry UniversityPondicherryIndia
  4. 4.Department of GeologyV.O.Chidambaram CollegeTuticorinIndia

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