Abstract
A novel Ag3PO4-AgBr-PTh composite loaded on Na2SiO3 was synthesized for enhanced visible-light photocatalytic activity. The photocatalytic activity of the samples was evaluated by photodegrading rhodamine B (RhB) under visible light irradiation. The main reactive species and possible photocatalytic mechanism were also discussed. As a result, the Ag3PO4-AgBr-PTh composite loaded on Na2SiO3 exhibited enhanced photocatalytic activity for RhB compared with Ag3PO4 under visible-light irradiation. Additionally, it was demonstrated that the hole (h+) and superoxide radical (•O −2 ) were the major reactive species involving in the RhB degradation. PTh played vital role for the enhanced photocatalytic activity of Ag3PO4-AgBr-PTh-Na2SiO3 composite, which offered an electron transfer expressway and accelerated the transfer of the electrons from the CB of AgBr into Ag3PO4. This work could provide a new perspective for the synthesis of Ag3PO4-based composites and the improvement of photocatalytic activity of Ag3PO4.
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Yi Z, Ye J, Kikugawa N, et al. An orthophosphate semiconductor with photooxidation properties under visible-light irradiation. Nature Materials, 2010, 9(7): 559–564
Tang C, Liu E, Wan J, et al. Co3O4 nanoparticles decorated Ag3PO4 tetrapods as an efficient visible-light-driven heterojunction photocatalyst. Applied Catalysis B: Environmental, 2016, 181: 707–715
Xu Y S, Zhang WD. Monodispersed Ag3PO4 nanocrystals loaded on the surface of spherical Bi2MoO6 with enhanced photocatalytic performance. Dalton Transactions, 2013, 42(4): 1094–1101
Yao W, Zhang B, Huang C, et al. Synthesis and characterization of high efficiency and stable Ag3PO4/TiO2 visible light photocatalyst for the degradation of methylene blue and rhodamine B solutions. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2012, 22: 4050–4055
Bi Y, Ouyang S, Cao J, et al. Facile synthesis of rhombic dodecahedral AgX/Ag3PO4 (X = Cl, Br, I) heterocrystals with enhanced photocatalytic properties and stabilities. Physical Chemistry Chemical Physics, 2011, 13(21): 10071–10075
Dong P, Wang Y, Cao B, et al. Ag3PO4/reduced graphite oxide sheets nanocomposites with highly enhanced visible light photocatalytic activity and stability. Applied Catalysis B: Environmental, 2013, 132–133(9): 45–53
Xu H, Wang C, Song Y, et al. CNT/Ag3PO4 composites with highly enhanced visible light photocatalytic activity and stability. Chemical Engineering Journal, 2014, 241: 35–42
Yu H, Yu Y, Liu J, et al. Space-confined growth of Ag3PO4 nanoparticles within WS2 sheets: Ag3PO4/WS2 composites as visible-light-driven photocatalysts for decomposing dyes. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2015, 3(38): 19439–19444
Patil S S, Tamboli M S, Deonikar V G, et al. Magnetically separable Ag3PO4/NiFe2O4 composites with enhanced photocatalytic activity. Dalton Transactions, 2015, 44(47): 20426–20434
Guan X, Guo L. Cocatalytic effect of SrTiO3 on Ag3PO4 toward enhanced photocatalytic water oxidation. ACS Catalysis, 2014, 4 (9): 3020–3026
Chen Z, Bing F, Liu Q, et al. Novel Z-scheme visible-light-driven Ag3PO4/Ag/SiC photocatalysts with enhanced photocatalytic activity. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2015, 3(8): 4652–4658
Yang X, Qin J, Jiang Y, et al. Fabrication of P25/Ag3PO4/graphene oxide heterostructures for enhanced solar photocatalytic degradation of organic pollutants and bacteria. Applied Catalysis B: Environmental, 2015, 166–167: 231–240
Yang X, Qin J, Jiang Y, et al. Bifunctional TiO2/Ag3PO4/graphene composites with superior visible light photocatalytic performance and synergistic inactivation of bacteria. RSC Advances, 2014, 4 (36): 18627–18636
Kumar S, Surendar T, Baruah A, et al. Synthesis of a novel and stable g-C3N4–Ag3PO4 hybrid nanocomposite photocatalyst and study of the photocatalytic activity under visible light irradiation. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2013, 1(17): 5333–5340
Yang X, Chen Z, Xu J, et al. Tuning the morphology of g-C3N4 for improvement of Z-scheme photocatalytic water oxidation. ACS Applied Materials & Interfaces, 2015, 7(28): 15285–15293
Yang X, Tang H, Xu J, et al. Silver phosphate/graphitic carbon nitride as an efficient photocatalytic tandem system for oxygen evolution. ChemSusChem, 2015, 8(8): 1350–1358
Bu Y, Chen Z. Role of polyaniline on the photocatalytic degradation and stability performance of the polyaniline/silver/silver phosphate composite under visible light. ACS Applied Materials & Interfaces, 2014, 6(20): 17589–17598
Liang H, Li X. Visible-induced photocatalytic reactivity of polymer-sensitized titania nanotube films. Applied Catalysis B: Environmental, 2009, 86(1–2): 8–17
Wang Y, Chu W, Wang S, et al. Simple synthesis and photoelectrochemical characterizations of polythiophene/Pd/TiO2 composite microspheres. ACS Applied Materials & Interfaces, 2014, 6(22): 20197–20204
Lv M, Yang H, Xu Y, et al. Improving the visible light photocatalytic activities of Bi25FeO40/MIL-101/PTH via polythiophene wrapping. Journal of Environmental Chemical Engineering, 2015, 3(2): 1003–1008
Zhang F, Shi Y, Zhao Z, et al. Influence of semiconductor/insulator/semiconductor structure on the photo-catalytic activity of Fe3O4/SiO2/polythiophene core/shell submicron composite. Applied Catalysis B: Environmental, 2014, 150: 472–478
Yang Z, Huang G, Huang W, et al. Novel Ag3PO4/CeO2 composite with high efficiency and stability for photocatalytic applications. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2014, 2(6): 1750–1756
Zhu Y, Xu S, Jiang L, et al. Synthesis and characterization of polythiophene/titanium dioxide composites. Reactive & Functional Polymers, 2008, 68(10): 1492–1498
Ma J, Liu Q, Zhu L, et al. Visible light photocatalytic activity enhancement of Ag3PO4 dispersed on exfoliated bentonite for degradation of rhodamine B. Applied Catalysis B: Environmental, 2016, 182: 26–32
Dong P, Wang Y, Li H, et al. Shape-controllable synthesis and morphology-dependent photocatalytic properties of Ag3PO4 crystals. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2013, 1(15): 4651–4656
Liu L, Qi Y, Lu J, et al. A stable Ag3PO4@g-C3N4 hybrid core@shell composite with enhanced visible light photocatalytic degradation. Applied Catalysis B: Environmental, 2016, 183: 133–141
Yu X, Liu S, Yu J. Superparamagnetic γ-Fe2O3@SiO2@TiO2 composite microspheres with superior photocatalytic properties. Applied Catalysis B: Environmental, 2011, 104(1–2): 12–20
Wang L, Chai Y, Ren J, et al. Ag3PO4 nanoparticles loaded on 3D flower-like spherical MoS2: a highly efficient hierarchical heterojunction photocatalyst. Dalton Transactions, 2015, 44(33): 14625–14634
Cao J, Luo B, Lin H, et al. Visible light photocatalytic activity enhancement and mechanism of AgBr/Ag3PO4 hybrids for degradation of methyl orange. Journal of Hazardous Materials, 2012, 217–218: 107–115
Yan T, Guan W, Li W, et al. Ag3PO4 photocatalysts loaded on uniform SiO2 supports for efficient degradation of methyl orange under visible light irradiation. RSC Advances, 2014, 4(70): 37095–37099
Zheng B, Wang X, Liu C, et al. High-efficiently visible lightresponsive photocatalysts: Ag3PO4 tetrahedral microcrystals with exposed {111} facets of high surface energy. Journal of Materials Chemistry A: Materials for Energy and Sustainability, 2013, 1 (40): 12635–12640
Yang X, Cui H, Li Y, et al. Fabrication of Ag3PO4–graphene composites with highly efficient and stable visible light photocatalytic performance. ACS Catalysis, 2013, 3(3): 363–369
Wang W S, Du H, Wang R X, et al. Heterostructured Ag3PO4/AgBr/Ag plasmonic photocatalyst with enhanced photocatalytic activity and stability under visible light. Nanoscale, 2013, 5(8): 3315–3321
Xiang Q, Lang D, Shen T, et al. Graphene-modified nanosized Ag3PO4 photocatalysts for enhanced visible-light photocatalytic activity and stability. Applied Catalysis B: Environmental, 2015, 162: 196–203
Chandra M R, Rao T S, Pammi S V N, et al. An enhanced visible light active rutile titania-copper/polythiophene nanohybrid material for the degradation of rhodamine B dye. Materials Science in Semiconductor Processing, 2015, 30: 672–681
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This work was supported by the open topics of State Key Laboratory of Pollution Control and Resource Research (PCRRF14006).
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Niu, X., Ma, J. Fabrication of Ag3PO4-AgBr-PTh composite loaded on Na2SiO3 with enhanced visible-light photocatalytic activity. Front. Mater. Sci. 12, 264–272 (2018). https://doi.org/10.1007/s11706-018-0430-3
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DOI: https://doi.org/10.1007/s11706-018-0430-3