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Frontiers of Materials Science

, Volume 12, Issue 1, pp 53–63 | Cite as

Mo-doped Na3V2(PO4)3@C composites for high stable sodium ion battery cathode

  • Xiaoxiao Wang
  • Wanwan Wang
  • Baichuan Zhu
  • Fangfang Qian
  • Zhen Fang
Research Article

Abstract

NASICON-type Na3V2(PO4)3 (NVP) with superior electrochemical performance has attracted enormous attention with the development of sodium ion batteries. The structural aggregation as well as poor conductivity of NVP hinder its application in high rate perforamance cathode with long stablity. In this paper, Na3V2-xMo x (PO4)3@C was successfully prepared through two steps method, including sol-gel and solid state thermal reduction. The optimal doping amount of Mo was defined by experiment. When x was 0.15, the Na3V1.85Mo0.15(PO4)3@C sample has the best cycle performance and rate performance. The discharge capacity of Na3V1.85Mo0.15(PO4)3@C could reach 117.26 mA·h·g-1 at 0.1 C. The discharge capacity retention was found to be 94.5% after 600 cycles at 5 C.

Keywords

storage materials doping electrochemical reactions Na ion battery 

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Notes

Acknowledgements

Financially supports from the National Natural Science Foundation of China (Grant Nos. 21671005 and 21171007) and the Programs for Science and Technology Development of Anhui Province (1501021019) were acknowledged.

Supplementary material

11706_2018_414_MOESM1_ESM.pdf (98 kb)
Supplementary information

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Copyright information

© Higher Education Press and Springer-Verlag GmbH Germany, part of Springer Nature 2018

Authors and Affiliations

  • Xiaoxiao Wang
    • 1
  • Wanwan Wang
    • 1
  • Baichuan Zhu
    • 2
  • Fangfang Qian
    • 1
  • Zhen Fang
    • 1
  1. 1.College of Chemistry and Materials Science, The Key Laboratory of Functional Molecular Solids (Ministry of Education), Anhui Laboratory of Molecule-Based Materials, Center for Nano Science and TechnologyAnhui Normal UniversityWuhuChina
  2. 2.Division of Nanomaterials and Chemistry, Hefei National Laboratory for Physical Sciences at the Microscale, Department of ChemistryUniversity of Science and Technology of ChinaHefeiChina

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