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Poly(methyl methacrylate) intercalated layered double hydroxide film with enhanced alkaline corrosion resistance for aluminum alloy AA6061

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Abstract

The oriented growth of Zn-Al LDH film perpendicular to the surface of AA6061 substrate was confirmed by scanning microscopy image and X-ray diffraction pattern. The LDH film achieved a complete surface coverage on the AA6061 substrate and exhibited strong corrosion resistance in NaOH solution (pH of 13). Furthermore, a preparation protocol for poly(methyl methacrylate) (PMMA)-LDH composite film was demonstrated. LDH film intercalated only with PMMA but not polyurethane demonstrated greatly enhanced alkaline corrosion resistance, showing a more positive corrosion potential and reduced corrosion current by four orders of magnitude in electrochemical polarization spectroscopy. The enhancement in corrosion resistance by PMMA intercalation could be attributed to the increasing compactness in the LDH film and increasing hydrophobicity.

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Acknowledgments

We gratefully acknowledge the financial support from the Ministry of Science and Technology of the Republic of China.

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Authors and Affiliations

  1. Department of Applied Chemistry, National University of Kaohsiung, Kaohsiung, 811, Taiwan

    Po-Yi Liu, Chih-Cheng Tsai, Shou-Chiu Cheng & Tseng-Chang Tsai

  2. Hawing GemS Technology Co. Ltd, Taichung, 402, Taiwan

    Shang-Tien Tsai & Wen-Chyuan ChangJean

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  1. Po-Yi Liu
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  2. Chih-Cheng Tsai
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  3. Shang-Tien Tsai
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  4. Wen-Chyuan ChangJean
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  5. Shou-Chiu Cheng
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  6. Tseng-Chang Tsai
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Correspondence to Tseng-Chang Tsai.

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Liu, PY., Tsai, CC., Tsai, ST. et al. Poly(methyl methacrylate) intercalated layered double hydroxide film with enhanced alkaline corrosion resistance for aluminum alloy AA6061. J Coat Technol Res 18, 777–787 (2021). https://doi.org/10.1007/s11998-020-00442-0

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  • DOI: https://doi.org/10.1007/s11998-020-00442-0

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