New approaches to water purification for resource-constrained settings: Production of activated biochar by chemical activation with diammonium hydrogenphosphate
- 71 Downloads
A significant portion of the world’s population does not have access to safe drinking water. This problem is most acute in remote, resource-constrained rural settings in developing countries. Water filtration using activated carbon is one of the important steps in treating contaminated water. Lignocellulosic biomass is generally available in abundance in such locations, such as the African rain forests. Our work is focused on developing a simple method to synthesize activated biochar from locally available materials. The preparation of activated biochar with diammonium hydrogenphosphate (DAP) as the activating agent is explored under N2 flow and air. The study, carried out with cellulose as a model biomass, provides some insight into the interaction between DAP and biomass, as well as the char forming mechanism. Various characterization techniques such as N2 physisorption, X-ray photoelectron spectroscopy, scanning electron microscopy, transmission electron microscopy and Raman spectroscopy are utilized to compare the properties between biochar formed under nitrogen and partial oxidative conditions. At a temperature of 450 °C, the loading of DAP over cellulose is systematically varied, and its effect on activation is examined. The activated biochar samples are predominantly microporous in the range of concentrations studied. The interaction of DAP with cellulose is investigated and the nature of bonding of the heteroatoms to the carbonaceous matrix is elucidated. The results indicate that the quality of biochar prepared under partial oxidation condition is comparable to that of biochar prepared under nitrogen, leading to the possibility of an activated biochar production scheme on a small scale in resource-constrained settings.
Keywordscellulose DAP activation heteroatom microporous
Unable to display preview. Download preview PDF.
Support of this work by REFRESCH, funded through the University of Michigan’s Global Challenges for the Third Century program, is gratefully acknowledged. The authors thank Dr. Galen Fisher, Dr. Xiaoyin Chen and Dr. Andrew Tadd for their valuable insights during the research.
- 12.Puziy A, Poddubnaya O, Martínez-Alonso A, Suárez-García F, Tascón J M. Synthetic carbons activated with phosphoric acid: I. Surface chemistry and ion binding properties. Carbon, 2002, 40(9): 1493–1505Google Scholar
- 23.Oshida K, Kogiso K, Matsubayashi K, Takeuchi K, Kobayashi S, Endo M, Dresselhaus M S, Dresselhaus G. Analysis of pore structure of activated carbon fibers using high resolution transmission electron microscopy and image processing. Journal of Materials Research, 1995, 10(10): 2507–2517CrossRefGoogle Scholar
- 28.Pelavin M, Hendrickson D N, Hollander J M, Jolly W L. Phosphorus 2p electron binding energies. Correlation with extended Hueckel charges. Journal of Physical Chemistry, 1970, 74(5): 1116–1121Google Scholar
- 29.Marsh H, Rodríguez-Reinoso F. Activated carbon. Elsevier, 2006, 224–225Google Scholar