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Effect of polyoxymethylene dimethyl ethers on particle properties and diesel particulate filter regeneration

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Abstract

The emission tests were performed on a light-duty direct injection diesel engine. A polyoxymethylene dimethyl ethers (PODE) mixture was blended with diesel at a volume ratio of 0, 10, 20 and 30%, denoted as P0, P10, P20 and P30, respectively. The particle size distribution before and after the diesel particulate filter (DPF) was measured to evaluate the DPF filtering efficiency of various modal particles. The oxidation activity of the particles on the DPF intake end plane was analyzed by the Arrhenius method. The regeneration of the DPF was conducted using a non-thermal plasma (NTP) injection system. The results showed that blending PODE with diesel contributed to reducing the particle number concentrations. PODE adversely affected the improvement of the DPF filtering efficiency, especially that of P30. However, the DPF filtering efficiency of all fuels was still higher than 94%. Blending PODE with diesel increased the mass fraction of volatile substances (VS) and decreased the mass fraction of dry soot. Particles of P20 showed a better oxidation activity with lower apparent activation energy. In addition, PODE increased the DPF regeneration effect by NTP technology. The deposit removal mass of the DPF rose to the peak level and then decreased as the PODE blending ratio increased. The better DPF regeneration effect was observed when P20 was employed.

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Abbreviations

PODE:

Polyoxymethylene dimethyl ethers

DPF:

Diesel particulate filter

NTP:

Non-thermal plasma

VS:

Volatile substances

DS:

Dry soot

PM:

Particulate matter

SOF:

Soluble organic fraction

ULSD:

Ultra-low sulfur diesel

B100:

Biodiesel fuel

B20:

20% biodiesel/diesel blends

FT:

Fischer–Tropsch fuel

CO:

Carbon monoxide

CO2 :

Carbon dioxide

NOx :

Nitrogen oxide

TG:

Thermogravimetric

DTG:

Differential thermogravimetric

LHV:

Low heating values

P0:

Diesel

P10:

10% PODE/diesel blends

P20:

20% PODE/diesel blends

P30:

30% PODE/diesel blends

INTP:

Indirect non-thermal plasma

CN:

Cetane number

PAHs:

Polycyclic aromatic hydrocarbons

EEPS:

Engine exhaust particle sizer spectrometer

DBD:

Dielectric barrier discharge

D P :

Characteristic particle size of PM

η :

The particle filtering efficiency of the DPF

n :

The particle total number concentration

E a :

Apparent activation energy

m :

The mass of reactants at the time of t

t :

The time of the heating process

A :

The pre-exponential factor

PO 2 :

The partial pressure of oxygen

R :

The gas constant

T :

The reaction temperature

m(C 1):

The removal mass of C in CO

m(C 2):

The removal mass of C in CO2

c1 :

The volume fraction of CO

c2 :

The volume fraction of CO2

M:

The molar mass of C

q a :

The flow rate of the active gas

V m :

The gas molar volume

m(C 12):

The sum of m(C1) and m(C2)

DMC:

Dimethyl carbonate

DME:

Dimethyl ether

DMM:

Dimethoxymethane

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Acknowledgements

This work was financially supported by the National Natural Science Foundation of China (No. 51676089), the Key University Science Research Project of Jiangsu Province (No. 16KJA470002), the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD), and the Science Research Project of Xuzhou Institute of Technology (No. XKY2016223).

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Correspondence to Yixi Cai.

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Tian, J., Cai, Y., Pu, X. et al. Effect of polyoxymethylene dimethyl ethers on particle properties and diesel particulate filter regeneration. Chem. Pap. 73, 455–468 (2019). https://doi.org/10.1007/s11696-018-0593-5

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  • DOI: https://doi.org/10.1007/s11696-018-0593-5

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