Abstract
In this work, the complexation of aluminium (III) with 3-[4-(dimethylamino)cinnamoyl]-4-hydroxy-6-methyl-3,4-2H-pyran-2-one (ligand) in the presence of fluoride using an optical probe for absorbance measurement was studied. It was adjusted that the complex was formed in the molar ratio (Al–Lig)3 to F 1:1. The reaction was applied to determine of fluoride. The optimum conditions were achieved at pH 8 with concentrations of Al3+ and ligand 6.75 and 0.195 mg L−1, respectively. Under optimized conditions, the calibration curve showed good linearity (r = –0.9976) in the range 0.23–1.9 mg L−1 of fluoride. The limit of detection of fluoride was found to be 0.02 mg L−1. The proposed method was applied for determination of fluoride concentration in mineral water samples and fully automated by sequential injection system.
Similar content being viewed by others
References
Akhond M, Absalan G, Khoshnoodi-Chasroddashti Y, Ershadifar H (2016) Reflection scanometry as a new detection technique in temperature-controlled ionic liquid based dispersive liquid phase microextraction. Anal Methods 8:111–118. https://doi.org/10.1039/c5ay01981h
Alpízar J, Crespí A, Cladera A, Forteza R, Cerdà V (1996) Simultaneous determination of chloride and fluoride ions in waters by sequential injection analysis. Electroanalysis 11(8):1051–1054. https://doi.org/10.1002/elan.1140081113
Barberio AM, Hosein FS, Quiñonez C, McLaren L (2017) Fluoride exposure and indicators of thyroid functioning in the Canadian population: implications for community water fluoridation. J Epidemiol Community Health 71(10):1019–1025. https://doi.org/10.1136/jech-2017-209129
Bayón MM, Rodrígues Garsia A, García Alonso JI, Sanz-Medel A (1999) Indirect determination of trace amounts of fluoride in natural waters by ion chromatography: a comparison of on-line post-column fluorimetry and ICP-MS detectors. Analyst 124:27–31. https://doi.org/10.1039/A807079B
Bellack E, Schouboe PJ (1958) Rapid photometric determination of fluoride in water: use of sodium 2-(p-sulfophenylazo)-1,8-dihydroxynaphthalene-3,6-disulfonate-zirconium lake. Anal Chem 30(12):2032–2034. https://doi.org/10.1021/ac60144a050
Cardwell TJ, Cattrall RW, Hauser PC, Hamilton IC (1987) Buffer systems for use with the fluoride electrode in flow injection analysis. Anal Chem 59:206–208. https://doi.org/10.1021/ac00128a045
Elečková L, Alexovič M, Kuchár J, Balogh IS, Andruch V (2015) Visual detection and sequential injection determination of aluminium using a cinnamoyl derivative. Talanta 133:27–33. https://doi.org/10.1016/j.talanta.2014.04.064
Everett ET (2011) Fluoride’s effects on formation of teeth and bones, and the influence of genetics. J Den Res 90(5):552–560. https://doi.org/10.1177/0022034510384626
Farajzadeh MA (2004) An extractive-spectrophotometric method for determination of fluoride ions in natural waters based on its bleaching effect on the iron (III)-thiocyanate complex. J Chin Chem Soc 51:303–308. https://doi.org/10.1002/jccs.200400047
Gleisner H, Welz B, Einax JW (2010) Optimization of fluorine determination via the molecular absorption of gallium mono-fluoride in a graphite furnace using a high-resolution continuum source spectrometer. Spectrochim Acta B 65(9–10):864–869. https://doi.org/10.1016/j.sab.2010.08.003
Guo W, Jin L, Hu Sh, Guo Q (2017) Method development for the determination of total fluorine in foods by tandem inductively coupled plasma mass spectrometry with a mass-shift strategy. J Agric Food Chem 65(16):3406–3412. https://doi.org/10.1021/acs.jafc.7b00535
Jones PH (1992) Development of a high-sensitivity ion chromatography method for the determination of trace fluoride in water utilizing the formation of the AlF2+ species. Anal Chem Acta 258:123–127. https://doi.org/10.1016/0003-2670(92)85204-J
Khalifa ME, Hafez MAH (1998) Spectrophotometric and complexometric methods for the determination of thorium and fluoride using bromocresol orange reagent. Talanta 47(3):547–559. https://doi.org/10.1016/S0039-9140(98)00078-2
Lou C, Gou D, Wang N, Wu S, Zhang P, Zhu Y (2017) Detection of trace fluoride in serum and urine by online membrane-based distillation coupled with ion chromatography. J Chrom A 1500:145–152. https://doi.org/10.1016/j.chroma.2017.04.029
Manzoori JL, Miyazaki A (1990) Indirect inductively coupled plasma atomic emission determination of fluoride in water samples by flow injection solvent extraction. Anal Chem 62(22):2457–2460. https://doi.org/10.1021/ac00124a032
Megregian S (1954) Rapid spectrophotometric determination of fluoride with zirconium-eriochrome cyanine R lake. Anal Chem 26(7):1161–1166. https://doi.org/10.1021/ac60091a018
Miyake Y, Yamashita N, So MK, Rostkowski P, Taniyasu S, Lam PKS, Kannan K (2007) Trace analysis of total fluorine in human blood using combustion ion chromatography for fluorine: a mass balance approach for the determination of known and unknown organofluorine compounds. J Chromatogr A 1154:214–221. https://doi.org/10.1016/j.chroma.2007.03.084
Morés S, Monteiro GC, Santos Fda S, Carasek E, Welz B (2011) Determination of fluorine in tea using high-resolution molecular absorption spectrometry with electrothermal vaporization of the calcium mono-fluoride CaF. Talanta 85:2681–2685. https://doi.org/10.1016/j.talanta.2011.08.044
Ozbek N, Akman S (2012) Method development for the determination of fluorine in toothpaste via molecular absorption of aluminum mono fluoride using a high-resolution continuum source nitrous oxide/acetylene flame atomic absorption spectrophotometer. Talanta 94:246–250. https://doi.org/10.1016/j.talanta.2012.03.034
Ozbek N, Akman S (2014) Determination of fluorine in milk and water via molecular absorption of barium monofluoride by high-resolution continuum source atomic absorption spectrometer. Microchem J 117:111–115. https://doi.org/10.1016/j.microc.2014.06.013
Pérez-Ruiz T, Martinez-Lozano C, Tomas V (1996) Flow injection spectrofluorimetric determination of fluoride or phosphate based on their inhibitory effect on the photo-oxidat ion of acridine catalysed by iron (III). Analyst 121:477–481. https://doi.org/10.1039/AN9962100477
Pochivalov A, Vakh C, Andruch V, Moskvin L, Bulatov A (2017) Automated alkaline-induced salting-out homogeneous liquid–liquid extraction coupled with in-line organic-phase detection by an optical probe for the determination of diclofenac. Talanta 169:159–162. https://doi.org/10.1016/j.talanta.2017.03.074
Sahin R, Tapadia R, Sharma A (2016) In situ determination of fluoride in groundwater using N-octyl acetamide with iron(III)–thiocyanate complex. J Appl Spectrosc 83(3):437–441. https://doi.org/10.1007/s10812-016-0307-0
Themelis DG, Tzanavaras PD (2001) Simultaneous spectrophotometric determination of fluoride and monofluorophosphate ions in toothpastes using a reversed flow injection manifold. Anal Chim Acta 429:111–116. https://doi.org/10.1016/S0003-2670(00)01271-X
Tykhanov DA, Serikova II, Yaremenko FG, Roshal AD (2010) Structure and spectral properties of cinnamoyl pyrones and their vinylogs. Cent Eur J Chem 8(2):347–355. https://doi.org/10.2478/s11532-009-0138-4
Zaruba S, Vishnikin AB, Škrliková J, Diuzheva A, Ozimaničova I, Gavazov K, Andruch V (2017) A two-in-one device for online monitoring of direct immersion single-drop microextraction: an optical probe as both microdrop holder and measuring cell. RSD Adv 7:29421–29427. https://doi.org/10.1039/C7RA02326J
Zolgharnein J, Shahrjerdi A, Azimi G, Ghasemi J (2009) Spectrophotometric determination of trace amounts of fluoride using an Al-xylenol orange complex as a colored reagent. Anal Sci 25(10):1249–1253. https://doi.org/10.2116/analsci.25.1249
Acknowledgements
A.D. would like to say a special thanks to the International Visegrad Fund for providing a 10-month scholarship.
Author information
Authors and Affiliations
Corresponding author
Ethics declarations
Conflict of interest
Authors have declared no conflict of interest.
Human and animal rights statement
This article does not contain any studies with human or animal subjects.
Rights and permissions
About this article
Cite this article
Diuzheva, A., Šandrejová, J. & Balogh, J. Study of complexation of aluminium with cinnamoyl derivative in the presence of fluoride ions using an optical probe: automated determination of fluoride. Chem. Pap. 73, 165–172 (2019). https://doi.org/10.1007/s11696-018-0570-z
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s11696-018-0570-z