Abstract
Calcined waste starfish was used as a base catalyst for the production of biodiesel from soybean oil for the first time. A batch reactor was used for the transesterification reaction. The thermal characteristics and crystal structures of the waste starfish were investigated by thermo-gravimetric analysis and X-ray diffraction. The biodiesel yield was determined by measuring the content of fatty acid methyl esters (FAME). The calcination temperature appeared to be a very important parameter affecting the catalytic activity. The starfish-derived catalyst calcined at 750 °C or higher exhibited high activity for the transesterification reaction. The FAME content increased with increasing catalyst dose and methanol-over-oil ratio.
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References
Helwani, Z., Othman, M. R., Aziz, N., Fernando, W. J. N., & Kim, J. (2009). Technologies for production of biodiesel focusing on green catalytic techniques: A review. Fuel Processing Technology, 90, 1502–1514.
Huo, H., Wang, M., Bloyd, C., & Putsche, V. (2008). Life-Cycle Assessment of Energy and Greenhouse Gas Effects of Soybean-Derived Biodiesel and Renewable Fuels. Argonne national laboratory.
Boey, P. L., Maniam, G. P., & Hamid, S. A. (2011). Performance of calcium oxide as a heterogeneous catalyst in biodiesel production: A review. Chemical Engineering Journal, 168, 15–22.
Liu, X., He, H., Wang, Y., Zhu, S., & Piao, X. (2008). Transesterification of soybean oil to biodiesel using CaO as a solid base catalyst. Fuel, 87, 216–221.
Lam, M. K., Lee, K. T., & Mohamed, A. R. (2010). Homogeneous, heterogeneous and enzymatic catalysis for transesterification of high free fatty acid oil (waste cooking oil) to biodiesel: A review. Biotechnology Advances, 28, 500–518.
Granados, M. L., Poves, M. D. Z., Alonso, D. M., Mariscal, R., Galisteo, F. C., Moreno-Tost, R., Santamari, J., & Fierro, J. L. G. (2007). Biodiesel from sunflower oil by using activated calcium oxide. Applied Catalysis B: Environmental, 73, 317–326.
Kouzu, M., Kasuno, T., Tajika, M., Sugimoto, Y., Yamanaka, S., & Hidaka, J. (2008). Calcium oxide as a solid base catalyst for transesterification of soybean oil and its application to biodiesel production. Fuel, 87, 2798–2806.
Gryglewicz, S. (1999). Rapeseed oil methyl esters preparation using heterogeneous catalysts. Bioresource Technology, 70, 249–253.
Boey, P. L., Maniam, G. P., & Hamid, S. A. (2009). Biodiesel production via transesterification of palm olein using waste mud crab (Scylla serrata) shell as a heterogeneous catalyst. Bioresource Technology, 100, 6362–6368.
Viriya-empikul, V., Krasae, P., Puttasawat, B., Yoosuk, B., Chollacoop, N., & Faungnawakij, K. (2010). Waste shells of mollusk and egg as biodiesel production catalysts. Bioresource Technology, 101, 3765–3767.
Nakatani, N., Takamori, H., Takeda, K., & Sakugawa, H. (2009). Transesterification of soybean oil using combusted oyster shell waste as a catalyst. Bioresource Technology, 100, 1510–1513.
Boey, P. L., Maniam, G. P., Hamic, S. A., & Ali, D. M. H. (2011). Utilization of waste cockle shell (Anadara Granosa) in biodiesel production from palm olein: Optimization using response surface methodology. Fuel, 90, 2353–2358.
Ma, F., & Hanna, M. A. (1999). Biodiesel production: a review. Bioresource Technology, 70, 1–15.
Yan, S., Kim, M. H., Salley, S. O., & Ng, K. Y. S. (2009). Oil transesterification over calcium oxides modified with lanthanum. Applied Catalysis A: General, 360, 163–170.
Granados, M. L., Alonso, D. M., Sadaba, I., Mariscal, R., & Ocon, P. (2009). Leaching and homogeneous contribution in liquid phase reaction catalysed by solids: the case of triglycerides methanolysis using CaO. Applied Catalysis B: Environmental, 89, 265–272.
Kouzu, M., Kasuno, T., Tajika, M., Yamanaka, S., & Hidaka, J. (2008). Active phase of calcium oxide used as solid base catalyst for transesterification of soybean oil with refluxing methanol. Applied Catalysis A: General, 334, 357–365.
Leon-Reina, L., Cabeza, A., Rius, J., Maireles-Torres, P., Alba-Rubio, A. C., & Granados, M. L. (2013). Structural and surface study of calcium glyceroxide, an active phase for biodiesel production under heterogeneous catalysis. Journal of Catalysis, 300, 30–36.
Alba-Rubio, A. C., Castillo, M. L. A., Albuquerque, M. C. G., Mariscal, R., & Cavalcante, C. L., Jr. (2012). A new and efficient procedure for removing calcium soaps in biodiesel obtained using CaO as a heterogeneous catalyst. Fuel, 95, 464–470.
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This research was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Education, Science and Technology (2012R1A1B3003394).
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Jo, Y.B., Park, S.H., Jeon, JK. et al. Biodiesel Production via the Transesterification of Soybean Oil Using Waste Starfish (Asterina pectinifera). Appl Biochem Biotechnol 170, 1426–1436 (2013). https://doi.org/10.1007/s12010-013-0279-y
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DOI: https://doi.org/10.1007/s12010-013-0279-y