Skip to main content
Log in

Quality of Groundwater Resources in Chikhwawa, Lower Shire Valley, Malawi

  • Published:
Water Quality, Exposure and Health Aims and scope Submit manuscript

Abstract

Groundwater resources in some parts of the lower section of the Shire River valley, Malawi, are not potable for rural domestic water supply due to high salinity. Knowledge of spatial variation of water quality is essential in locating and sustaining usable water supplies. In this study, a comprehensive assessment of the quality of groundwater from the area has been conducted to establish a spatial variation of major ions and general groundwater quality. World Health Organisation (WHO) guidelines for sodium (200 mg/l), chloride (250 mg/l), sulphate (250 mg/l), magnesium (30 mg/l) and calcium (75 mg/l) in drinking water were exceeded by 42%, 29%, 15%, 70% and 53% for all groundwater samples, respectively. The concentrations of analysed solutes are very wide in range, suggesting that the hydrochemistry is controlled by several intermixed processes such as saline water mixing and water–rock interaction. Based on the interpretation of the cumulative probability curve for TDS content, groundwater samples are grouped into three groups, as follows: (1) Group 1 waters (51%) that are relatively poor in Cl, representing fresh groundwater affected mainly by weathering reactions; (2) Group 2 waters (45%) relatively enriched in Cl, indicating considerable effects of rock-water interaction and mixing with saline water; (3) Group 3 waters (4%) enriched in Cl, representing the saline groundwater resources. High total hardness (TH) and total dissolved solids (TDS) (in several places) render the groundwater, in large sections of the study area, unsuitable for domestic and irrigation purposes. Results reported in this study provide baseline data towards the utility of groundwater resources in the area.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  • Al-Bassam AM, Al-Rumikhani YA (2003) Integrated hydrochemical method of water quality assessment for irrigation in arid areas: application to the Jilh aquifer, Saudi Arabia. J Afr Earth Sci 36:345–356

    Article  CAS  Google Scholar 

  • Allison JD, Brown DS, Novo-Gradac KJ (1991) MINTEQA2, a geochemical assessment model for environmental systems. Report EPA/600/3-91/0-21, USEPA, Athens, Georgia

  • Alobaidy AHMJ, Abid HS, Maulood BK (2010) Application of water quality index for assessment of Dokan Lake ecosystem, Kurdistan Region. Iraq J Water Resour Prot 2:792–798

    Article  CAS  Google Scholar 

  • American Public Health Association (APHA) (2005) Standard methods of the examination of water and wastewater, 21st edn. APHA/AWWA/WPCF, Washington

    Google Scholar 

  • Appelo CAJ, Postma D (2005) Geochemistry, groundwater and pollution. Balkema, Rotterdam

    Book  Google Scholar 

  • Avvannavar SM, Shrihari S (2008) Evaluation of water quality index for drinking purposes for river Netravathi, Mangalore, South India. Environ Monit Assess 143:279–290

    Article  CAS  Google Scholar 

  • Bath AH (1980) Hydrochemistry in groundwater development: report on an advisory visit to Malawi. British Geological Survey report, WD/OS/80/20

  • Bloomfield K (1966) 1:1,000,000 geological map of Malawi. Geol Surv Malawi

  • Bradford RB (1973) Groundwater reconnaissance study: lower Shire valley. Report RB/5 File T601 Geol Surv Malawi

  • Bovolo CI, Parkin G, Sophocleous M (2009) Groundwater resources, climate and vulnerability. Environ Res Lett 4(3):1–4

    Article  Google Scholar 

  • Carter GS, Bennet JD (1973) The geology and mineral resources of Malawi. Bull 6 Geol Surv Malawi

  • Castaing C (1991) Post-Pan-African tectonic evolution of South Malawi in relation to the Karroo and recent East African rift systems. Tectonophysics 191:55–73

    Article  Google Scholar 

  • Chae G-T, Yuna S-T, Kangjoo K, Mayer B (2006) Hydrogeochemistry of sodium-bicarbonate type bedrock groundwater in the Pocheon spa area, South Korea: water–rock interaction and hydrologic mixing. J Hydrol 321:326–343

    Article  CAS  Google Scholar 

  • Chapola LS, Kaphwiyo CE (1992) The Malawi rift: geology, tectonics and seismicity. Tectonophysics 209:159–164

    Article  Google Scholar 

  • Chappelle FH (1983) Groundwater geochemistry and calcite cementation of the Aquia Aquifer in southern Maryland. Water Resour Res 19(2):545–558

    Article  Google Scholar 

  • Davis RW (1969) Groundwater, gravity and rift valleys in Malawi. Groundwater 7(2):34–36

    Article  Google Scholar 

  • Drever JI (1997) The geochemistry of natural waters, 3rd edn. Prentice-Hall, Englewood Cliffs

    Google Scholar 

  • Drever JI, Smith CL (1978) Cyclic wetting and drying of the soil zone as an influence on the chemistry of groundwater in arid terrains. Am J Sci 278:1448–1454

    Article  CAS  Google Scholar 

  • Dongarrà G, Mann E, Sebation G, Varrica D (2009) Geochemical characteristics of waters in mineralised area of Peloritani Mountains (Sicily, Italy). Appl Geochem 24:900–914

    Article  Google Scholar 

  • Eaton FM (1950) Significance of carbonates in irrigation waters. Soil Sci 69:123–133. doi:10.1097/00010694-195002000-00004

    Article  CAS  Google Scholar 

  • Epule ET, Peng C, Miriele MW, Mafany NM (2011) Well water quality and public health implications: the case of four neighbourhoods of the City of Douala Cameroon. Glob J Health Sci 3(2):75–83

    Google Scholar 

  • Eugster HP, Jones BF (1979) Behaviour of major solutes during closed-basin brine evolution. Am J Sci 279:609–631

    Article  CAS  Google Scholar 

  • Freeze RA, Cherry JA (1979) Groundwater. Prentice-Hall, Englewood Cliffs

    Google Scholar 

  • Foster MD (1950) The origin of high sodium bicarbonate waters in the Atlantic and Gulf Coastal Plains. Geochim Cosmochim Acta 1:33–48

    Article  CAS  Google Scholar 

  • Gascoyne M, Kamineni DC (1994) The hydrogeochemistry of fractured plutonic rocks in the Canadian Shield. Appl Hydrogeol 2:43–49

    Article  Google Scholar 

  • Gibrilla A, Bam EKP, Adomako D, Ganyaglo S, Osae S, Akiti TT, Kebede S, Achoribo E, Ahialey E, Ayanu G, Agyeman EK (2011) Application of water quality index (WQI) and multivariate analysis for groundwater quality assessment of the Birimian and Cape coast granitoid complex: Densu River basin of Ghana. Water Qual Expo Health 3(2):63–78

    Article  CAS  Google Scholar 

  • Habgood F (1963) The geology of the country west of the Shire River between Chikhwawa and Chiromo. Bull 14 Geol Surv Malawi

  • Hanor JS, McManus KM (1988) Sediment alteration and clay mineral diagenesis in a regional ground water flow system, Mississippi Gulf Coastal Plain. Trans Gulf Coast Assoc Geol Soc 38:495–501

    Google Scholar 

  • Harkins RD (1974) An objective water quality index. J Water Pollut Control Fed 46(1):588–591

    CAS  Google Scholar 

  • Hem JD (1991) Study and interpretation of the chemical characteristics of natural waters, 3rd edn. Scientific, Jodhpur. Book 2254

    Google Scholar 

  • Hiscock KM (2009) Hydrogeology: principles and practice. Blackwell Sci, Oxford

    Google Scholar 

  • Horton RK (1965) An index-number system for Rating Water Quality. J Water Pollut Control Fed 37(3):300–306

    Google Scholar 

  • Hutcheson AM (1971) Atlas for Malawi. Longman, Harlow

    Google Scholar 

  • International Standards Organisation (ISO) (1985) Water quality—determination of electrical conductivity. ISO 7888

  • International Standards Organisation (ISO) (1993) Water quality—sampling—Part 11: guidance on sampling of ground waters. ISO 5667-11

  • International Standards Organisation (ISO) (1994). Water quality—determination of pH. ISO 10523-1

  • Janardhana Raju N (2007) Hydrogeochemical parameters for assessment of groundwater quality in the upper Gunjanaeru River basin, Cuddapah District, Andhra Pradesh, South India. Environ Geol 52:1067–1074

    Article  Google Scholar 

  • Kelly WP (1951) Alkali soils—their formation, properties and reclamation. Reinhold, New York

    Google Scholar 

  • Koh D-C, Chae G-T, Yoon Y-Y, Kang B-R, Koh G-W, Park K-H (2009) Baseline geochemical characteristics of groundwater in the mountainous area of Jeju Island, Sout Korea: implications for degree of mineralization and nitrate contamination. J Hydrol 376:81–93

    Article  CAS  Google Scholar 

  • Krothe NC, Parizek RR (1979) An anomalous occurrence of sodium bicarbonate water in a flood plain in a carbonate terrain. Groundwater 17(6):595–603

    Article  CAS  Google Scholar 

  • Lee RW (1985) Geochemistry of groundwater in Cretaceous sediments of the Southeastern coastal plain of Eastern Mississippi and Western Alabama. Water Resour Res 21(10):1545–1556

    Article  CAS  Google Scholar 

  • Lepeltier C (1969) A simplified statistical treatment of geochemical data by graphical representation. Econ Geol 64:538–550

    Article  CAS  Google Scholar 

  • Lockwood Survey Cooperation (1970) Lower shire valley—landforms, soils and land classification. Food and Agricultural Organisation (FAO)

  • Lowole MW (1985) Properties, management and classification of vertisols in Malawi. World soil reports, Fifth meeting of the Eastern African subcommittee for soil correction and land evaluation, Food and Agricultural Organisation (FAO)

  • Milovanovic M (2007) Water quality assessment and determination of pollution sources along the Axios/Vardar River, Southeastern Europe. Desalination 213:159–173

    Article  CAS  Google Scholar 

  • Mishra PC, Patel RK (2001) Study of the pollution load in the drinking water of Rairangpur a small tribal dominated town of North Orissa Indian. J Environ Ecoplanet 5(2):293–298

    Google Scholar 

  • Mondal NC, Sigh VP (2011) Hydrochemical analysis of salinisation for a tannery belt in Southern India. J Hydrol 405:235–247

    Article  CAS  Google Scholar 

  • Monjerezi M, Vogt RD, Aagaard P, Saka JDK (2011a) Hydro-geochemical processes in an area with saline groundwater in lower Shire River valley, Malawi: an integrated application of hierarchical cluster and principal component analyses. Appl Geochem 26:1399–1413

    Article  CAS  Google Scholar 

  • Monjerezi M, Vogt RD, Aagaard P, Gebru AG, Saka JDK (2011b) Using 87Sr/86Sr, δ 18O and δ 2H isotope data along with major chemical composition to assess groundwater salinization in lower Shire River valley, Malawi. Appl Geochem 26:2201–2214

    Article  CAS  Google Scholar 

  • Morel SW (1989) Chemical mineralogy and geothermometry of the middle Shire granulites, Malawi. J Afr Earth Sci 9:169–178

    Article  CAS  Google Scholar 

  • Morris BL, Lawrence ARL, Chilton PJC, Adams B, Calow RC, Klinck BA (2003) Groundwater and its susceptibility to degradation: a global assessment of the problem and options for management. Early warning and assessment report series, RS. 03-3, United Nations Environment Programme, Nairobi, Kenya

  • Muss DL (1962) Relationship between water quality and deaths from cardiovascular disease. J Am Water Works Assoc 54:1371–1378

    CAS  Google Scholar 

  • Naik S, Purohit KM (2001) Studies on water quality of river Brahmani in Sundargarh district, Orissa. Indian J Environ Ecoplan 5(2):397–402

    Google Scholar 

  • Olajire AA, Imeokparia FE (2001) Water quality assessment of Osun River: studies on inorganic nutrients. Environ Monit Assess 69(1):17–28

    Article  CAS  Google Scholar 

  • Panno SV, Kelly WR, Martinsek AT, Hackley KC (2006) Estimating background and threshold nitrate concentrations using probability graphs. Groundwater 44:697–709

    Article  CAS  Google Scholar 

  • Park S, Yun S, Chae G, Yoo I, Shin K, Heo C, Lee S (2005) Regional hydrochemical study on salinization of coastal aquifers, Western Coastal area of South Korea. J Hydrol 313:182–194

    Article  CAS  Google Scholar 

  • Parkhurst DL, Appelo CAJ (1999) User’s guide to PHREEQC (version 2)—a computer program for speciation, batch-reaction, one-dimensional transport and inverse geochemical calculations. Water Resources Investigation report, 99-4259, US department of the Interior, US Geological Survey

  • Prasad A, Kumar D, Singh DV (2001) Effect of residual sodium carbonate in irrigation water in the soil solidification and yield of palmarosa (Cymbopogon martini) and lemongrass (Cymbopogon flexiousus). Agric Water Manag 50:161–172

    Article  Google Scholar 

  • Reimann C, Filzmoser P, Garrett RG (2005) Background and threshold: critical comparison of methods of determination. Sci Total Environ 346:1–16

    Article  CAS  Google Scholar 

  • Richards LA (1954) Diagnosis and improvement of saline and alkali soils. US Department of Agriculture Handbook, vol 60

  • Sahu P, Sikdar PK (2008) Hydrochemical framework of the aquifer in and around East Kolkata wetlands, West Bengal. India Environ Geol 55:823–835

    Article  CAS  Google Scholar 

  • Sawyer GN, McMcartly DL, Parkin GF (2003) Chemistry for environmental engineering and science, 5th edn. McGraw Hill, New York, p 752

    Google Scholar 

  • Şen Z (2011) Groundwater quality variation assessment indices. Water Qual Expo Health. doi:10.1007/s12403-011-0050-y

    Google Scholar 

  • Schroeder HA (1960) Relations between hardness of water and death rates from certain chronic and degenerative diseases in the United States. J Chron Dis 12:586–591

    Article  CAS  Google Scholar 

  • Sinclair AJ (1974) Selection of thresholds in geochemical data using probability graphs. J Geochem Explor 3:129–149

    Article  CAS  Google Scholar 

  • Sinclair AJ (1991) A fundamental approach to threshold estimation in exploration geochemistry: probability plots revisited. J Geochem Explor 4:1–22

    Article  Google Scholar 

  • Sinha DK, Srivastava AK (1994) Water quality index for River Sai at RaeBareli for the pre monsoon period and after the onset of monsoon. Indian J Environ Prot 14(5):340–345

    Google Scholar 

  • Stigter TY, Ribeiro L, Dill AMMC (2006) Application of a groundwater quality index as an assessment and communication tool in agro-environmental policies—two Portuguese case studies. J Hydrol 327:578–591

    Article  Google Scholar 

  • Srinivasamoorthy K, Chidambaram M, Prasanna MV, Vasanthavigar M, John Peter A, Anandhan P (2008) Identification of major sources controlling groundwater chemistry from a hard rock terrain—a case study from Mettur taluk, Salem district, Tamilnadu, India. J Earth Syst Sci 117(1):49–58

    Article  CAS  Google Scholar 

  • Tiwari TN, Mishra M (1985) A preliminary assignment of water quality index of major Indian rivers. Indian J Environ Prot 5(4):276–279

    CAS  Google Scholar 

  • Toran LE, Saunders JE (1999) Modeling alternative paths of chemical evolution of Na–\({\mbox{HCO}_{3}}^{-}\) type groundwater near Oak Ridge, Tennessee, USA. Hydrogeology 7:355–364

    Article  Google Scholar 

  • Vasanthavigar M, Srinivasamoorthy K, Vijayaragavan K, Ganthi RR, Chidambaram S, Anandhan P, Manivannan R, Vasudevan S (2010) Application of water quality index for groundwater quality assessment: Thirumanimuttar sub-basin, Tamilnadu, India. Environ Monit Assess 171:595–609

    Article  CAS  Google Scholar 

  • World Health Organisation/WHO (2004) Guidelines for drinking water quality, vol 1: recommendations. World Health Organisation, Geneva

  • Yidana MS (2010) Groundwater classification using multivariate statistical methods: Southern Ghana. J Afr Earth Sci 57:455–469

    Article  CAS  Google Scholar 

  • Yidana SM, Yidana A (2010) Assessing water quality using water quality index and multivariate analysis. Environ Earth Sci 59:1461–1473

    Article  CAS  Google Scholar 

  • Yidana SM, Ophori D, Banoeng-Yakubo B (2008) Hydrogeological and hydrochemical characterization of the Voltaian Basin: the Afram Plains area. Environ Geol 53:1213–1223

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Maurice Monjerezi.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Monjerezi, M., Ngongondo, C. Quality of Groundwater Resources in Chikhwawa, Lower Shire Valley, Malawi. Water Qual Expo Health 4, 39–53 (2012). https://doi.org/10.1007/s12403-012-0064-0

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12403-012-0064-0

Keywords

Navigation