Skip to main content
Log in

Performance Behavior of Chitosan Based Water Dispersible Polyurethanes: Physicochemical Properties

  • Published:
Fibers and Polymers Aims and scope Submit manuscript

Abstract

The research work was carried out to synthesize a series of novel chitosan based water dispersible polyurethanes (CS-WDPUs). The three step synthesis involves the formation of end capped PU-prepolymer was formed through the reaction between polyethylene glycol (PEG) (Mn=600 g/mole, dimethylolpropionic acid (DMPA) and isophorone diisocyanate (IPDI) followed by the preparation of neutralized NCO terminated PU-prepolymer, which lead to the chain extension by using the chitosan. The dispersion of the obtained product was carried out by adding proper proportion of water. The synthesized CS-WDPUs were applied onto the different qualities of plain weave poly-cotton printed and dyed textile swatches by employing pad-dry-cure procedures. The textile assets of the treated and untreated textile swatches were assessed, as color fastness, pilling resistance, tear and tensile strength. The results showed that the chitosan incorporation into PU backbone has significant effect on the assets of treated textiles. These synthesized CS-WDPUs are eco-friendly bio-based finishes with potential applications for polyester/cotton textiles.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. W. D. Schindler and P. J. Hauser, “Chemical Finishing of Textiles”, p.74, Wood head Publishing Ltd. and CRC Press LLC, Cambridge, England, 2004.

    Book  Google Scholar 

  2. H. M. Fahmy, S. H. Samaha, M. H. Abo–Shosha, and N. A. Ibrahim, Tinctoria, 10, 22 (2004).

    Google Scholar 

  3. N. F. Attia and M. Mousa, Polymer, 19, 471 (2018).

    CAS  Google Scholar 

  4. M. H. Abo–Shosha, Z. H. El–Hilw, A. A. Aly, A. Amr, and A. S. I. El–Nagdy, J. Ind. Text., 37, 315 (2008).

    Article  CAS  Google Scholar 

  5. N. A. Ibrahim, M. H. Abo–Shosha, H. M. Fahmy, Z. M. El–Sayed, and A. Hebeish, J. Mater. Process. Technol., 200, 385 (2008).

    Article  CAS  Google Scholar 

  6. M. H. Abo–Shosha, Z. H. El–Hilw, A. A. Aly, A. Amr, and A. M. Rabie, AATCC Rev., 9, 38 (2009).

    Google Scholar 

  7. H. M. Fahmy and E. S. Abdel–Halim, J. Ind. Text., 40, 109 (2010).

    Article  CAS  Google Scholar 

  8. H. E. Gaffer, M. M. G. Fouda, and H. M. Fahmy, J. Appl. Sci. Res., 9, 4059 (2013).

    Google Scholar 

  9. B. F. Abdel–Wahab, H. E. Gaffer, M. M. G. Fouda, E. M. Osman, and M. H. Fahmy, J. Appl. Polym. Sci., 112, 2221 (2009).

    Article  CAS  Google Scholar 

  10. R. A. A. Eid, T. M. Hassan, M. H. Fahmy, A. Amr, and D. E. Nada, Egypt. J. Chem., 58, 203 (2015).

    Article  Google Scholar 

  11. N. A. Ibrahim, Z. El–Sayed, M. H. Fahmy, A. G. A. Hasabo, and M. H. Abo–Shosha, Res. J. Text. Appar., 17, 58 (2013).

    Article  Google Scholar 

  12. M. H. Fahmy, R. A. A. Eid, D. E. Nada, and S. M. Abd El–Aziz, Egypt. J. Chem., 58, 447 (2015).

    Article  Google Scholar 

  13. M. H. Fahmy, A. A. Aly, A. Amr, Sh. M. Sayed, and A. M. Rabie, Prog. Org. Coat., 99, 166 (2016).

    Article  CAS  Google Scholar 

  14. M. H. Fahmy, A. A. Aly, and Z. E. Mohamed, Int. J. Chem. Tech. Res., 9, 96 (2016).

    CAS  Google Scholar 

  15. M. H. Fahmy, A. A. Aly, and Sh. M. Sayed, Prog. Org. Coat., 105, 176 (2017).

    Article  CAS  Google Scholar 

  16. K. M. Zia, H. N. Bhatti, and I. A. Bhatti, React. Function. Polym., 67, 675 (2007).

    Article  CAS  Google Scholar 

  17. F. Wang, J. Q. Hu, and W. P. Tu, Prog. Org. Coat., 62, 245 (2008).

    Article  CAS  Google Scholar 

  18. P. Krol, B. Krol, S. Pikus, and K. Skrzypiec, Physicochem. Eng. Aspec., 259, 35 (2005).

    Article  CAS  Google Scholar 

  19. D. A. Ley, D. E. Fiori, and R. J. Quinm, Prog. Org. Coat., 35, 109 (1999).

    Article  CAS  Google Scholar 

  20. J. R. Caldwell and R. Gillrey, US Patent, 3, 236 (1966).

    Google Scholar 

  21. A. S. Forschirm and L. Hiawatha, US Patent, 4, 063 (1977).

    Google Scholar 

  22. A. Watanabe and T. Doyama, US Patent, 4, 831 (1989).

    Google Scholar 

  23. K. S. Yokohama and S. M. Yamato, US Patent, 4, 980 (1990).

    Google Scholar 

  24. N. A. Ibrahim, A. Amr, B. M. Eid, Z. E. Mohamed, and M. H. Fahmy, Carbohydr. Polym., 89, 648 (2012).

    Article  CAS  PubMed  Google Scholar 

  25. S. Muzaffar, I. A. Bhatti, M. Zuber, H. N. Bhatti, and M. Shahid, Fiber. Polym., 19, 587 (2018).

    Article  CAS  Google Scholar 

  26. M. H. Fahmy, R. A. A. Eid, S. S. Hashem, and A. Amr, Carbohydr. Polym., 92, 1539 (2013).

    Article  CAS  PubMed  Google Scholar 

  27. B. Xu, Q. Li, L. Zhuang, Q,Wang, C. Li, G. Wang, F. Xie, and P. J. Halley, Fiber. Polym., 17, 1741 (2016).

    Article  CAS  Google Scholar 

  28. M. H. Fahmy, M. H. Abo–Shosha, and N. A. Ibrahim, Carbohydr. Polym., 77, 845 (2009).

    Article  CAS  Google Scholar 

  29. B. Simoncic and B. Tomsic, Text. Res. J., 80, 1721 (2010).

    Article  CAS  Google Scholar 

  30. M. Akrami, S. Uddini, A. Ahmed, K. Usmanghani, A. E. Hannan Mohiuddin, and M. Asif, Rom. J. Biol.–Plant Biol., 55, 65 (2010).

    Google Scholar 

  31. M. Asouri, R. Ataee, A. A. Ahmadi, A. Amini, and M. R. Moshaei, Asian J. Chem., 25, 7593 (2013).

    Article  CAS  Google Scholar 

  32. S. Han and Y. Yang, Dyes Pigm., 64, 157 (2005).

    Article  CAS  Google Scholar 

  33. Y. Zhou, J. Zhang, R. Tang, and J. Zhang, Ind. Crop. Prod., 64, 224 (2015).

    Article  CAS  Google Scholar 

  34. T. Sawano and F. Yazama, J. Bio Phys. Acta, 2, 170 (2011).

    Google Scholar 

  35. P. Suppakul and T. Jinkarn, J. Food Ag–Ind., 2, 138 (2009).

    Google Scholar 

  36. F. Shahidi, Food/Nahrung., 44, 158 (2000).

    Article  CAS  PubMed  Google Scholar 

  37. D. F. Buck and M. K. Edwards, Food Tech. Int., 2, 29 (1997).

    Google Scholar 

  38. N. Ooi, I. Chopra, E. A. Eady, J. Cove, R. Bojar, and A. J. O'Neill, J. Antimicrob. Chemother., 68, 1297 (2013).

    Article  CAS  PubMed  Google Scholar 

  39. N. Arshad, K. M. Zia, F. Jabeen, M. N. Anjum, N. Akram, and M. Zuber, Int. J. Biolog. Macromol., 111, 485 (2018).

    Article  CAS  Google Scholar 

  40. N. G. Yogeshkumar, A. S. Gurav, and A. V. Yadav, I. J. Res. Pharm. Biomed. Sci., 4, 312 (2013).

    Google Scholar 

  41. D. Zuo, Y. Tao, and Y. Chen, Polym. Bull., 62, 713 (2009).

    Article  CAS  Google Scholar 

  42. J. Li, Y. Gong, and N. Zhao, J. Appl. Polym. Sci., 98, 1016 (2005).

    Article  CAS  Google Scholar 

  43. K. V. Harish Prashanth and R. N. Tharanathan, Trends Food Sci. Technol., 18, 117 (2007).

    Article  CAS  Google Scholar 

  44. V. R. Giri Dev, R. Neelkandan, N. Sudha, O. L. Shamugasundaram, and R. N. Nadaraj, Text. Mag., 7, 83 (2005).

    Google Scholar 

  45. T. Kean, S. Roth, and M. Thanou, J. Control. Release, 103, 643 (2005).

    Article  CAS  PubMed  Google Scholar 

  46. J. Shao, Y. Yang, and Q. Zhong, Polym. Degrad. Stab., 82, 395 (2003).

    Article  CAS  Google Scholar 

  47. S. A. Bahmani, G. C. East, and I. Holme, Color. Technol., 116, 94 (2000).

    Article  CAS  Google Scholar 

  48. T. Öktem, Color. Technol., 119, 241 (2003).

    Article  Google Scholar 

  49. W. B. Achwal, Colourage, 50, 51 (2003).

    CAS  Google Scholar 

  50. D. Chattopadhyay and M. S. Inamdar, Indian J. Fiber Text. Res., 38, 14 (2014).

    Google Scholar 

  51. M. Joshi, S. W. Ali, and R. Purwar, Indian J. Fiber Text. Res., 34, 295 (2009).

    CAS  Google Scholar 

  52. ASTM D 1647–89, Annual Book ASTM Stand, pp.236–237 (1998).

  53. Standard Test Method for Pilling Resistance and Other Related Surface Changes of Textile Fabrics: Elastomeric Pad–1 (D 3514–02), American Society of Testing Material, ASTM International, USA, 2004.

  54. M. Sultan, K. M. Zia, H. N. Bhatti, T. Jamil, R. Hussain, and M. Zuber, Carbohydr. Polym., 87, 397 (2012).

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Khalid Mahmood Zia.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Arshad, N., Zia, K.M., Jabeen, F. et al. Performance Behavior of Chitosan Based Water Dispersible Polyurethanes: Physicochemical Properties. Fibers Polym 19, 2219–2228 (2018). https://doi.org/10.1007/s12221-018-8610-4

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s12221-018-8610-4

Keywords

Navigation