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Organometallic chiral Schiff base for enantio-selective fluorescent recognition of methionine

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Abstract

Herein, the synthesis and characterization of a novel chiral Schiff bases derived from ferrocene, coded as 3, have been reported. The sensing behavior of the synthesized compound has been examined towards the enantiomers of some amino acids (methionine, alanine, serine, histidine, and threonine) by spectrofluorimetric method. The fluorescence response of compound 3 showed noticeable enhancement upon addition of d-methionine compared to l-methionine and kept nearly linear correlation with the concentration of d-methionine. The value of enantiomeric fluorescence difference ratio (ef) has been determined to be 1.54 when d - and l- methionine amount is 100 times more than compound 3. The results showed that the compound 3 can be used as a sensor for enantio-selective recognition of d-methionine.

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Acknowledgements

The authors are grateful to the grant sponsored by the Scientific Research Projects (BAP-13201020) of Selcuk University.

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Authors and Affiliations

  1. Department of Science Education, Education Faculty, Agri İbrahim Cecen University, 04100, Agri, Turkey

    Asuman Ucar

  2. Department of Chemistry, Faculty of Science, Selcuk University, 42130, Selcuklu/Konya, Turkey

    Asuman Ucar, Mukerrem Findik, Ersin Guler & Emine Ozcan

  3. Chemistry Department, Ahmet Kelesoglu Education Faculty, Necmettin Erbakan University, 42090, Meram/Konya, Turkey

    Haluk Bingol

Authors
  1. Asuman Ucar
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  2. Mukerrem Findik
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  3. Haluk Bingol
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  4. Ersin Guler
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  5. Emine Ozcan
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Correspondence to Asuman Ucar.

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Ucar, A., Findik, M., Bingol, H. et al. Organometallic chiral Schiff base for enantio-selective fluorescent recognition of methionine. Chem. Pap. 71, 1855–1862 (2017). https://doi.org/10.1007/s11696-017-0179-7

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