Abstract
A new Keggin-type heteropolyoxometalates compound, {[Cd(DMA)4]2(bibp)(SiW12O40)}n (1), (DMA = N, N-dimethylacetamide, bibp = 4,4′-bis(1-imidazolyl) biphenyl) has been synthesized and characterized by single-crystal X-ray diffraction, IR spectrum, elemental analysis, powder X-ray diffraction, thermogravimetric (TG) analysis and electrochemical analysis. Compound 1 is crystallized in orthorhombic with Pbca space group. The [SiW12O40]4− anions and bibp ligands are linked by coordinated Cd2+ ions alternately into a zigzag-like chain, and the chains are extended into a three-dimensional (3D) framework by the C–H···O hydrogen bonds. The cyclic voltammetry analyses show that compound 1 presences of W-centered reversible redox processes and that 1 has electrocatalytic activities towards the reduction of nitrite.
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References
Brese NE, O’keeffe M (1991) Bond-valence parameters for solids. Acta Crystallogr B 47:192–197. https://doi.org/10.1107/S0108768190011041
Dong S, Xi X, Tian M (1995) Study of the electrocatalytic reduction of nitrite with silicotungstic heteropolyanion. J Electroanal Chem 385:227–233. https://doi.org/10.1016/0022-0728(94)03770-4
Enferadi-Kerenkan A, Do TO, Kaliaguine S (2018) Heterogeneous catalysis by tungsten-based heteropoly compounds. Catal Sci Technol 8:2257–2284. https://doi.org/10.1039/c8cy00281a
Fan J, Hanson BE (2005) A two-dimensional cationic lattice built from [Zn6(HPO4)2(PO4)2]2+ clusters. Chem Commun 18:2327–2329. https://doi.org/10.1039/b501221j
Flack HD, Bernardinelli G (2000) Reporting and evaluating absolute-structure and absolute-configuration determinations. J Appl Cryst 33:1143–1148. https://doi.org/10.1107/S0021889800007184
Hao XL, Ma YY, Zhang C, Wang Q, Cheng X, Wang YH, Li YG, Wang EB (2012) Assembly of new organic-inorganic hybrids based on copper-bis (triazole) complexes and Keggin-type polyoxometalates with different negative charges. CrystEngComm 14:6573–6580. https://doi.org/10.1039/c2ce25747e
Hu SY, Ma CC, Zhan FY, Cao YL, Hu PF, Zhen Q (2017) Batch synthesis of polyoxometalate-based phosphonium compounds by one-step room-temperature mechanochemical process, and their morphology-dependent antibacterial activities. Chem Pap 71:1–7. https://doi.org/10.1007/s11696-016-0124-1
Jiang XY, Wu XY, Yu RM, Yuan DQ, Chen WZ (2011) A glycine ligand coordinated hybrid complex constructed from hexanuclear copper clusters and octamolybdates. Inorg Chem Commun 14:1546–1549. https://doi.org/10.1016/j.inoche.2011.05.001
Kong Z, Wang CL, Ren YH, Gu M, Hu YC, Yue B, He HY (2012) Synthesis, structure, and properties of two supramolecular compounds based on silicotungstic acid and transition metal (II) coordinated isonicotinic acid. Chin J Chem 30:759–764. https://doi.org/10.1002/cjoc.201100439
Meng XM, Zhang X, Qi PF, Zong ZA, Jin F, Fan YH (2017) Syntheses, structures, luminescent and photocatalytic properties of various polymers based on a “V”-shaped dicarboxylic acid. Rsc Adv 7:4855–4871. https://doi.org/10.1039/c6ra27509e
Proust A, Thouvenot R, Gouzerh P (2008) Functionalization of polyoxometalates: towards advanced applications in catalysis and materials science. Chem Commun 39:1837–1852. https://doi.org/10.1039/b715502f
Sheldrick GM (2015) Crystal structure refinement with SHELXL. Acta Crystallogr C 71:3–8. https://doi.org/10.1107/S2053229614024218
Shi ZY, Zhang ZY, Peng J, Yu X, Wang X (2013) Assembly of copper–tetrazole frameworks with role-changeable Keggin clusters: syntheses, structures, solvent-dependent luminescence and electrochemistry properties. CrystEngComm 15:7199–7205. https://doi.org/10.1039/c3ce41008k
Silva MJD, Oliveira CMD (2018) Catalysis by Keggin heteropolyacid salts. Curr Catal 7:26–34. https://doi.org/10.2174/2211544707666171219161414
Teazea A, Hervea G, Finke RG, Lyon DK (2007) α-, β-, and γ-dodecatungstosilicic acids: isomers and related lacunary compounds. Inorg Synth 27:85–96. https://doi.org/10.1002/9780470132586.ch16
Wu XY, Yang WB, Wu WM, Liao JZ, Wang SS, Lu CZ (2017) A inorganic-organic hybrid material constructed from the monolacunary polyoxomolybdates and multi-nuclear copper clusters. Inorg Chem Commun 76:118–121. https://doi.org/10.1016/j.inoche.2017.01.026
Zhang CL, Qin L, Zheng HG (2013) Synthesis, characterization and crystal structure of one Mn(II) complex with 4,4′-bisimidazolylbiphenyl and 4,4′-sulfonyldibenzoic acid. Inorg Chem Commun 34:34–36. https://doi.org/10.1016/j.inoche.2013.05.006
Zhao JW, Li YZ, Chen LJ, Yang GY (2016) Research progress on polyoxometalate-based transition-metal-rare-earth heterometallic derived materials: synthetic strategies, structural overview and functional applications. Chem Commun 52:4418–4445. https://doi.org/10.1039/c5cc10447e
Zhao WJ, Tan JT, Li X, Lu YL, Feng X, Yang XW (2014) Two new frameworks for biphenyl-3, 3′, 5, 5′-tetracarboxylic acid and nitrogen-containing organics. Chem Pap 68:1415–1420. https://doi.org/10.2478/s11696-014-0584-0
Zonoz FM, Jamshidi A, Tavakoli S (2013) Preparation, characterization and electrochemical investigation of a new inorganic-organic hybrid material based on keggin-type polyoxometalate and organic imidazole cation. Solid State Sci 17:83–89. https://doi.org/10.1016/j.solidstatesciences.2012.10.029
Zonoz FM, Zonoz IM, Jamshidi A, Alizadeh MH (2014) Synthesis, characterization and electrochemical investigation of a new inorganic-organic hybrid compound constructed by Keggin-type polyoxometalate and cyanoguanidine. Solid State Sci 32:13–19. https://doi.org/10.1016/j.solidstatesciences.2014.03.010
Acknowledgements
This work was supported by the National Natural Science Foundation of China [Grant numbers 51672271]; the National Natural Science Foundation of China [Grant numbers 21701172]; the Key Project of Science and Technology Plan of Fujian Province [Grant numbers 2014H0007]; and the Fujian University of Technology [Grant numbers GY-Z12088].
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Xiao, H., Wu, XY., Yang, MX. et al. A new Keggin-type heteropolyoxometalates compound built up by coordinated cadmium. Chem. Pap. 73, 2165–2170 (2019). https://doi.org/10.1007/s11696-019-00738-5
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DOI: https://doi.org/10.1007/s11696-019-00738-5