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Combination of supercritical fluid elution and resin adsorption for removal of procymidone from ginseng extracts

  • Separation Technology, Thermodynamics
  • Published:
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Abstract

We propose a new method of resin adsorption (RA) coupled with supercritical fluid elution (SFE) for removal of pesticide residue and recovery of ginsenosides from ginseng extracts. D-101-1 resin was selected as the proper adsorption resin, acetone-n-hexane (4 : 6, v : v) served as the modifier with the flow rate of 1.5 mL/min during supercritical CO2 elution of procymidone at 25 MPa, 55°C for 2 h, and absolute ethanol as the modifier at a flow rate of 1 mL/min for supercritical CO2 elution of ginsenosides at 20 MPa, 60°C and 1 h. The results showed that the content of procymidone in the final products was only 0.0089 mg/kg. Meanwhile, the recovery rate of ginsenosides reached up to 92.5%. RA-SFE procedure provides an efficient approach to remove pesticide residue traces with little loss of active ingredients. The used resin can be recycled without any additional regeneration.

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Authors and Affiliations

  1. Key Laboratory for Green Chemical Technology of Ministry of Education, School of Chemical Engineering & Technology, Tianjin University, Tianjin, 300072, China

    Guangtao Li, Liwei Sun & Shaokun Tang

  2. Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin University, Tianjin, 300072, China

    Shaokun Tang

Authors
  1. Guangtao Li
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  2. Liwei Sun
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  3. Shaokun Tang
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Correspondence to Shaokun Tang.

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Li, G., Sun, L. & Tang, S. Combination of supercritical fluid elution and resin adsorption for removal of procymidone from ginseng extracts. Korean J. Chem. Eng. 35, 956–963 (2018). https://doi.org/10.1007/s11814-018-0001-4

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  • DOI: https://doi.org/10.1007/s11814-018-0001-4

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