To recover dyes and reuse adsorbents in the process of dye wastewater treatment, a new composite adsorbent based on viscose fiber cloth and Cu–BTEC MOFs was designed. The MOF materials were evenly distributed on the fiber surface via an in situ hot pressing process. The adsorbent could effectively adsorb methylene blue as the model dye in the solution, and the adsorption efficiency could reach 84% in 4 h. When the adsorbent is spent after several adsorption cycles, it could be recovered to a higher adsorption efficiency by UV catalytic regeneration. Hence, the explored material should be applicable in the field of wastewater treatment.
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Abbasi AR, Akhbari K, Morsali A (2012) Dense coating of surface mounted CuBTC metal–organic framework nanostructures on silk fibers, prepared by layer-by-layer method under ultrasound irradiation with antibacterial activity. Ultrason Sonochem 19(4):846–852. https://doi.org/10.1016/j.ultsonch.2011.11.016
Brillasa E, Martínez-Huitle CA (2015) Decontamination of wastewaters containing synthetic organic dyes by electrochemical methods. Appl Catal B Environ 166:603–643. https://doi.org/10.1016/j.apcatb.2014.11.016
Fang Y, Zhang L, Zhao Q, Wang X, Jia X (2019) Application of acid-promoted UiO-66-NH2 MOFs in the treatment of wastewater containing methylene blue. Chem Pap 73(6):1401–1411. https://doi.org/10.1007/s11696-019-00692-2
Feng L, Ren G, Wang F, Yang W, Zhu G, Pan Q (2019) Two bimetallic metal–organic frameworks capable of direct photocatalytic degradation of dyes under visible light. Transit Met Chem 44:275–281. https://doi.org/10.1007/s11243-018-0292-7
Han R, Zhang J, Han P, Wang Y, Zhao Z, Tang M (2009) Study of equilibrium, kinetic and thermodynamic parameters about methylene blue adsorption onto natural zeolite. Chem Eng J 145:496–504. https://doi.org/10.1016/j.cej.2008.05.003
Huo S, Yan X (2012) Metal–organic framework MIL-100(Fe) for the adsorption of malachite green from aqueous solution. J Mater Chem 22:7449–7455. https://doi.org/10.1039/C2JM16513A
Ji L, Wang J, Wu K, Yang N (2018) Tunable electrochemistry of electrosynthesized copper metal–organic frameworks. Adv Funct Mater 28(13):1706961. https://doi.org/10.1002/adfm.201706961
Kaur R, Kaur A, Umar A, Anderson WA, Kansal SK (2019) Metal organic framework (MOF) porous octahedral nanocrystals of Cu-BTC: synthesis, properties and enhanced adsorption properties. Mater Res Bull 109:124–133. https://doi.org/10.1016/j.materresbull.2018.07.025
Khansorthong S, Hunsom M (2009) Remediation of wastewater from pulp and paper mill industry by the electrochemical technique. Chem Eng J 151:228–234. https://doi.org/10.1016/j.cej.2009.02.038
Liu J, Wang Y, Guo H, Fan S (2020) A novel heterogeneous MOF membrane MIL-121/118 with selectivity towards hydrogen. Inorg Chem Commun 111:107637. https://doi.org/10.1016/j.inoche.2019.107637
Liu L, Zhang J, Tan Y, Jiang Y, Hu M, Li S, Zhai Q (2014) Rapid decolorization of anthraquinone and triphenylmethane dye using chloroperoxidase: catalytic mechanism, analysis of products and degradation route. Chem Eng J 244:9–18. https://doi.org/10.1016/j.cej.2014.01.063
Ozer RR, Hinestroza JP (2015) One-step growth of isoreticular luminescent metal–organic frameworks on cotton fibers. RSC Adv 5(20):15198–15204. https://doi.org/10.1039/C4RA15161E
Yener J, Kopac T, Dogu G, Dogu T (2008) Dynamic analysis of sorption of methylene blue dye on granular and powdered activated carbon. Chem Eng J 144:400–406. https://doi.org/10.1016/j.cej.2008.02.009
Zeng L, Xiao L, Long Y, Shi X (2018) Trichloroacetic acid-modulated synthesis of polyoxometalate@UiO-66 for selective adsorption of cationic dyes. J Colloid Interface Sci 516:274–283. https://doi.org/10.1016/j.jcis.2018.01.070
Zhao Q, Zhu L, Lin G, Chen G, Liu B, Zhang L, Duan T, Lei J (2019) Controllable synthesis of porous Cu-BTC@ polymer composite beads for iodine capture. ACS Appl Mater Interfaces 11(45):42635–42645. https://doi.org/10.1021/acsami.9b15421
This project was financially supported by the Henan Province Program for Science and Technology Development (16210221247), the Program of Henan Province Department of Education (15A430053) and the Basic Scientific Research Program of Zhongyuan University of Technology (K2018QN018).
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Jia, X., Wang, X., Zhang, L. et al. A regenerated adsorbent by ultraviolet irradiation based on viscose fiber cloth/Cu–BTEC MOFs for methylene blue adsorption. Chem. Pap. (2020). https://doi.org/10.1007/s11696-020-01219-w
- Viscose fiber
- Metal–organic framework material
- Regeneration by UV
- Methylene blue