Gd3+ doped Fe3O4 nanoparticles with proper magnetic and supercapacitive characteristics: A novel synthesis platform and characterization

  • Mustafa Aghazadeh
  • Isa Karimzadeh
  • Mohammad Ghannadi Maragheh
  • Mohammad Reza Ganjali
Research papers
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Abstract

A novel electrochemical procedure was developed for the facile preparation of Gd-doped iron oxide nanoparticles (GdIO-NPs). A simple galvanostatic deposition (i=10 mA cm-2) was done in an additive-free aqueous solution containing FeCl2·4H2O, Fe(NO3)3·9H2O and GdCl3·6H2O. The XRD, FE-SEM, EDS and TEM characterizations showed that the product is composed of 15% GdIO-NPs with 10 nm in size. VSM analysis proved that the GdIO-NPs are superparamagnetic. The cyclic voltammetry and charge-discharge tests showed that the prepared GdIO-NPs are capable to deliver specific capacity as high as 190.1 F g-1 at 0.5A g-1 and capacity retention of 95.1% after 2000 cycling. Based on the results, it was concluded that the developed electrochemical strategy acts as an efficient procedure for the preparation of lanthanide doped MNPs with proper magnetic and supercapacitive characters.

Keywords

Iron Oxide Gd Ion Doping Nanoparticles Electrodeposition Magnetic Materials Supercapacitors 

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Copyright information

© Korean Institute of Chemical Engineers, Seoul, Korea 2018

Authors and Affiliations

  • Mustafa Aghazadeh
    • 1
  • Isa Karimzadeh
    • 2
  • Mohammad Ghannadi Maragheh
    • 1
  • Mohammad Reza Ganjali
    • 3
    • 4
  1. 1.Materials and Nuclear Research SchoolNSTRITehranIran
  2. 2.Department of Physics, Bonab BranchIslamic Azad UniversityBonabIran
  3. 3.Center of Excellence in Electrochemistry, Faculty of ChemistryUniversity of TehranTehranIran
  4. 4.Biosensor Research Center, Endocrinology and Metabolism Molecular-Cellular Sciences InstituteTehran University of Medical SciencesTehranIran

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