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Effects of process and design parameters on heat management in fixed bed Fischer-Tropsch synthesis reactor

  • Catalysis, Reaction Engineering
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Abstract

A two-dimensional pseudo-homogeneous model of wall-cooled fixed bed Fischer-Tropsch synthesis (FTS) reactor with Co/Re/γ-Al2O3 catalyst was developed to study the effect of process and design parameters on heat generation and removal characteristics. The influence of liquid-phase formation on heat transport was accounted for by using two-phase correlations. The effect of intraparticle diffusion on heat generation was considered. Detailed numerical simulations were performed to analyze the effect of process and design parameters on the reactor performance in terms of heat management. Results show that thermal behavior of FTS fixed bed reactors is very sensitive and any large disturbances can lead to temperature runaway. Large tube diameters are shown to be particularly unfavorable, with d t >5 cm resulting in axial and radial gradients greater than 20 K and 13 K, respectively. The importance of detailed reactor modeling when designing and optimizing FTS fixed bed reactors is highlighted.

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Authors and Affiliations

  1. Chemical Engineering Program, Texas A&M University at Qatar, P. O. Box, 23874, Doha, Qatar

    Branislav Todic, Milos Mandic & Dragomir B. Bukur

  2. Faculty of Technology and Metallurgy, University of Belgrade, Karnegijeva 4, Belgrade, Serbia

    Nikola Nikacevic

  3. Texas A&M University, 3122 TAMU, College Station, Texas, 77843, USA

    Dragomir B. Bukur

Authors
  1. Branislav Todic
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  2. Milos Mandic
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  3. Nikola Nikacevic
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  4. Dragomir B. Bukur
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Correspondence to Branislav Todic or Dragomir B. Bukur.

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Todic, B., Mandic, M., Nikacevic, N. et al. Effects of process and design parameters on heat management in fixed bed Fischer-Tropsch synthesis reactor. Korean J. Chem. Eng. 35, 875–889 (2018). https://doi.org/10.1007/s11814-017-0335-3

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  • DOI: https://doi.org/10.1007/s11814-017-0335-3

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