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Chemical Papers

, Volume 72, Issue 11, pp 2745–2752 | Cite as

Iodine-mediated acyloxyselenenylation of alkenes

  • Xiaolong Wang
  • Junxing Wang
  • Hongjie Li
  • Jie Yan
  • Zhenping YangEmail author
Original Paper
  • 91 Downloads

Abstract

In the presence of I2, an acyloxyselenenylation of alkenes with diselenides and carboxylic acids is developed. This metal-free iodine-mediated acyloxyselenenylation proceeds efficiently under mild reaction conditions, affording a series of 2-acyloxy-1-selenides with high regioselectivity and in moderate to good yields.

Keywords

Acyloxyselenenylation Acetoxyselenenylation Formyloxyselenylation I2 

Supplementary material

11696_2018_496_MOESM1_ESM.doc (1.3 mb)
Supplementary material 1 (DOC 1328 kb)

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Copyright information

© Institute of Chemistry, Slovak Academy of Sciences 2018

Authors and Affiliations

  • Xiaolong Wang
    • 1
  • Junxing Wang
    • 1
  • Hongjie Li
    • 1
  • Jie Yan
    • 1
  • Zhenping Yang
    • 1
    Email author
  1. 1.College of Chemical EngineeringZhejiang University of TechnologyHangzhouPeople’s Republic of China

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