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Weak mismatch epitaxy and structural Feedback in graphene growth on copper foil

Nano Research volume 6, pages 99–112 (2013)Cite this article

Abstract

Graphene growth by low-pressure chemical vapor deposition on low cost copper foils shows great promise for large scale applications. It is known that the local crystallography of the foil influences the graphene growth rate. Here we find an epitaxial relationship between graphene and copper foil. Interfacial restructuring between graphene and copper drives the formation of (n10) facets on what is otherwise a mostly Cu(100) surface, and the facets in turn influence the graphene orientations from the onset of growth. Angle resolved photoemission shows that the electronic structure of the graphene is decoupled from the copper indicating a weak interaction between them. Despite this, two preferred orientations of graphene are found, ±8° from the Cu[010] direction, creating a non-uniform distribution of graphene grain boundary misorientation angles. Comparison with the model system of graphene growth on single crystal Cu(110) indicates that this orientational alignment is due to mismatch epitaxy. Despite the differences in symmetry the orientation of the graphene is defined by that of the copper. We expect these observations to not only have importance for controlling and understanding the growth process for graphene on copper, but also to have wider implications for the growth of two-dimensional materials on low cost metal substrates.

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Authors and Affiliations

  1. Department of Physics, University of Warwick, Coventry, CV4 7AL, UK

    Neil R. Wilson, Alexander J. Marsden, Mohammed Saghir, Ana M. Sanchez, James J. Mudd, Marc Walker & Gavin R. Bell

  2. EaStCHEM School of Chemistry, University of St Andrews, St Andrews, KY16 9ST, UK

    Catherine J. Bromley & Renald Schaub

  3. Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK

    Giovanni Costantini, Thomas W. White & Cerianne Partridge

  4. Sincrotrone Trieste S.C.p.A., Area Science Park, I-34012, Basovizza, Trieste, Italy

    Alexei Barinov & Pavel Dudin

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  1. Neil R. Wilson
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Correspondence to Neil R. Wilson.

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Wilson, N.R., Marsden, A.J., Saghir, M. et al. Weak mismatch epitaxy and structural Feedback in graphene growth on copper foil. Nano Res. 6, 99–112 (2013). https://doi.org/10.1007/s12274-013-0285-y

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  • DOI: https://doi.org/10.1007/s12274-013-0285-y

Keywords

  • graphene
  • chemical vapor deposition
  • mismatch epitaxy
  • structural feedback
  • low energy electron diffraction
  • angle resolved photo-emission spectroscopy (ARPES)