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Assessment of Water Quality of a River-Dominated Estuary with Hydrochemical Parameters: A Statistical Approach

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Abstract

This study was aimed (1) to evaluate the water quality of Chalakudy river, the fifth longest (145.5 km) river of Kerala (South India), by assessing the general hydrochemical parameters like temperature, dissolved oxygen (DO), salinity and chemical oxygen demand (COD) on a seasonal and spatial basis and (2) to manifest the data using statistical tools like analysis of variance, dendrograms, non-metric multidimensional scaling (nMDS), trellis diagrams, discriminant analysis etc., so as to identify the factors and sources influencing the quality of river water. The sustainability of Chalakudy river estuarine ecosystem is of great significance as thousands of people depend on this particular river, and it is one of the very few rivers in the state of Kerala which is having relics of riparian vegetation in substantial level. DO showed significant differences between estuarine stations and other stations in the trellis diagram. Distribution of COD in water, arranged over seasons showed high seasonal variability at all stations and dendrogram delineated two distinct clusters, representing monsoon and non-monsoon seasons. nMDS drawn to group the stations based on salinity showed two distinct groups of stations (viz. estuarine and riverine). Wider separation (in Canonical discriminant analysis) between estuarine and non-estuarine stations of parameters particularly during nonmonsoon seasons with lower DO, high salinity and high COD indicated higher level of pollution during November to March. Chalakudy town and ferry regions of the riverine stations and the estuarine stations showed considerable levels of pollution.

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References

  • American Public Health Association (APHA) (1999) In: Eaton AD, Clesceri LC, Greenberg AE (eds) Standard methods for examination of water and wastewater. APHA, Washington

  • Anderson JA (1979) Multivariate logistic compounds. Biometrika 66:7–16

    Article  Google Scholar 

  • Anu G, Nair SM, Kumar NC, Jayalakshmi KV (2011) Statistical significance of biomonitoring of marine algae for trace metal levels in a coral environment. Environ Forensics 12:98–105

    Article  CAS  Google Scholar 

  • Babu KN, Padmalal D, Maya K, Sreeja R, Arun PR (2007) Quality of surface and ground water around tile and brick clay mines in Chalakudy river basin, Southwestern India. J Geol Soc India 169:279–284

    Google Scholar 

  • Beck NG, Fisher AT, Bruland KW (2001) Modeling water, heat, and oxygen budgets in a tidally dominated estuarine pond. Mar Ecol Prog Ser 217:43–58

    Article  Google Scholar 

  • Chattopadhyay S, Asarani L, Sangeetha PV (2005) Water quality variations as linked to land use pattern: a case study in Chalakudy river basin, Kerala. Curr Sci 89:2163–2169

    CAS  Google Scholar 

  • Culter JK (1999) City of Venice discharge ambient water quality and benthic monitoring. Mote Technical Report No. 642, Mote Marine Laboratory, Sarasota. http://hdl.handle.net/2075/2860. Accessed 30 Aug 2013

  • Dallas H, Day J (2004) The effect of water quality variables on aquatic ecosystems: a review. WRC Technical Report No. 224/04, Water Research Commission, Pretoria, South Africa

  • Falkowski PG (1994) The role of phytoplankton photosynthesis in global biogeochemical cycles. Photosynth Res 39:235–258

    Article  CAS  Google Scholar 

  • Gibrilla A, Bam EKP, Adomako D, Ganyaglo S, Osae S, Akiti TT, Kebede S, Achoribo E, Ahialey E, Ayanu G, Agyeman EK (2011) Application of water quality index (wqi) and multivariate analysis for groundwater quality assessment of the Birimian and Cape Coast granitoid complex: Densu River basin of Ghana. Water Qual Expo Health 3:63–78

    Article  CAS  Google Scholar 

  • Govindasamy C, Kannan L, Azariah J (2000) Seasonal variation in the physico-chemical properties and primary production in the coastal water biotops of Coramandal coast. Indian J Environ Biol 21:1–7

    Google Scholar 

  • Grasshoff K, Erhardt M (1999) Determination of salinity. Methods of Seawater Analyses. Chemie, Weinhein

    Book  Google Scholar 

  • Hardy HT, Apts CW (1984) The sea-surface microlayer: phytoneuston productivity and effects of atmospheric particulate matter. Mar Biol 82:293–300

    Article  Google Scholar 

  • Hoeksema BW (2012) Evolutionary trends in onshore–offshore distribution patterns of mushroom coral species (Scleractinia: Fungiidae). Contrib Zool 81:199–221

    Google Scholar 

  • Iwanyshyn M, Ryan MC, Chu A (2008) Separation of physical loading from photosynthesis/respiration processes in rivers by mass balance. Sci Total Environ 390:205–214

    Article  CAS  Google Scholar 

  • Jayalakshmy KV (1998) Biometric studies on trophic level relations in the Indian Ocean. Ph.D. Thesis submitted to Cochin University of Science and Technology, Cochin, India. pp 434

  • Koffi KK, Gbotto AA, Malice M, Dje Y, Bertin P, Baudoin JP, Bi IAZ (2008) Morphological and allozyme variation in a collection of Cucumeropsis mannii Naudin (Cucurbitaceae) from Cote d’Ivoire. Biochem Syst Ecol 36:777–789

    Article  CAS  Google Scholar 

  • Kotti ME, Vlessids AG, Thanasoulias NC, Evmiridis NP (2005) Assessment of River water quality in northwestern : Greece. Water Resour Manag 19:77–94

    Article  Google Scholar 

  • Kruskal JB, Wish M (1978) Multidimensional Scaling. Sage university paper series on quantitative applications in the social sciences. Sage, Newbury Park, pp 7–11

    Google Scholar 

  • Maya K (2005) Studies on the nature and chemistry of sediments and water of Periyar and Chalakudy rivers, Kerala, India, p 276 . Ph.D. Thesis. Cochin University of Science and Technology, Kalamassery, Kochi, Kerala, India

  • Maya K, Babu KN, Padmalal D, Seralathan P (2007) Hydrochemistry and dissolved nutrient flux of small catchment rivers, south-western India. Chem Ecol 23:13–27

    Article  CAS  Google Scholar 

  • Neal C, Neal M, Hill L, Wickham H (2006) River water quality of the River Cherwell. An agricultural clay-dominated catchment in the upper Thames Basin, Southeastern England. Sci Total Environ 360:272–289

    Article  CAS  Google Scholar 

  • Padma P (2008) Nutrient mobility in Chalakudy River, typified with riparian buffer zone and its adjoining estuary: spatiotemporal manifestation, Ph.D. Thesis, Cochin University of Science and Technology, Kerala, India

  • Padma P, Nair SM (2010) Assessing the P fractionation in a tropical river-estuarine system of South India. Chem Ecol 26:453–466

    Article  CAS  Google Scholar 

  • Padmalal D, Maya K, Sreebha K, Sreeja R (2008) Environmental effects of river sand mining: a case from the river catchments of Vembanad lake. Southwest coast India Environ Geol 54:879–889

    Article  CAS  Google Scholar 

  • Purushothaman P, Chakrapani GJ (2007) Heavy metals fractionation in Ganga river sediments, India. Environ Monit Assess 132:475–489

    Article  CAS  Google Scholar 

  • Raghavan R, Prasad G, Anvar-Ali PH, Pereira B (2008) Exotic fish species in a global biodiversity hot spot: observations from River Chalakudy, part of Western Ghats, Kerala, India. Biol Invasions 10:37–40

    Article  Google Scholar 

  • Santhosh V, Padmalal D, Baijulal B, Maya K (2013) Brick and tile clay mining from the paddy lands of Central Kerala (southwest coast of India) and emerging environmental issues. Environ Earth Sci 68:2111–2121

    Article  CAS  Google Scholar 

  • Singh UB, Ahluwalia AS, Jindal R, Sharma C (2013) Water quality assessment of some freshwater bodies supporting vegetation in and around Chandigarh (India), using multivariate statistical methods. Water Qual Expo Health 5:149–161

    Article  CAS  Google Scholar 

  • Sneath PHA, Sokal RR (1973) Numerical taxonomy. Freeman, San Francisco

    Google Scholar 

  • Snedecor GW, Cochran WG (1967) Statistical methods, 6th edn. Oxford and IBH Publishing Company, New Delhi

    Google Scholar 

  • Sokal RR, Rohlf JF (1981) Biometry-the principles and practice of statistics in biological research, 2nd edn. W.H. Freeman and Company, New York

    Google Scholar 

  • Soleimani A, Ahmadikhah A, Soleimani S (2009) Performance of different greenhouse cucumber cultivars (Cucumis sativus L.) in southern Iran. Afr J Biotechnol 8:4077–4083

    Google Scholar 

  • Song MW, Hunang P, Zhang H, Xie KZ, Wang XH, He GX (2011) Water quality of a tributary of the Pearl River, the Beijiang, Southern China: implications from multivariate statistical analyses. Environ Monit Assess 172:589–603

    Article  Google Scholar 

  • Sreebha S, Padmalal D (2011) Environmental impact assessment of sand mining from the small catchment rivers in the southwestern coast of India: A case study. Environ Manag 47:130–140

    Article  Google Scholar 

  • Stumm W, Morgan JJ (1996) Aquatic chemistry; chemical equilibria and rates in natural waters. Wiley, New York

    Google Scholar 

  • Tuckey JW (1949) One degree of freedom non additivity. Biometric 5:232–242

    Google Scholar 

  • USEPA (United States Environmental Protection Agency) (2012) Coastal Watershed Factsheets - Estuaries and Your Coastal Watershed. http://water.epa.gov/type/oceb/fact5.cfm. Accessed 30 Aug 2013

  • Vannote R, Sweeney B (1980) Geographic analysis of thermal equilibria: a conceptual model for evaluating the effect of natural and modified thermal regimes on aquatic insect communities. Am Nat 115:667–695

    Article  Google Scholar 

  • Xia X, Yang Z, Wang R, Meng L (2005) Contamination of oxygen-consuming organics in the Yellow River of China. Environ Monit Assess 110:185–202

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The authors thank Cochin University of Science and Technology for the facilities. The authors also wish to acknowledge the anonymous reviewer for his/her detailed and helpful comments to the manuscript.

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Correspondence to S. M. Nair.

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Padma, P., Sheela, V.S., Suryakumari, S. et al. Assessment of Water Quality of a River-Dominated Estuary with Hydrochemical Parameters: A Statistical Approach. Water Qual Expo Health 5, 197–214 (2014). https://doi.org/10.1007/s12403-014-0115-9

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