Abstract
Polyorganosilazane (PSZ) has been used for many years as a ceramic precursor for the preparation of silicon carbonitrides. Recently, polymethyl (hydro)/polydimethylsilazane-derived coatings that can be cured with atmospheric moisture at low temperatures have attracted interest due to their hydrophobic nature and electrochemical properties. In this work, polymethyl (hydro)/polydimethylsilazane-derived coatings have been deposited on aluminum alloy AA1050. The effect of the PSZ precursor concentration (5–40 v/v%) on the final properties of the coatings has been investigated. Butyl acetate has been employed as solvent. The layers were applied on the substrate by dipping. The experimental results showed that the concentration of the PSZ in the solvent strongly affects the dry thickness of the hybrid layer. The electrochemical impedance spectroscopy measurements revealed that the coatings derived from PSZ precursor concentration higher than 20 v/v% are protective and homogenous. Contact angle measurements evidenced that the presence of the coatings increased the hydrophobicity of the substrate as well as the oleophobicity regardless of the dilution in the organic solvent. The graffiti resistance of the coatings has been demonstrated to be acceptable regardless of the dilution of the PSZ precursor, in the investigated range.
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References
Plueddemann, EP, Silane Coupling Agents, 2nd ed. Plenum Press, New York (1990)
Mittal, KL (ed.) Silanes and Other Coupling Agents, Vol. 4. VSP Brill, Leiden (2007)
Mittal, KL (ed.) Silanes and Other Coupling Agents, Vol. 5. VSP Brill, Leiden (2009)
Sathyanarayana, MN, Yaseen, M, “Role of Promoters in Improving Adhesions of Organic Coatings to a Substrate.” Prog. Org. Coat., 26 (2–4) 275–313 (1995)
Wang, H, Akid, R, “A Room Temperature Cured Sol–Gel Anticorrosion Pre-treatment for Al 2024-T3 Alloys.” Corros. Sci., 49 4491–4503 (2007)
Motz, G, Hacker, J, Ziegler, G, “Special Modified Silazanes for Coatings, Fibers and CMC’s.” Ceram. Eng. Sci. Proc., 21 307–314 (2000)
Figueira, RB, Silva, CJR, Pereira, EV, “Organic–Inorganic Hybrid Sol–Gel Coatings for Metal Corrosion Protection: A Review of Recent Progress.” J. Coat. Technol. Res., 12 (1) 1–35 (2015)
Wang, D, Bierwagen, GP, “Sol–Gel Coatings on Metals for Corrosion Protection.” Prog. Org. Coat., 64 (4) 327–338 (2009)
Jothi, KJ, Palanivelu, K, “Praseodymium Oxide Modified Hybrid Silane Coatings for Anti-corrosion Applications.” Surf. Eng., 32 (1) 47–52 (2016)
Belhadjamor, M, El Mansori, M, Belghith, S, Mezlini, S, “Anti-fingerprint Properties of Engineering Surfaces: A Review.” Surf. Eng., 34 (2) 85–120 (2018)
Huanga, C, Ye, X, Yang, X, Yao, A, Fan, Z, “Preparation of a Superhydrophobic Aluminium Alloy Surface by UV Laser.” Surf. Eng., (2017). https://doi.org/10.1080/02670844.2017.1395982
Bauer, F, Decker, U, Dierdorf, A, Ernst, H, Heller, R, Liebe, H, Mehnert, R, “Preparation of Moisture Curable Polysilazane Coatings Part I. Elucidation of Low Temperature Curing Kinetics by FT-IR Spectroscopy.” Prog. Org. Coat., 53 (3) 183–190 (2005)
D’Elia, R, Dusserre, G, Del Confetto, S, Eberling-Fux, N, Descamps, C, Cutard, T, “Cure Kinetics of a Polysilazane System: Experimental Characterization and Numerical Modelling.” Eur. Polym. J., 76 40–52 (2016)
Mueller, S, De Hazan, Y, Penner, D, “Effect of Temperature, Humidity and Aminoalkoxysilane Additive on the Low Temperature Curing of Polyorganosilazane Coatings Studied by IR Spectroscopy, Gravimetric and Evolved Gas Analysis.” Prog. Org. Coat., 97 133–145 (2016)
Kong, J, Fan, X, Zhang, G, Xie, X, Si, Q, Wang, S, “Synthesis and UV-Curing Behaviours of Novel Rapid UV-Curable Polyorganosilazanes.” Polymer, 47 (5) 1519–1525 (2006)
Kroke, E, Li, YL, Konetschny, C, Lecomte, E, Fasel, C, Riedel, R, “Silazane Derived Ceramics and Related Materials.” Mater. Sci. Eng., 26 (4–6) 97–199 (2000)
Bernardo, E, Fiocco, L, Parcianello, G, Storti, E, Colombo, P, “Advanced Ceramics from Preceramic Polymers Modified at the Nano-Scale: A Review.” Materials, 7 (3) 1927–1956 (2014)
Barroso, GS, Krenkel, W, Motz, G, “Low Thermal Conductivity Coating System for Application up to 1000°C by Simple PDC Processing with Active and Passive Fillers.” J. Eur. Ceram. Soc., 35 (12) 3339–3348 (2015)
Lenz Leite, M, Barroso, G, Parchovianský, M, Galusek, D, Ionescu, E, Krenkel, W, Motz, G, “Synthesis and Characterization of Yttrium and Ytterbium Silicates from Their Oxides and an Oligosilazane by the PDC Route for Coating Applications to Protect Si3N4 in Hot Gas Environments.” J. Eur. Ceram. Soc., 37 (16) 5177–5191 (2017)
Furtat, P, Lenz-Leite, M, Ionescu, E, Machado, RAF, Motz, G, “Synthesis of Fluorine-Modified Polysilazanes: Via Si–H Bond Activation and Their Application as Protective Hydrophobic Coatings.” J. Mater. Chem. A, 5 (48) 25509–25521 (2017)
Akutsu, K, Niizeki, T, Nagayama, S, Miyata, N, Sahara, M, Shimomura, A, Yoshii, M, Hasegawa, Y, “Investigation of Structure of a Thin SiO2 Layer as an Antifouling and Corrosion-Resistant Coating.” J. Ceram. Soc. Jpn., 124 (2) 172–176 (2016)
Augustinho, TR, Motz, G, Ihlow, S, Machado, RAF, “Application of Hybrid Organic/Inorganic Polymers as Coatings on Metallic Substrates.” Mater. Res. Exp., 3 095301 (2016)
Lukacs, A, Knasiak, GJ, “Thermally Stable, Moisture Curable Polysilazanes and Polysiloxazanes.” US Patent US6652978B2, 2003
Marceaux, S, Bressy, C, Perrin, FX, Martin, C, Margaillan, A, “Development of Polyorganosilazane–Silicone Marine Coatings.” Prog. Org. Coat., 77 (11) 1919–1928 (2014)
Vu, C, Osterod, F, Brand, S, Ryan, K, “Silicon and Nitrogen.” Eur. Coat. J., 38 1–11 (2008)
Amouzou, D, Fourdrinier, L, Maseri, F, Sporken, R, “Formation of Me–O–Si Covalent Bonds at the Interface Between Polysilazane and Stainless Steel.” Appl. Surf. Sci., 320 519–523 (2014)
Rossi, S, Deflorian, F, Fedel, M, “Polysilazane-Based Coatings: Corrosion Protection and Anti-graffiti Properties.” Surf. Eng., (2018). https://doi.org/10.1080/02670844.2018.1465748
ASTM D6578/D6578M − 13 standard, Standard Practice for Determination of Graffiti Resistance. ASTM International, West Conshohocken
Howarter, JA, Genson, KL, Youngblood, JP, “Wetting Behavior of Oleophobic Polymer Coatings Synthesized from Fluorosurfactant-Macromers.” ACS Appl. Mater. Interfaces, 3 (6) 2022–2030 (2011)
Rossi, S, Fedel, M, Petrolli, S, Deflorian, F, “Accelerated Weathering and Chemical Resistance of Polyurethane Powder Coatings.” J. Coat. Technol. Res., 13 (3) 427–437 (2016)
Rossi, S, Fedel, M, Deflorian, F, Feriotti, A, “Anti-graffiti Properties of Polyurethane Powder Coatings.” J. Test. Eval., 45 (4) 1192–1200 (2017)
CIE 15 Technical Report: Colorimetry, 3rd ed.; International Commission on Illumination, Bureau Central de la CIE: Paris, France (2004)
Gulrajani, ML, Colour Measurement: Principles, Advances and Industrial Applications. Woodhead Publishing, Oxford (2016)
Al-Oweini, R, El-Rassy, H, “Synthesis and Characterization by FTIR Spectroscopy of Silica Aerogels Prepared Using Several Si(OR)4 and R’’Si(OR’)3 Precursors.” J. Mol. Struct., 919 (1–3) 140–145 (2009)
Fedel, M, Callone, E, Fabbian, M, Deflorian, F, Dirè, S, “Influence of Ce3+ Doping on Molecular Organization of Si-Based Organic/Inorganic Sol–Gel Layers for Corrosion Protection.” Appl. Surf. Sci., 414 82–91 (2017)
Schiavon, MA, Ciuffi, KJ, Valéria, I, Yoshida, P, “Glasses in the Si–O–C–N System Produced by Pyrolysis of Polycyclic Silazane/Siloxane Networks.” J. Non-Cryst. Solids, 353 2280–2288 (2007)
Fedel, M, Callone, E, Diré, S, Deflorian, F, Olivier, MG, Poelman, M, “Effect of Na-Montmorillonite Sonication on the Protective Properties of Hybrid Silica Coatings.” Electrochim. Acta, 124 90–99 (2014)
Seo, Y, Cho, S, Kim, S, Choi, S, Kim, H, “Synthesis of Refractive Index Tunable Silazane Networks for Transparent Glass Fiber Reinforced Composite.” Ceram. Int., 43 (10) 7895–7900 (2017)
Schiavon, MA, Sorarù, GD, Yoshida, IVP, “Synthesis of a Polycyclic Silazane Network and Its Evolution to Silicon Carbonitride Glass.” J. Non-Cryst. Solids, 304 (1–3) 76–83 (2002)
van Ooij, WJ, Zhu, D, Stacy, M, Seth, A, Mugada, T, Gandhi, J, Puomi, P, “Corrosion Protection Properties of Organofunctional Silanes—An Overview.” Tsinghua Sci. Technol., 10 (6) 639–664 (2005)
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The authors are grateful to Stefano Corrado (Merck SpA, Milan, Italy) for the materials supply and the useful discussion.
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Fedel, M., Rossi, S. & Deflorian, F. Polymethyl (hydro)/polydimethylsilazane-derived coatings applied on AA1050: effect of the dilution in butyl acetate on the structural and electrochemical properties. J Coat Technol Res 16, 1013–1019 (2019). https://doi.org/10.1007/s11998-018-00176-0
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DOI: https://doi.org/10.1007/s11998-018-00176-0