Skip to main content
Log in

Flotation of kaolinite and diaspore with hexadecyl dimethyl benzyl ammonium chloride

  • Published:
Journal of Central South University of Technology Aims and scope Submit manuscript

Abstract

Tertiary amine was synthesized from fatty amine and formaldehyde. And then the synthesized tertiary amine was used to react with benzyl chloride to synthesize hexadecyl dimethyl benzyl ammonium chloride (1627) at ambient pressure. Using the synthesized 1627 as collector, the flotation properties of diaspore and kaolinite were investigated by single mineral and mixed mineral test. The flotation mechanism of diaspore, kaolinite and 1627 was discussed based on FTIR spectra. The results show that the mass ratio of aluminum to silicate achieves 15.02 and the recovery of alumina in concentrate is 43.07% using 1627 as a collector. The 1627 is found to be a more effective and a promising collector for reverse flotation to remove aluminum-silicate minerals from bauxite.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

References

  1. ZHAO Zu-de. Bauxite and alumina industry of world [M]. Beijing: Science Process, 1994. (in Chinese)

    Google Scholar 

  2. GUO Jian. A study on separation diaspore and kaolinite by reverse flotation [D]. Beijing: University of Science and Technology Beijing, 2001. (in Chinese)

    Google Scholar 

  3. QIN Wen-qing, HU Yue-hua, QIU Guan-zhou, JIANG Hao. Interaction and flotation of diaspore with alkylamine hydrochlorides [J]. Trans Nonferrous Met Soc China, 2001, 11(3): 430–433.

    Google Scholar 

  4. HU Yue-hua, CAO Xue-feng, LI Hai-pu, JLANG Yu-ren, DU Ping. Synthesis of N-decyl-1, 3-diaminopropanes and its flotation properties on aluminium silicate minerals [J]. Trans Nonferrous Met Soc China, 2003, 13(2): 417–420.

    Google Scholar 

  5. HU Yue-hua, JIANG Hao, QIU Guan-zhou, WANG Dian-zuo. Solution chemistry of flotation separation of diasporic bauxite [J]. The Chinese Journal of Nonferrous Metals, 2001, 11(1): 125–130. (in Chinese)

    Google Scholar 

  6. ZHAO Sheng-gui, ZHONG Hong, LIU Guang-yi. Effect of quaternary ammonium salts on flotation behavior of aluminosilicate minerals [J]. J Cent South Univ Technol, 2007, 14(4): 500–503.

    Article  Google Scholar 

  7. HU Yue-hua, WANG Yu-hua, WANG Dian-zuo. Flotation chemistry and desilication of bauxite [M]. Beijing: Science Press, 2004. (in Chinese)

    Google Scholar 

  8. JIANG Hao. Studies on solution chemistry of interactions between cationic collectors and aliminosilicate aluminum minerals in bauxite flotation desilica [D]. Changsha: Central South University, 2004. (in Chinese)

    Google Scholar 

  9. LIU Pi-wang, ZHANG Lun-he, ZHANG Xiao-feng, PEI Yu, LI Kai-gong. Theoretical basis of new technology in predesilicification and bauxite dressing-buyer process and industry technique of new technology [J]. Journal of Chemical Industry and Engineering, 2000, 51(6): 734–739. (in Chinese)

    Google Scholar 

  10. CAO Xue-feng, HU Yue-hua, XU Jing. Synthesis of γ-alkoxy-propylamines and their collecting properties on aluminosilicate minerals [J]. J Cent South Univ Technol, 2004, 11(3):280–285.

    Article  Google Scholar 

  11. REN Jian-wei, WANG Yu-hua. Reverse flotation desilicates on iron ores [J]. China Mining Magazine, 2004, 13(4): 70–72. (in Chinese)

    Google Scholar 

  12. CAO Xue-feng. Synthesis of collectors to catch aluminum silicate minerals and studies on structure-activity relationship [D]. Changsha: Central South University, 2004. (in Chinese)

    Google Scholar 

  13. LI Shu-wen, FAN Ru-lin. The handbook of organic chemistry [M]. Shanghai: Shanghai Science Technology Press, 1981. (in Chinese)

    Google Scholar 

  14. ZOTOV V I, MANKOVICH L. Method for producing alkyldimethylbenzylammonium chlorides [P]. CN03809057. 2005-07-27.

  15. ZHU Guang-jun, ZHANG Xi-he, LIU Bin, XU Xiao-feng. Synthesis study of a new surfactant oxidated tertiary amine [J]. Fine Chemicals, 1994, 11(1): 1–3. (in Chinese)

    Google Scholar 

  16. XIE Jing-xi. Application of infrared spectrum in organic chemistry and medicament [M]. Beijing: Science Press, 1987. (in Chinese)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Yue-hua Hu  (胡岳华).

Additional information

Foundation item: Project(2006AA06Z120) supported by the National High-Tech Research and Development Program of China; Project(2005CB623701) supported by the Major State Basic Research Development Program of China

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hu, Yh., Ouyang, K., Cao, Xf. et al. Flotation of kaolinite and diaspore with hexadecyl dimethyl benzyl ammonium chloride. J. Cent. South Univ. Technol. 15, 378–381 (2008). https://doi.org/10.1007/s11771-008-0071-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11771-008-0071-2

Key words

Navigation