Abstract
The research work was carried out to synthesize a series of novel chitosan based water dispersible polyurethanes (CS-WDPUs). The three step synthesis involves the formation of end capped PU-prepolymer was formed through the reaction between polyethylene glycol (PEG) (Mn=600 g/mole, dimethylolpropionic acid (DMPA) and isophorone diisocyanate (IPDI) followed by the preparation of neutralized NCO terminated PU-prepolymer, which lead to the chain extension by using the chitosan. The dispersion of the obtained product was carried out by adding proper proportion of water. The synthesized CS-WDPUs were applied onto the different qualities of plain weave poly-cotton printed and dyed textile swatches by employing pad-dry-cure procedures. The textile assets of the treated and untreated textile swatches were assessed, as color fastness, pilling resistance, tear and tensile strength. The results showed that the chitosan incorporation into PU backbone has significant effect on the assets of treated textiles. These synthesized CS-WDPUs are eco-friendly bio-based finishes with potential applications for polyester/cotton textiles.
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W. D. Schindler and P. J. Hauser, “Chemical Finishing of Textiles”, p.74, Wood head Publishing Ltd. and CRC Press LLC, Cambridge, England, 2004.
H. M. Fahmy, S. H. Samaha, M. H. Abo–Shosha, and N. A. Ibrahim, Tinctoria, 10, 22 (2004).
N. F. Attia and M. Mousa, Polymer, 19, 471 (2018).
M. H. Abo–Shosha, Z. H. El–Hilw, A. A. Aly, A. Amr, and A. S. I. El–Nagdy, J. Ind. Text., 37, 315 (2008).
N. A. Ibrahim, M. H. Abo–Shosha, H. M. Fahmy, Z. M. El–Sayed, and A. Hebeish, J. Mater. Process. Technol., 200, 385 (2008).
M. H. Abo–Shosha, Z. H. El–Hilw, A. A. Aly, A. Amr, and A. M. Rabie, AATCC Rev., 9, 38 (2009).
H. M. Fahmy and E. S. Abdel–Halim, J. Ind. Text., 40, 109 (2010).
H. E. Gaffer, M. M. G. Fouda, and H. M. Fahmy, J. Appl. Sci. Res., 9, 4059 (2013).
B. F. Abdel–Wahab, H. E. Gaffer, M. M. G. Fouda, E. M. Osman, and M. H. Fahmy, J. Appl. Polym. Sci., 112, 2221 (2009).
R. A. A. Eid, T. M. Hassan, M. H. Fahmy, A. Amr, and D. E. Nada, Egypt. J. Chem., 58, 203 (2015).
N. A. Ibrahim, Z. El–Sayed, M. H. Fahmy, A. G. A. Hasabo, and M. H. Abo–Shosha, Res. J. Text. Appar., 17, 58 (2013).
M. H. Fahmy, R. A. A. Eid, D. E. Nada, and S. M. Abd El–Aziz, Egypt. J. Chem., 58, 447 (2015).
M. H. Fahmy, A. A. Aly, A. Amr, Sh. M. Sayed, and A. M. Rabie, Prog. Org. Coat., 99, 166 (2016).
M. H. Fahmy, A. A. Aly, and Z. E. Mohamed, Int. J. Chem. Tech. Res., 9, 96 (2016).
M. H. Fahmy, A. A. Aly, and Sh. M. Sayed, Prog. Org. Coat., 105, 176 (2017).
K. M. Zia, H. N. Bhatti, and I. A. Bhatti, React. Function. Polym., 67, 675 (2007).
F. Wang, J. Q. Hu, and W. P. Tu, Prog. Org. Coat., 62, 245 (2008).
P. Krol, B. Krol, S. Pikus, and K. Skrzypiec, Physicochem. Eng. Aspec., 259, 35 (2005).
D. A. Ley, D. E. Fiori, and R. J. Quinm, Prog. Org. Coat., 35, 109 (1999).
J. R. Caldwell and R. Gillrey, US Patent, 3, 236 (1966).
A. S. Forschirm and L. Hiawatha, US Patent, 4, 063 (1977).
A. Watanabe and T. Doyama, US Patent, 4, 831 (1989).
K. S. Yokohama and S. M. Yamato, US Patent, 4, 980 (1990).
N. A. Ibrahim, A. Amr, B. M. Eid, Z. E. Mohamed, and M. H. Fahmy, Carbohydr. Polym., 89, 648 (2012).
S. Muzaffar, I. A. Bhatti, M. Zuber, H. N. Bhatti, and M. Shahid, Fiber. Polym., 19, 587 (2018).
M. H. Fahmy, R. A. A. Eid, S. S. Hashem, and A. Amr, Carbohydr. Polym., 92, 1539 (2013).
B. Xu, Q. Li, L. Zhuang, Q,Wang, C. Li, G. Wang, F. Xie, and P. J. Halley, Fiber. Polym., 17, 1741 (2016).
M. H. Fahmy, M. H. Abo–Shosha, and N. A. Ibrahim, Carbohydr. Polym., 77, 845 (2009).
B. Simoncic and B. Tomsic, Text. Res. J., 80, 1721 (2010).
M. Akrami, S. Uddini, A. Ahmed, K. Usmanghani, A. E. Hannan Mohiuddin, and M. Asif, Rom. J. Biol.–Plant Biol., 55, 65 (2010).
M. Asouri, R. Ataee, A. A. Ahmadi, A. Amini, and M. R. Moshaei, Asian J. Chem., 25, 7593 (2013).
S. Han and Y. Yang, Dyes Pigm., 64, 157 (2005).
Y. Zhou, J. Zhang, R. Tang, and J. Zhang, Ind. Crop. Prod., 64, 224 (2015).
T. Sawano and F. Yazama, J. Bio Phys. Acta, 2, 170 (2011).
P. Suppakul and T. Jinkarn, J. Food Ag–Ind., 2, 138 (2009).
F. Shahidi, Food/Nahrung., 44, 158 (2000).
D. F. Buck and M. K. Edwards, Food Tech. Int., 2, 29 (1997).
N. Ooi, I. Chopra, E. A. Eady, J. Cove, R. Bojar, and A. J. O'Neill, J. Antimicrob. Chemother., 68, 1297 (2013).
N. Arshad, K. M. Zia, F. Jabeen, M. N. Anjum, N. Akram, and M. Zuber, Int. J. Biolog. Macromol., 111, 485 (2018).
N. G. Yogeshkumar, A. S. Gurav, and A. V. Yadav, I. J. Res. Pharm. Biomed. Sci., 4, 312 (2013).
D. Zuo, Y. Tao, and Y. Chen, Polym. Bull., 62, 713 (2009).
J. Li, Y. Gong, and N. Zhao, J. Appl. Polym. Sci., 98, 1016 (2005).
K. V. Harish Prashanth and R. N. Tharanathan, Trends Food Sci. Technol., 18, 117 (2007).
V. R. Giri Dev, R. Neelkandan, N. Sudha, O. L. Shamugasundaram, and R. N. Nadaraj, Text. Mag., 7, 83 (2005).
T. Kean, S. Roth, and M. Thanou, J. Control. Release, 103, 643 (2005).
J. Shao, Y. Yang, and Q. Zhong, Polym. Degrad. Stab., 82, 395 (2003).
S. A. Bahmani, G. C. East, and I. Holme, Color. Technol., 116, 94 (2000).
T. Öktem, Color. Technol., 119, 241 (2003).
W. B. Achwal, Colourage, 50, 51 (2003).
D. Chattopadhyay and M. S. Inamdar, Indian J. Fiber Text. Res., 38, 14 (2014).
M. Joshi, S. W. Ali, and R. Purwar, Indian J. Fiber Text. Res., 34, 295 (2009).
ASTM D 1647–89, Annual Book ASTM Stand, pp.236–237 (1998).
Standard Test Method for Pilling Resistance and Other Related Surface Changes of Textile Fabrics: Elastomeric Pad–1 (D 3514–02), American Society of Testing Material, ASTM International, USA, 2004.
M. Sultan, K. M. Zia, H. N. Bhatti, T. Jamil, R. Hussain, and M. Zuber, Carbohydr. Polym., 87, 397 (2012).
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Arshad, N., Zia, K.M., Jabeen, F. et al. Performance Behavior of Chitosan Based Water Dispersible Polyurethanes: Physicochemical Properties. Fibers Polym 19, 2219–2228 (2018). https://doi.org/10.1007/s12221-018-8610-4
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DOI: https://doi.org/10.1007/s12221-018-8610-4