Skip to main content
Log in

A simple single-step approach towards synthesis of nanofluids containing cuboctahedral cuprous oxide particles using glucose reduction

  • Research Article
  • Published:
Frontiers of Materials Science Aims and scope Submit manuscript

Abstract

Enhancement of thermal properties of conventional heat transfer fluids has become one of the important technical challenges. Since nanofluids offer a promising help in this regard, development of simpler and hassle free routes for their synthesis is of utmost importance. Synthesis of nanofluids using a hassle free route with greener chemicals has been reported. The single-step chemical approach reported here overcomes the drawbacks of the two-step procedures in the synthesis of nanofluids. The resulting Newtonian nanofluids prepared contained cuboctahedral particles of cuprous oxide and exhibited a thermal conductivity of 2.852 W·m-1·K-1. Polyvinylpyrrolidone (PVP) used during the synthesis acted as a stabilizing agent rendering the nanofluid a stability of 9 weeks.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Shin D, Banerjee D. Specific heat of nanofluids synthesized by dispersing alumina nanoparticles in alkali salt eutectic. International Journal of Heat and Mass Transfer, 2014, 74: 210–214

    Article  Google Scholar 

  2. Chakraborty S, Sarkar I, Haldar K, et al. Synthesis of Cu–Al layered double hydroxide nanofluid and characterization of its thermal properties. Applied Clay Science, 2015, 107: 98–108

    Article  Google Scholar 

  3. Chopkar M, Das P K, Manna I. Synthesis and characterization of nanofluid for advanced heat transfer applications. Scripta Materialia, 2006, 55(6): 549–552

    Article  Google Scholar 

  4. Li Y, Zhou J, Tung S, et al. A review on development of nanofluid preparation and characterization. Powder Technology, 2009, 196 (2): 89–101

    Article  Google Scholar 

  5. Li C C, Chang M H. Colloidal stability of CuO nanoparticles in alkanes via oleate modifications. Materials Letters, 2004, 58(30): 3903–3907

    Article  Google Scholar 

  6. Beck M P, Yuan Y, Warrier P, et al. The thermal conductivity of alumina nanofluids in water, ethylene glycol and ethylene glycolwater mixtures. Journal of Nanoparticle Research, 2010, 12(4): 1469–1477

    Article  Google Scholar 

  7. Eastman J A, Choi S U S, Li S, et al. Anomalously increased effective thermal conductivities of ethylene glycol based nanofluids containing copper nanoparticles. Applied Physics Letters, 2001, 78(6): 718–720

    Article  Google Scholar 

  8. Heo Y K, Bratescu M A, Aburaya D, et al. A phonon thermodynamics approach of gold nanofluids synthesized in solution Plasma. Applied Physics Letters, 2014, 104(11): 111902 (3 pages)

    Article  Google Scholar 

  9. Phuoc T X, Soong Y, Chyu MK. Synthesis of Ag-deionized water nanofluids using multi-beam laser ablation in liquids. Optics and Lasers in Engineering, 2007, 45(12): 1099–1106

    Article  Google Scholar 

  10. Lee G J, Kim C K, Lee M K, et al. Thermal conductivity enhancement of ZnO nanofluid using a one-step physical method. Thermochimica Acta, 2012, 542: 24–27

    Article  Google Scholar 

  11. Tavares J, Coulombe S. Dual plasma synthesis and characterization of a stable copper-ethylene glycol nanofluid. Powder Technology, 2011, 210(2): 132–142

    Article  Google Scholar 

  12. Zhao T, Sun R, Yu S, et al. Size controlled preparation of silver nanoparticles by a modified polyol method. Colloids and Surfaces A: Physicochemical and Engineering Aspects, 2010, 366(1–3): 197–202

    Article  Google Scholar 

  13. Zhu H T, Lin Y S, Yin Y S. A novel one-step chemical method for preparation of copper nanofluids. Journal of Colloid and Interface Science, 2004, 277(1): 100–103

    Article  Google Scholar 

  14. Kumar A S, Meenakshi K S, Narashimhan B R V, et al. Synthesis and characterization of copper nanofluid by a novel one-step method. Materials Chemistry and Physics, 2009, 113(1): 57–62

    Article  Google Scholar 

  15. Shenoy U S, Shetty A N. Synthesis of copper nanofluids using ascorbic acid reduction method via one step solution phase approach. Journal of ASTM International, 2012, 9(5): 104416

    Article  Google Scholar 

  16. Shenoy U S, Shetty A N. Simple glucose reduction route for one step synthesis of copper nanofluids. Applied Nanoscience, 2014, 4 (1): 47–54

    Article  Google Scholar 

  17. Shenoy U S, Shetty A N. Copper nanofluids: A facile synthetic approach. Journal of Nanoengineering and Nanomanufacturing, 2013, 3(1): 64–69

    Article  Google Scholar 

  18. Shenoy U S, Shetty A N. A facile ascorbic acid reduction method for solution phase single step synthesis of copper nanofluids. NanoTrends: A Journal of Nanotechnology and Its Applications, 2013, 14: 09734181

    Google Scholar 

  19. Shenoy U S, Shetty A N. A simple solution phase synthesis of copper nanofluids using single step glucose reduction method. Synthesis and Reactivity in Inorganic, Metal-Organic and Nano- Metal Chemistry, 2013, 43(3): 343–348

    Article  Google Scholar 

  20. Shenoy U S, Shetty A N. A simple approach towards synthesis of nanofluids containing octahedral copper nanoparticles. Journal of Nanofluids, 2015, 4(4): 428–434

    Article  Google Scholar 

  21. Shenoy U S, Shetty A N. Direct synthesis of nanofluids containing novel hexagonal disc shaped copper nanoparticles. Journal of Nanofluids, 2017, 6(1): 11–17

    Article  Google Scholar 

  22. Shenoy U S, Shetty A N. A facile one step solution route to synthesize cuprous oxide nanofluid. Nanomaterials and Nanotechology, 2013, 3(5): 2013 (7 pages)

    Google Scholar 

  23. Song H C, Cho Y S, Huh Y D. Morphology controlled synthesis of Cu2O microcrystal. Materials Letters, 2008, 62(10–11): 1734–1736

    Article  Google Scholar 

  24. Pal J, Ganguly M, Mondal C, et al. Crystal plane dependent etching of cuprous oxide nanoparticles of varied shapes and their application in visible light photocatalysis. The Journal of Physical Chemistry C, 2013, 117(46): 24640–24653

    Google Scholar 

  25. Zhang H, Liu F, Li B, et al. Microwave assisted synthesis of Cu2O microcrystals with systematic shape evolution from octahedral to cubic and their comparative photocatalytic activities. RSC Advances, 2014, 4(72): 38059–38063

    Article  Google Scholar 

  26. Wei X, Zhu H, Kong T, et al. Synthesis and thermal conductivity of Cu2O nanofluids. International Journal of Heat and Mass Transfer, 2009, 52(19–20): 4371–4374

    Article  Google Scholar 

  27. Murshed S M S, Leong K C, Yang C. Investigations of thermal conductivity and viscosity of nanofluid. International Journal of Thermal Sciences, 2008, 47(5): 560–568

    Article  Google Scholar 

  28. Sreeremya T S, Krishnan A, Satapathy L N, et al. Facile synthetic strategy of oleophilic zirconia nanoparticles allows preparation of highly stable thermo-conductive coolant. RSC Advances, 2014, 4 (53): 28020–28028

    Article  Google Scholar 

  29. Yu W, Xie H, Chen L, et al. Investigation of thermal conductivity and viscosity of ethylene glycol based ZnO nanofluid. Thermochimica Acta, 2009, 491(1–2): 92–96

    Article  Google Scholar 

  30. Li D, Xie W, Fang W. Preparation and properties of copper-oilbased nanofluids. Nanoscale Research Letters, 2011, 6(1): 373 (7 pages)

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to U. Sandhya Shenoy.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Shenoy, U.S., Shetty, A.N. A simple single-step approach towards synthesis of nanofluids containing cuboctahedral cuprous oxide particles using glucose reduction. Front. Mater. Sci. 12, 74–82 (2018). https://doi.org/10.1007/s11706-018-0411-6

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s11706-018-0411-6

Keywords

Navigation