Abstract
Hydrogen is a clean energy carrier. Converting abundant coal sources and green biomass energy into hydrogen effectively and without any pollution promotes environmental protection. The co-gasification performance of coal and a model compound of biomass, carboxymethylcellulose (CMC) in supercritical water (SCW), were investigated experimentally. The influences of temperature, pressure and concentration on hydrogen production from co-gasification of coal and CMC in SCW under the given conditions (20–25 MPa, 650°C, 15–30 s) are discussed in detail. The experimental results show that H2, CO2 and CH4 are the main gas products, and the molar fraction of hydrogen reaches in excess of 60%. The higher pressure and higher CMC content facilitate hydrogen production; production is decreased remarkably given a longer residence time.
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References
Antal J M J, Allen S G, Schulman D, et al. Biomass gasification in supercritical water. Ind Eng Chem Res, 2000, 39(11): 4040–4053
Elliott D C, Neuenschwander G G, Hart T R, et al. Chemical Processing in High-Pressure Aqueous Environments. 7. Process Development for Catalytic Gasification of Wet Biomass Feedstocks. Ind Eng Chem Res, 2004, 43(9): 1999–2004
Usui Y, Minowa T, Inoue S, et al. Selective hydrogen production from cellulose at low-temperature catalyzed by supported group 10 metal. Chem Lett, 2000, 346(10): 1166–1167
Kruse A, Gawlik A. Biomass conversion in water at 330°C–410°C and 30–50 mpa identification of key compounds for indicating different chemical reaction pathways. Ind Eng Chem Res, 2003, 42(2): 267–279
Hao X H, Guo L J, Mao X, et al. Hydrogen production from glucose used as a model compound of biomass gasified in supercritical water. International Journal of Hydrogen Energy, 2003, 28(1): 55–64
Lin Shiying, Harada M, Suzuki Y, et al. Hydrogen production from coal by separating carbon dioxide during gasification. Fuel, 2002, 81(16): 2079–2085
Hong G T, Spitzer M H. Supercritical water partial oxidation. Hydrogen Program Annual Review, Berkeley, 2003
Liao Hongqiang, Deng Deming, Li Baoqing, et al. The progress of coal catalytic gasification and co-gasification of coal and paper pulp. Coal conversion, 2000, 23(3): 1–5
Pinto F, Franco C, Andre R N, et al. Effect of experimental conditions on co-gasification of coal, biomass and plastics wastes with air/steam mixtures in a fluidized bed system. Fuel, 2003, 82(15–17): 1967–1976
Savage P E, Gopalan S, Mizan T I, et al. Reaction at supercritical conditions: Applications and fundamentals. AIChE, 1995, 41(7): 1723–1778
Zhu Ziqiang. The Technology of Supercritical Fluids—Principle and Usage. Beijing: Chemical Industry Press, 2000, 504–507
Mao Xiaoan, Hao Xiaohong, Guo Liejin, et al. Experimental study on hydrogen production by cellulose gasification in supercritical water. Journal of Engineering Thermoplastics, 2003, 21(3): 388–390
Lin Shiying, Harada M, Suzuki Y, et al. Continuous experiment regarding hydrogen production by coal/CaO reaction with steam (I) gas products. Fuel, 2004, 83(7–8): 869–874
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Translated from Journal of Xi’an Jiao Tong University, 2005, 39(5): 454–457 [译自: 西安交通大学学报]
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Yan, Q., Guo, L., Liang, X. et al. Hydrogen production from co-gasification of coal and biomass in supercritical water by continuous flow thermal-catalytic reaction system. Front. Energy Power Eng. China 1, 327–330 (2007). https://doi.org/10.1007/s11708-007-0048-0
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DOI: https://doi.org/10.1007/s11708-007-0048-0